Thiomolybdate Clusters: From Homogeneous Catalysis to Heterogenization and Active Sites
- Publication type:
- Journal article
- Metadata:
-
- Autoren
- Samar Batool
- Marcel Langer
- Stephen Nagaraju Myakala
- Magdalena Heiland
- Dominik Eder
- Carsten Streb
- Alexey Cherevan
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:001120856600001&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1002/adma.202305730
- eISSN
- 1521-4095
- Externe Identifier
- Clarivate Analytics Document Solution ID: LV5K0
- PubMed Identifier: 37899494
- ISSN
- 0935-9648
- Ausgabe der Veröffentlichung
- 7
- Zeitschrift
- ADVANCED MATERIALS
- Schlüsselwörter
- electrocatalysis
- heterogenization
- hydrogen evolution
- molybdenum sulfide
- photocatalysis
- thiomolybdate
- Datum der Veröffentlichung
- 2024
- Status
- Published
- Titel
- Thiomolybdate Clusters: From Homogeneous Catalysis to Heterogenization and Active Sites
- Sub types
- Review
- Ausgabe der Zeitschrift
- 36
Data source: Web of Science (Lite)
- Other metadata sources:
-
- Abstract
- <jats:title>Abstract</jats:title><jats:p>Thiomolybdates are molecular molybdenum‐sulfide clusters formed from Mo centers and sulfur‐based ligands. For decades, they have attracted the interest of synthetic chemists due to their unique structures and their relevance in biological systems, e.g., as reactive sites in enzymes. More recently, thiomolybdates are explored from the catalytic point of view and applied as homogeneous and molecular mimics of heterogeneous molybdenum sulfide catalysts. This review summarizes prominent examples of thiomolybdate‐based electro‐ and photocatalysis and provides a comprehensive analysis of their reactivities under homogeneous and heterogenized conditions. Active sites of thiomolybdates relevant for the hydrogen evolution reaction are examined, aiming to shed light on the link between cluster structure and performance. The shift from solution‐phase to surface‐supported thiomolybdates is discussed with a focus on applications in electrocatalysis and photocatalysis. The outlook highlights current trends and emerging areas of thiomolybdate research, ending with a summary of challenges and key takeaway messages based on the state‐of‐the‐art research.</jats:p>
- Autoren
- Samar Batool
- Marcel Langer
- Stephen Nagaraju Myakala
- Magdalena Heiland
- Dominik Eder
- Carsten Streb
- Alexey Cherevan
- DOI
- 10.1002/adma.202305730
- eISSN
- 1521-4095
- ISSN
- 0935-9648
- Ausgabe der Veröffentlichung
- 7
- Zeitschrift
- Advanced Materials
- Sprache
- en
- Online publication date
- 2023
- Datum der Veröffentlichung
- 2024
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/adma.202305730
- Datum der Datenerfassung
- 2024
- Titel
- Thiomolybdate Clusters: From Homogeneous Catalysis to Heterogenization and Active Sites
- Ausgabe der Zeitschrift
- 36
Data source: Crossref
- Abstract
- Thiomolybdates are molecular molybdenum-sulfide clusters formed from Mo centers and sulfur-based ligands. For decades, they have attracted the interest of synthetic chemists due to their unique structures and their relevance in biological systems, e.g., as reactive sites in enzymes. More recently, thiomolybdates are explored from the catalytic point of view and applied as homogeneous and molecular mimics of heterogeneous molybdenum sulfide catalysts. This review summarizes prominent examples of thiomolybdate-based electro- and photocatalysis and provides a comprehensive analysis of their reactivities under homogeneous and heterogenized conditions. Active sites of thiomolybdates relevant for the hydrogen evolution reaction are examined, aiming to shed light on the link between cluster structure and performance. The shift from solution-phase to surface-supported thiomolybdates is discussed with a focus on applications in electrocatalysis and photocatalysis. The outlook highlights current trends and emerging areas of thiomolybdate research, ending with a summary of challenges and key takeaway messages based on the state-of-the-art research.
- Addresses
- Institute of Materials Chemistry, TU Wien, Getreidemarkt 9/BC/02, Vienna, 1060, Austria.
