Synthesis of graphene nanoribbons by ambient-pressure chemical vapor deposition and device integration

Autoren

Zongping Chen
Wen Zhang
Carlos-Andres Palma
Alberto Lodi Rizzini
Bilu Liu
Ahmad Abbas
Nils Richter
Leonardo Martini
Xiao-Ye Wang
Nicola Cavani
Hao Lu
Neeraj Mishra
Camilla Coletti
Reinhard Berger
Florian Klappenberger
Mathias Klaui
Andrea Candini
Marco Affronte
Chongwu Zhou
Valentina De Renzi
Umberto del Pennino
Johannes V Barth
Hans Joachim Raeder
Akimitsu Narita
Xinliang Feng
Klaus Muellen

Autoren-URL

https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000389160500028&DestLinkType=FullRecord&DestApp=WOS_CPL

DOI

10.1021/jacs.6b10374

Externe Identifier

Clarivate Analytics Document Solution ID: ED8ZV
PubMed Identifier: 27933922

ISSN

0002-7863

Ausgabe der Veröffentlichung

47

Zeitschrift

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Paginierung

15488 - 15496

Datum der Veröffentlichung

2016

Status

Published

Titel

Synthesis of Graphene Nanoribbons by Ambient-Pressure Chemical Vapor Deposition and Device Integration

Sub types

Article

Ausgabe der Zeitschrift

138

Data source: Web of Science (Lite)

Autoren

Zongping Chen
Wen Zhang
Carlos-Andres Palma
Alberto Lodi Rizzini
Bilu Liu
Ahmad Abbas
Nils Richter
Leonardo Martini
Xiao-Ye Wang
Nicola Cavani
Hao Lu
Neeraj Mishra
Camilla Coletti
Reinhard Berger
Florian Klappenberger
Mathias Kläui
Andrea Candini
Marco Affronte
Chongwu Zhou
Valentina De Renzi
Umberto del Pennino
Johannes V Barth
Hans Joachim Räder
Akimitsu Narita
Xinliang Feng
Klaus Müllen

DOI

10.1021/jacs.6b10374

eISSN

1520-5126

ISSN

0002-7863

Ausgabe der Veröffentlichung

47

Zeitschrift

Journal of the American Chemical Society

Sprache

en

Online publication date

2016

Paginierung

15488 - 15496

Datum der Veröffentlichung

2016

Status

Published

Herausgeber

American Chemical Society (ACS)

Herausgeber URL

http://dx.doi.org/10.1021/jacs.6b10374

Datum der Datenerfassung

2023

Titel

Synthesis of Graphene Nanoribbons by Ambient-Pressure Chemical Vapor Deposition and Device Integration

Ausgabe der Zeitschrift

138

Data source: Crossref

Abstract

Graphene nanoribbons (GNRs), quasi-one-dimensional graphene strips, have shown great potential for nanoscale electronics, optoelectronics, and photonics. Atomically precise GNRs can be "bottom-up" synthesized by surface-assisted assembly of molecular building blocks under ultra-high-vacuum conditions. However, large-scale and efficient synthesis of such GNRs at low cost remains a significant challenge. Here we report an efficient "bottom-up" chemical vapor deposition (CVD) process for inexpensive and high-throughput growth of structurally defined GNRs with varying structures under ambient-pressure conditions. The high quality of our CVD-grown GNRs is validated by a combination of different spectroscopic and microscopic characterizations. Facile, large-area transfer of GNRs onto insulating substrates and subsequent device fabrication demonstrate their promising potential as semiconducting materials, exhibiting high current on/off ratios up to 6000 in field-effect transistor devices. This value is 3 orders of magnitude higher than values reported so far for other thin-film transistors of structurally defined GNRs. Notably, on-surface mass spectrometry analyses of polymer precursors provide unprecedented evidence for the chemical structures of the resulting GNRs, especially the heteroatom doping and heterojunctions. These results pave the way toward the scalable and controllable growth of GNRs for future applications.

Addresses

Max Planck Institute for Polymer Research , Ackermannweg 10, D-55128 Mainz, Germany.

