Rhenium(I) and platinum(II) complexes with diimine ligands bearing acidic phenol substituents : hydrogen-bonding, acid-base chemistry andoptical properties

Publication type:
Journal article
Metadata:
Autoren
  • Wei Liu
  • Katja Heinze
Sammlungen
  • metadata
ISSN
1477-9226
Ausgabe der Veröffentlichung
40
Zeitschrift
Dalton transactions
Schlüsselwörter
  • 540 Chemie
  • 540 Chemistry and allied sciences
Sprache
eng
Paginierung
Seiten: 9554 - 9564
Datum der Veröffentlichung
2010
Herausgeber URL
http://dx.doi.org/10.1039/C0DT00393J
Datum der Datenerfassung
2020
Datum, an dem der Datensatz öffentlich gemacht wurde
2020
Zugang
Public
Titel
Rhenium(I) and platinum(II) complexes with diimine ligands bearing acidic phenol substituents : hydrogen-bonding, acid-base chemistry andoptical properties
Ausgabe der Zeitschrift
39

Data source: METADATA.UB

Other metadata sources:
Autoren
  • Wei Liu
  • Katja Heinze
Autoren-URL
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000282516500019&DestLinkType=FullRecord&DestApp=WOS_CPL
DOI
10.1039/c0dt00393j
eISSN
1477-9234
Externe Identifier
  • Clarivate Analytics Document Solution ID: 658VC
  • PubMed Identifier: 20820607
ISSN
1477-9226
Ausgabe der Veröffentlichung
40
Zeitschrift
DALTON TRANSACTIONS
Paginierung
9554 - 9564
Datum der Veröffentlichung
2010
Status
Published
Titel
Rhenium(I) and platinum(II) complexes with diimine ligands bearing acidic phenol substituents: hydrogen-bonding, acid-base chemistry and optical properties
Sub types
  • Article
Ausgabe der Zeitschrift
39

Data source: Web of Science (Lite)

Autoren
  • Wei Liu
  • Katja Heinze
DOI
10.1039/c0dt00393j
eISSN
1477-9234
ISSN
1477-9226
Ausgabe der Veröffentlichung
40
Zeitschrift
Dalton Transactions
Sprache
en
Paginierung
9554 - 9554
Datum der Veröffentlichung
2010
Status
Published
Herausgeber
Royal Society of Chemistry (RSC)
Herausgeber URL
http://dx.doi.org/10.1039/c0dt00393j
Datum der Datenerfassung
2024
Titel
Rhenium(i) and platinum(ii) complexes with diimine ligands bearing acidic phenol substituents: hydrogen-bonding, acid–base chemistry and optical properties
Ausgabe der Zeitschrift
39

Data source: Crossref

Abstract
Tricarbonylchloro-rhenium(i) (1-4) and catecholato-platinum(ii) complexes (6, 7) of diimine ligands bearing phenol and O-protected phenol substituents have been prepared and fully characterised including single crystal structure analyses of 1, 4 and 7. The redox behaviour of the catecholato platinum(ii) complexes 6 and 7 has been probed by cyclic voltammetry, preparative oxidation and EPR spectroscopy (6˙(+), 7˙(+)). Reversible deprotonation of the hydroxy substituted complexes 1, 3 and 6 to 1(-), 3(-) and 6(-) resulted in significant changes in their electronic spectra. The luminescence properties of the diamagnetic complexes have been investigated using emission spectroscopy. DFT and TD-DFT calculations were invoked to shed some light onto the geometric and electronic structures as well as the experimental spectroscopic properties of the neutral complexes 1-7, the radical cations 6˙(+) and 7˙(+) and the conjugate bases 1(-), 3(-) and 6(-).
Addresses
  • Johannes Gutenberg-University of Mainz, Duesbergweg 10-14, 55128, Mainz, Germany.
Autoren
  • Wei Liu
  • Katja Heinze
DOI
10.1039/c0dt00393j
eISSN
1477-9234
Externe Identifier
  • PubMed Identifier: 20820607
Open access
false
ISSN
1477-9226
Ausgabe der Veröffentlichung
40
Zeitschrift
Dalton transactions (Cambridge, England : 2003)
Schlüsselwörter
  • Platinum
  • Rhenium
  • Imines
  • Phenol
  • Ligands
  • Crystallography, X-Ray
  • Spectrophotometry, Infrared
  • Spectrophotometry, Ultraviolet
  • Molecular Conformation
  • Hydrogen Bonding
  • Quantum Theory
  • Coordination Complexes
Sprache
eng
Medium
Print-Electronic
Online publication date
2010
Paginierung
9554 - 9564
Datum der Veröffentlichung
2010
Status
Published
Datum der Datenerfassung
2010
Titel
Rhenium(I) and platinum(II) complexes with diimine ligands bearing acidic phenol substituents: hydrogen-bonding, acid-base chemistry and optical properties.
Sub types
  • Journal Article
Ausgabe der Zeitschrift
39

Data source: Europe PubMed Central

Abstract
Tricarbonylchloro-rhenium(i) (1-4) and catecholato-platinum(ii) complexes (6, 7) of diimine ligands bearing phenol and O-protected phenol substituents have been prepared and fully characterised including single crystal structure analyses of 1, 4 and 7. The redox behaviour of the catecholato platinum(ii) complexes 6 and 7 has been probed by cyclic voltammetry, preparative oxidation and EPR spectroscopy (6˙(+), 7˙(+)). Reversible deprotonation of the hydroxy substituted complexes 1, 3 and 6 to 1(-), 3(-) and 6(-) resulted in significant changes in their electronic spectra. The luminescence properties of the diamagnetic complexes have been investigated using emission spectroscopy. DFT and TD-DFT calculations were invoked to shed some light onto the geometric and electronic structures as well as the experimental spectroscopic properties of the neutral complexes 1-7, the radical cations 6˙(+) and 7˙(+) and the conjugate bases 1(-), 3(-) and 6(-).
Autoren
  • Wei Liu
  • Katja Heinze
Autoren-URL
https://www.ncbi.nlm.nih.gov/pubmed/20820607
DOI
10.1039/c0dt00393j
eISSN
1477-9234
Ausgabe der Veröffentlichung
40
Zeitschrift
Dalton Trans
Schlüsselwörter
  • Coordination Complexes
  • Crystallography, X-Ray
  • Hydrogen Bonding
  • Imines
  • Ligands
  • Molecular Conformation
  • Phenol
  • Platinum
  • Quantum Theory
  • Rhenium
  • Spectrophotometry, Infrared
  • Spectrophotometry, Ultraviolet
Sprache
eng
Country
England
Paginierung
9554 - 9564
Datum der Veröffentlichung
2010
Status
Published
Datum, an dem der Datensatz öffentlich gemacht wurde
2011
Titel
Rhenium(I) and platinum(II) complexes with diimine ligands bearing acidic phenol substituents: hydrogen-bonding, acid-base chemistry and optical properties.
Sub types
  • Journal Article
Ausgabe der Zeitschrift
39

Data source: PubMed

Beziehungen:
Property of

Tools