Sustainably Scaled Electrochemical Synthesis of 3‐Propyladipic Acid in Line with Fluctuating Grid Supply
- Publication type:
- Journal article
- Metadata:
-
- Abstract
- <jats:title>Abstract</jats:title><jats:p>Chemical production is a significant contributor to global climate change, which expedites the growing demand for transitioning to more sustainable and climate‐friendly methodologies. Ideally this should include high compatibility with the fluctuating electricity supply which results from renewable energy sources in the electrical grid. Here we show an electrochemical path for the 3‐propyladipic acid synthesis from 4‐propylcyclohexanol implementing a semi‐technical electrochemical continuously stirred tank reactor. Following a <jats:italic>Design of Experiments</jats:italic> approach, we found a strong influence of the biphasic electrolyte mixing and the continuous feeding in of the substrate. By switching to an electrolyte recirculation mode and efficient mixing, the isolated product yield could be increased up to 31 % for a 10 L total reaction volume, indicating the potential for further scale‐up into the technical range. This reaction proceeds while forming several by‐products, which have not been fully described yet. A proposal for the formation mechanism is included.</jats:p>
- Autoren
- Roland J‐R Bednarz
- Pilar Jiménez‐Meneses
- Annika S Gold
- Damián Monllor‐Satoca
- Andreas Stenglein
- Roberto Gómez
- Siegfried R Waldvogel
- DOI
- 10.1002/cctc.202300606
- eISSN
- 1867-3899
- ISSN
- 1867-3880
- Ausgabe der Veröffentlichung
- 17
- Zeitschrift
- ChemCatChem
- Sprache
- en
- Online publication date
- 2023
- Datum der Veröffentlichung
- 2023
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/cctc.202300606
- Datum der Datenerfassung
- 2023
- Titel
- Sustainably Scaled Electrochemical Synthesis of 3‐Propyladipic Acid in Line with Fluctuating Grid Supply
- Ausgabe der Zeitschrift
- 15
Data source: Crossref
- Other metadata sources:
-
- Author's licence
- CC-BY
- Autoren
- Roland J-R Bednarz
- Pilar Jiménez-Meneses
- Annika S Gold
- Damián Monllor-Satoca
- Andreas Stenglein
- Roberto Gómez
- Siegfried R Waldvogel
- Hosting institution
- Universitätsbibliothek Mainz
- Sammlungen
- DFG-491381577-H
- Resource version
- Published version
- DOI
- 10.1002/cctc.202300606
- Funding acknowledgements
- Deutsche Forschungsgemeinschaft (DFG)|491381577|Open-Access-Publikationskosten 2022–2024 Universität Mainz - Universitätsmedizin
- File(s) embargoed
- false
- Open access
- true
- ISSN
- 1867-3899
- Ausgabe der Veröffentlichung
- 17
- Zeitschrift
- ChemCatChem
- Schlüsselwörter
- 540 Chemie
- 540 Chemistry and allied sciences
- Sprache
- eng
- Open access status
- Open Access
- Paginierung
- e202300606
- Datum der Veröffentlichung
- 2023
- Public URL
- https://openscience.ub.uni-mainz.de/handle/20.500.12030/9524
- Herausgeber
- Wiley-VCH
- Datum der Datenerfassung
- 2023
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2023
- Zugang
- Public
- Titel
- Sustainably scaled electrochemical synthesis of 3-propyladipic acid in line with fluctuating grid supply
- Ausgabe der Zeitschrift
- 15
Files
sustainably_scaled_electroche-20230914112046960.pdf
Data source: OPENSCIENCE.UB