Autoren

Zongping Chen
Wen Zhang
Carlos-Andres Palma
Alberto Lodi Rizzini
Bilu Liu
Ahmad Abbas
Nils Richter
Leonardo Martini
Xiao-Ye Wang
Nicola Cavani
Hao Lu
Neeraj Mishra
Camilla Coletti
Reinhard Berger
Florian Klappenberger
Mathias Kläui
Andrea Candini
Marco Affronte
Chongwu Zhou
Valentina De Renzi
Umberto Del Pennino
Johannes V Barth
Hans Joachim Räder
Akimitsu Narita
Xinliang Feng
Klaus Müllen

DOI

10.1021/jacs.6b10374

eISSN

1520-5126

Externe Identifier

PubMed Identifier: 27933922

Funding acknowledgements

Ministero dell?Istruzione, dell?Universit? e della Ricerca: RBFR13YKWX
European Research Council:
European Commission: 610449
Deutsche Forschungsgemeinschaft: SPP 1459
Office of Naval Research:
European Commission: 604391
Ministero dell?Istruzione, dell?Universit? e della Ricerca: 20105ZZTSE_008
Alexander von Humboldt-Stiftung:

Open access

false

ISSN

0002-7863

Ausgabe der Veröffentlichung

47

Zeitschrift

Journal of the American Chemical Society

Sprache

eng

Medium

Print-Electronic

Online publication date

2016

Paginierung

15488 - 15496

Datum der Veröffentlichung

2016

Status

Published

Datum der Datenerfassung

2016

Titel

Synthesis of Graphene Nanoribbons by Ambient-Pressure Chemical Vapor Deposition and Device Integration.

Sub types

Research Support, Non-U.S. Gov't
Journal Article

Ausgabe der Zeitschrift

138

Data source: Europe PubMed Central

Abstract

Graphene nanoribbons (GNRs), quasi-one-dimensional graphene strips, have shown great potential for nanoscale electronics, optoelectronics, and photonics. Atomically precise GNRs can be "bottom-up" synthesized by surface-assisted assembly of molecular building blocks under ultra-high-vacuum conditions. However, large-scale and efficient synthesis of such GNRs at low cost remains a significant challenge. Here we report an efficient "bottom-up" chemical vapor deposition (CVD) process for inexpensive and high-throughput growth of structurally defined GNRs with varying structures under ambient-pressure conditions. The high quality of our CVD-grown GNRs is validated by a combination of different spectroscopic and microscopic characterizations. Facile, large-area transfer of GNRs onto insulating substrates and subsequent device fabrication demonstrate their promising potential as semiconducting materials, exhibiting high current on/off ratios up to 6000 in field-effect transistor devices. This value is 3 orders of magnitude higher than values reported so far for other thin-film transistors of structurally defined GNRs. Notably, on-surface mass spectrometry analyses of polymer precursors provide unprecedented evidence for the chemical structures of the resulting GNRs, especially the heteroatom doping and heterojunctions. These results pave the way toward the scalable and controllable growth of GNRs for future applications.

Autoren

Zongping Chen
Wen Zhang
Carlos-Andres Palma
Alberto Lodi Rizzini
Bilu Liu
Ahmad Abbas
Nils Richter
Leonardo Martini
Xiao-Ye Wang
Nicola Cavani
Hao Lu
Neeraj Mishra
Camilla Coletti
Reinhard Berger
Florian Klappenberger
Mathias Kläui
Andrea Candini
Marco Affronte
Chongwu Zhou
Valentina De Renzi
Umberto Del Pennino
Johannes V Barth
Hans Joachim Räder
Akimitsu Narita
Xinliang Feng
Klaus Müllen

Autoren-URL

https://www.ncbi.nlm.nih.gov/pubmed/27933922

DOI

10.1021/jacs.6b10374

eISSN

1520-5126

Ausgabe der Veröffentlichung

47

Zeitschrift

J Am Chem Soc

Sprache

eng

Country

United States

Paginierung

15488 - 15496

Datum der Veröffentlichung

2016

Status

Published

Datum, an dem der Datensatz öffentlich gemacht wurde

2018

Titel

Synthesis of Graphene Nanoribbons by Ambient-Pressure Chemical Vapor Deposition and Device Integration.

Sub types

Journal Article
Research Support, Non-U.S. Gov't

Ausgabe der Zeitschrift

138

Data source: PubMed

Synthesis of graphene nanoribbons by ambient-pressure chemical vapor deposition and device integration

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