Anodic Dehydrogenative Cyanamidation of Thioethers: Simple and Sustainable Synthesis of N‐Cyanosulfilimines
- Publication type:
- Journal article
- Metadata:
-
- Abstract
- <jats:title>Abstract</jats:title><jats:p>A novel and very simple to perform electrochemical approach for the synthesis of several N‐cyanosulfilimines in good to excellent yields was established. This method provides access to biologically relevant sulfoximines by consecutive oxidation using electro‐generated periodate. This route can be easily scaled‐up to gram quantities. The S,N coupling is carried out at an inexpensive carbon anode by direct oxidation of sulfide. Therefore, the designed process is atom economic and represents a new “green route” for the synthesis of sulfilimines and sulfoximines.</jats:p>
- Autoren
- Martin Klein
- Siegfried R Waldvogel
- DOI
- 10.1002/anie.202109033
- eISSN
- 1521-3773
- ISSN
- 1433-7851
- Ausgabe der Veröffentlichung
- 43
- Zeitschrift
- Angewandte Chemie International Edition
- Sprache
- en
- Online publication date
- 2021
- Paginierung
- 23197 - 23201
- Datum der Veröffentlichung
- 2021
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/anie.202109033
- Datum der Datenerfassung
- 2023
- Titel
- Anodic Dehydrogenative Cyanamidation of Thioethers: Simple and Sustainable Synthesis of <i>N</i>‐Cyanosulfilimines
- Ausgabe der Zeitschrift
- 60
Data source: Crossref
- Other metadata sources:
-
- Author's licence
- CC-BY-NC-ND
- Autoren
- Martin Klein
- Siegfried R Waldvogel
- Hosting institution
- Universitätsbibliothek Mainz
- Sammlungen
- JGU-Publikationen
- Resource version
- Published version
- DOI
- 10.1002/anie.202109033
- File(s) embargoed
- false
- Open access
- true
- ISSN
- 1521-3773
- Ausgabe der Veröffentlichung
- 43
- Zeitschrift
- Angewandte Chemie : international edition
- Schlüsselwörter
- 540 Chemie
- 540 Chemistry and allied sciences
- Sprache
- eng
- Open access status
- Open Access
- Paginierung
- 23197 - 23201
- Datum der Veröffentlichung
- 2021
- Public URL
- https://openscience.ub.uni-mainz.de/handle/20.500.12030/8052
- Herausgeber
- Wiley-VCH
- Datum der Datenerfassung
- 2022
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2022
- Zugang
- Public
- Titel
- Anodic dehydrogenative cyanamidation of thioethers : simple and sustainable synthesis of N-cyanosulfilimines
- Ausgabe der Zeitschrift
- 60
Files
anodic_dehydrogenative_cyanam-20221014171537800.pdf
Data source: OPENSCIENCE.UB