A General Access Route to High-Nuclearity, Metal-Functionalized Molecular Vanadium Oxides
- Publication type:
- Journal article
- Metadata:
-
- Autoren
- Simon Greiner
- Jan Hettig
- Alec Laws
- Katharina Baumgaertner
- Jenna Bustos
- Ann-Christin Poeppler
- Adam H Clark
- May Nyman
- Carsten Streb
- Montaha Anjass
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000744444200001&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1002/anie.202114548
- eISSN
- 1521-3773
- Externe Identifier
- Clarivate Analytics Document Solution ID: 0D4ZK
- PubMed Identifier: 34936179
- ISSN
- 1433-7851
- Ausgabe der Veröffentlichung
- 9
- Zeitschrift
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Schlüsselwörter
- Polyoxometalate
- Self-assembly
- Supramolecular
- Synthesis
- Vanadium oxide
- Artikelnummer
- ARTN e202114548
- Datum der Veröffentlichung
- 2022
- Status
- Published
- Titel
- A General Access Route to High-Nuclearity, Metal-Functionalized Molecular Vanadium Oxides
- Sub types
- Article
- Ausgabe der Zeitschrift
- 61
Data source: Web of Science (Lite)
- Other metadata sources:
-
- Abstract
- <jats:title>Abstract</jats:title><jats:p>Molecular metal oxides are key materials in diverse fields like energy storage and conversion, molecular magnetism and as model systems for solid‐state metal oxides. To improve their performance and increase the variety of accessible motifs, new synthetic approaches are necessary. Herein, we report a universal, new precursor to access different metal‐functionalized polyoxovanadate (POV) clusters. The precursor is synthesized by a novel solid‐state thermal treatment procedure. Solution‐phase test reactions at room temperature and pressure show that reaction of the precursor with various metal nitrate salts gives access to a range of metal‐functionalized POVs. The first nitrate‐templated molecular calcium vanadate cluster is reported. We show that this precursor could open new access routes to POV components for molecular magnetism, energy technologies or catalysis.</jats:p>
- Autoren
- Simon Greiner
- Jan Hettig
- Alec Laws
- Katharina Baumgärtner
- Jenna Bustos
- Ann‐Christin Pöppler
- Adam H Clark
- May Nyman
- Carsten Streb
- Montaha Anjass
- DOI
- 10.1002/anie.202114548
- eISSN
- 1521-3773
- ISSN
- 1433-7851
- Ausgabe der Veröffentlichung
- 9
- Zeitschrift
- Angewandte Chemie International Edition
- Sprache
- en
- Online publication date
- 2022
- Datum der Veröffentlichung
- 2022
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/anie.202114548
- Datum der Datenerfassung
- 2023
- Titel
- A General Access Route to High‐Nuclearity, Metal‐Functionalized Molecular Vanadium Oxides
- Ausgabe der Zeitschrift
- 61
Data source: Crossref
- Abstract
- Molecular metal oxides are key materials in diverse fields like energy storage and conversion, molecular magnetism and as model systems for solid-state metal oxides. To improve their performance and increase the variety of accessible motifs, new synthetic approaches are necessary. Herein, we report a universal, new precursor to access different metal-functionalized polyoxovanadate (POV) clusters. The precursor is synthesized by a novel solid-state thermal treatment procedure. Solution-phase test reactions at room temperature and pressure show that reaction of the precursor with various metal nitrate salts gives access to a range of metal-functionalized POVs. The first nitrate-templated molecular calcium vanadate cluster is reported. We show that this precursor could open new access routes to POV components for molecular magnetism, energy technologies or catalysis.
- Addresses
- Institute of Inorganic Chemistry I, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.
- Autoren
- Simon Greiner
- Jan Hettig
- Alec Laws
- Katharina Baumgärtner
- Jenna Bustos
- Ann-Christin Pöppler
- Adam H Clark
- May Nyman
- Carsten Streb
- Montaha Anjass
- DOI
- 10.1002/anie.202114548
- eISSN
- 1521-3773
- Externe Identifier
- PubMed Identifier: 34936179
- PubMed Central ID: PMC9302674
- Funding acknowledgements
- Helmholtz-Gemeinschaft:
- Alexander von Humboldt-Stiftung:
- Baden-Württemberg Stiftung:
- European Research Council: 101002212
- Deutsche Forschungsgemeinschaft: STR1164/12; STR1164/14; 364549901; 390874152
- Ministerium für Wissenschaft, Forschung und Kunst Baden-Württemberg:
- Open access
- true
- ISSN
- 1433-7851
- Ausgabe der Veröffentlichung
- 9
- Zeitschrift
- Angewandte Chemie (International ed. in English)
- Sprache
- eng
- Medium
- Print-Electronic
- Online publication date
- 2022
- Open access status
- Open Access
- Paginierung
- e202114548
- Datum der Veröffentlichung
- 2022
- Status
- Published
- Publisher licence
- CC BY
- Datum der Datenerfassung
- 2021
- Titel
- A General Access Route to High-Nuclearity, Metal-Functionalized Molecular Vanadium Oxides.
- Sub types
- research-article
- Journal Article
- Ausgabe der Zeitschrift
- 61
Files
https://www.dora.lib4ri.ch/psi/islandora/object/psi%3A40808/datastream/PDF/Greiner-2022-A_general_access_route_to-%28published_version%29.pdf https://europepmc.org/articles/PMC9302674?pdf=render
Data source: Europe PubMed Central
- Abstract
- Molecular metal oxides are key materials in diverse fields like energy storage and conversion, molecular magnetism and as model systems for solid-state metal oxides. To improve their performance and increase the variety of accessible motifs, new synthetic approaches are necessary. Herein, we report a universal, new precursor to access different metal-functionalized polyoxovanadate (POV) clusters. The precursor is synthesized by a novel solid-state thermal treatment procedure. Solution-phase test reactions at room temperature and pressure show that reaction of the precursor with various metal nitrate salts gives access to a range of metal-functionalized POVs. The first nitrate-templated molecular calcium vanadate cluster is reported. We show that this precursor could open new access routes to POV components for molecular magnetism, energy technologies or catalysis.
- Autoren
- Simon Greiner
- Jan Hettig
- Alec Laws
- Katharina Baumgärtner
- Jenna Bustos
- Ann-Christin Pöppler
- Adam H Clark
- May Nyman
- Carsten Streb
- Montaha Anjass
- Autoren-URL
- https://www.ncbi.nlm.nih.gov/pubmed/34936179
- DOI
- 10.1002/anie.202114548
- eISSN
- 1521-3773
- Externe Identifier
- PubMed Central ID: PMC9302674
- Funding acknowledgements
- Deutsche Forschungsgemeinschaft: STR1164/12; STR1164/14; 364549901; 390874152
- Ministerium für Wissenschaft, Forschung und Kunst Baden-Württemberg:
- Alexander von Humboldt-Stiftung:
- Helmholtz-Gemeinschaft:
- Baden-Württemberg Stiftung:
- European Research Council: 101002212
- Ausgabe der Veröffentlichung
- 9
- Zeitschrift
- Angew Chem Int Ed Engl
- Schlüsselwörter
- Polyoxometalate
- Self-assembly
- Supramolecular
- Synthesis
- Vanadium oxide
- Sprache
- eng
- Country
- Germany
- Paginierung
- e202114548
- Datum der Veröffentlichung
- 2022
- Status
- Published
- Titel
- A General Access Route to High-Nuclearity, Metal-Functionalized Molecular Vanadium Oxides.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 61
Data source: PubMed
- Beziehungen:
- Property of