- Autoren
- Samar Batool
- Marcel Langer
- Stephen Nagaraju Myakala
- Magdalena Heiland
- Dominik Eder
- Carsten Streb
- Alexey Cherevan
- DOI
- 10.1002/adma.202305730
- eISSN
- 1521-4095
- Externe Identifier
- PubMed Identifier: 37899494
- Funding acknowledgements
- Ministeriums für Wissenschaft, Weiterbildung und Kultur, Rheinland-Pfalz:
- Deutsche Forschungsgemeinschaft: 364549901
- Johannes Gutenberg University Mainz:
- Johannes Gutenberg-Universität Mainz:
- Alexander von Humboldt-Stiftung:
- Austrian Science Fund FWF: P32801
- Open access
- false
- ISSN
- 0935-9648
- Ausgabe der Veröffentlichung
- 7
- Zeitschrift
- Advanced materials (Deerfield Beach, Fla.)
- Sprache
- eng
- Medium
- Print-Electronic
- Online publication date
- 2023
- Paginierung
- e2305730
- Datum der Veröffentlichung
- 2024
- Status
- Published
- Publisher licence
- CC BY
- Datum der Datenerfassung
- 2023
- Titel
- Thiomolybdate Clusters: From Homogeneous Catalysis to Heterogenization and Active Sites.
- Sub types
- Review
- Journal Article
- Ausgabe der Zeitschrift
- 36
Data source: Europe PubMed Central
- Abstract
- Thiomolybdates are molecular molybdenum-sulfide clusters formed from Mo centers and sulfur-based ligands. For decades, they have attracted the interest of synthetic chemists due to their unique structures and their relevance in biological systems, e.g., as reactive sites in enzymes. More recently, thiomolybdates are explored from the catalytic point of view and applied as homogeneous and molecular mimics of heterogeneous molybdenum sulfide catalysts. This review summarizes prominent examples of thiomolybdate-based electro- and photocatalysis and provides a comprehensive analysis of their reactivities under homogeneous and heterogenized conditions. Active sites of thiomolybdates relevant for the hydrogen evolution reaction are examined, aiming to shed light on the link between cluster structure and performance. The shift from solution-phase to surface-supported thiomolybdates is discussed with a focus on applications in electrocatalysis and photocatalysis. The outlook highlights current trends and emerging areas of thiomolybdate research, ending with a summary of challenges and key takeaway messages based on the state-of-the-art research.
- Autoren
- Samar Batool
- Marcel Langer
- Stephen Nagaraju Myakala
- Magdalena Heiland
- Dominik Eder
- Carsten Streb
- Alexey Cherevan
- Autoren-URL
- https://www.ncbi.nlm.nih.gov/pubmed/37899494
- DOI
- 10.1002/adma.202305730
- eISSN
- 1521-4095
- Funding acknowledgements
- Austrian Science Fund: P32801
- Deutsche Forschungsgemeinschaft: 364549901
- Johannes Gutenberg University Mainz:
- Alexander von Humboldt-Stiftung:
- Ministeriums für Wissenschaft, Weiterbildung und Kultur, Rheinland-Pfalz:
- Ausgabe der Veröffentlichung
- 7
- Zeitschrift
- Adv Mater
- Schlüsselwörter
- electrocatalysis
- heterogenization
- hydrogen evolution
- molybdenum sulfide
- photocatalysis
- thiomolybdate
- Sprache
- eng
- Country
- Germany
- Paginierung
- e2305730
- Datum der Veröffentlichung
- 2024
- Status
- Published
- Titel
- Thiomolybdate Clusters: From Homogeneous Catalysis to Heterogenization and Active Sites.
- Sub types
- Journal Article
- Review
- Ausgabe der Zeitschrift
- 36
Data source: PubMed
- Author's licence
- CC-BY
- Autoren
- Samar Batool
- Marcel Langer
- Stephen Nagaraju Myakala
- Magdalena Heiland
- Dominik Eder
- Carsten Streb
- Alexey Cherevan
- Hosting institution
- Universitätsbibliothek Mainz
- Sammlungen
- DFG-491381577-H
- Resource version
- Published version
- DOI
- 10.1002/adma.202305730
- File(s) embargoed
- false
- Open access
- true
- ISSN
- 1521-4095
- Zeitschrift
- Advanced materials
- Schlüsselwörter
- 540 Chemie
- 540 Chemistry and allied sciences
- Sprache
- eng
- Open access status
- Open Access
- Paginierung
- 2305730
- Datum der Veröffentlichung
- 2023
- Public URL
- https://openscience.ub.uni-mainz.de/handle/20.500.12030/9769
- Herausgeber
- Wiley-VCH
- Datum der Datenerfassung
- 2023
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2023
- Zugang
- Public
- Titel
- Thiomolybdate clusters: from homogeneous catalysis to heterogenization and active sites
- Ausgabe der Zeitschrift
- Version of Record (VoR)
Files
thiomolybdate_clusters__from_-20231205120926326.pdf
Data source: OPENSCIENCE.UB
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