High Proton‐Conductivity in Covalently Linked Polyoxometalate‐Organoboronic Acid‐Polymers
- Publication type:
- Journal article
- Metadata:
-
- Abstract
- <jats:title>Abstract</jats:title><jats:p>The controlled bottom‐up design of polymers with metal oxide backbones is a grand challenge in materials design, as it could give unique control over the resulting chemical properties. Herein, we report a 1D‐organo‐functionalized polyoxometalate polymer featuring a purely inorganic backbone. The polymer is self‐assembled from two types of monomers, inorganic Wells–Dawson‐type polyoxometalates, and aromatic organo‐boronates. Their covalent linkage results in 1D polymer strands, which combine an inorganic oxide backbone (based on B−O and Nb−O linkages) with functional organic side‐chains. The polymer shows high bulk proton conductivity of up to 1.59×10<jats:sup>−1</jats:sup> S cm<jats:sup>−1</jats:sup> at 90 °C and 98 % relative humidity. This synthetic approach could lead to a new class of organic–inorganic polymers where function can be designed by controlled tuning of the monomer units.</jats:p>
- Autoren
- Shujun Li
- Yue Zhao
- Sebastian Knoll
- Rongji Liu
- Gang Li
- Qingpo Peng
- Pengtao Qiu
- Danfeng He
- Carsten Streb
- Xuenian Chen
- DOI
- 10.1002/ange.202104886
- eISSN
- 1521-3757
- ISSN
- 0044-8249
- Ausgabe der Veröffentlichung
- 31
- Zeitschrift
- Angewandte Chemie
- Sprache
- en
- Online publication date
- 2021
- Paginierung
- 17090 - 17094
- Datum der Veröffentlichung
- 2021
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/ange.202104886
- Datum der Datenerfassung
- 2023
- Titel
- High Proton‐Conductivity in Covalently Linked Polyoxometalate‐Organoboronic Acid‐Polymers
- Ausgabe der Zeitschrift
- 133
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