Topochemical polymerization in self-assembled rodlike micelles of bisurea bolaamphiphiles

Publication type:
Journal article
Metadata:
Autoren
  • Asish Pal
  • Panayiotis Voudouris
  • Marcel ME Koenigs
  • Pol Besenius
  • Hans M Wyss
  • Volkan Degirmenci
  • Rint P Sijbesma
Autoren-URL
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000330118800004&DestLinkType=FullRecord&DestApp=WOS_CPL
DOI
10.1039/c3sm52605d
eISSN
1744-6848
Externe Identifier
  • Clarivate Analytics Document Solution ID: 295LY
  • PubMed Identifier: 24983103
ISSN
1744-683X
Ausgabe der Veröffentlichung
7
Zeitschrift
SOFT MATTER
Paginierung
952 - 956
Datum der Veröffentlichung
2014
Status
Published
Titel
Topochemical polymerization in self-assembled rodlike micelles of bisurea bolaamphiphiles
Sub types
  • Article
Ausgabe der Zeitschrift
10

Data source: Web of Science (Lite)

Other metadata sources:
Autoren
  • Asish Pal
  • Panayiotis Voudouris
  • Marcel ME Koenigs
  • Pol Besenius
  • Hans M Wyss
  • Volkan Degirmenci
  • Rint P Sijbesma
DOI
10.1039/c3sm52605d
eISSN
1744-6848
ISSN
1744-683X
Ausgabe der Veröffentlichung
7
Zeitschrift
Soft Matter
Sprache
en
Paginierung
952 - 952
Datum der Veröffentlichung
2014
Status
Published
Herausgeber
Royal Society of Chemistry (RSC)
Herausgeber URL
http://dx.doi.org/10.1039/c3sm52605d
Datum der Datenerfassung
2024
Titel
Topochemical polymerization in self-assembled rodlike micelles of bisurea bolaamphiphiles
Ausgabe der Zeitschrift
10

Data source: Crossref

Abstract
Rod-like micelles, formed from bolaamphiphiles with oligo(ethylene oxide) hydrophilic outer segments and a hydrophobic segment with diacetylene flanked by two urea moieties, were covalently fixated by topochemical photopolymerization to high degrees of polymerization by optimizing the hydrophobic core and the hydrophilic periphery of the bolaamphiphiles. Analysis of the polymerized product with dynamic light scattering in chloroform showed degrees of polymerization of approximately 250. Cryo-TEMof bolaamphiphiles before and after UV irradiation showed that the morphology of the rods was conserved upon topochemical polymerization.
Autoren
  • Asish Pal
  • Panayiotis Voudouris
  • Marcel ME Koenigs
  • Pol Besenius
  • Hans M Wyss
  • Volkan Degirmenci
  • Rint P Sijbesma
DOI
10.1039/c3sm52605d
eISSN
1744-6848
Externe Identifier
  • PubMed Identifier: 24983103
Open access
false
ISSN
1744-683X
Ausgabe der Veröffentlichung
7
Zeitschrift
Soft matter
Sprache
eng
Medium
Print
Paginierung
952 - 956
Datum der Veröffentlichung
2014
Status
Published
Datum der Datenerfassung
2014
Titel
Topochemical polymerization in self-assembled rodlike micelles of bisurea bolaamphiphiles.
Sub types
  • Research Support, Non-U.S. Gov't
  • Journal Article
Ausgabe der Zeitschrift
10

Data source: Europe PubMed Central

Abstract
Rod-like micelles, formed from bolaamphiphiles with oligo(ethylene oxide) hydrophilic outer segments and a hydrophobic segment with diacetylene flanked by two urea moieties, were covalently fixated by topochemical photopolymerization to high degrees of polymerization by optimizing the hydrophobic core and the hydrophilic periphery of the bolaamphiphiles. Analysis of the polymerized product with dynamic light scattering in chloroform showed degrees of polymerization of approximately 250. Cryo-TEMof bolaamphiphiles before and after UV irradiation showed that the morphology of the rods was conserved upon topochemical polymerization.
Autoren
  • Asish Pal
  • Panayiotis Voudouris
  • Marcel ME Koenigs
  • Pol Besenius
  • Hans M Wyss
  • Volkan Degirmenci
  • Rint P Sijbesma
Autoren-URL
https://www.ncbi.nlm.nih.gov/pubmed/24983103
DOI
10.1039/c3sm52605d
eISSN
1744-6848
Ausgabe der Veröffentlichung
7
Zeitschrift
Soft Matter
Sprache
eng
Country
England
Paginierung
952 - 956
Datum der Veröffentlichung
2014
Status
Published
Datum, an dem der Datensatz öffentlich gemacht wurde
2015
Titel
Topochemical polymerization in self-assembled rodlike micelles of bisurea bolaamphiphiles.
Sub types
  • Journal Article
  • Research Support, Non-U.S. Gov't
Ausgabe der Zeitschrift
10

Data source: PubMed

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