Synthesis and Unusual NMR-Spectroscopic Behavior of a Strained Bicyclic Ammonium Salt
- Publication type:
- Journal article
- Metadata:
-
- Autoren
- Stefan Pusch
- Dieter Schollmeyer
- Till Opatz
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000427473000002&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1002/ejoc.201701594
- eISSN
- 1099-0690
- Externe Identifier
- Clarivate Analytics Document Solution ID: FZ3FV
- ISSN
- 1434-193X
- Ausgabe der Veröffentlichung
- 10
- Zeitschrift
- EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
- Schlüsselwörter
- Density functional calculations
- NMR spectroscopy
- Photochemistry
- Strained molecules
- Nitrogen heterocycles
- Paginierung
- 1204 - 1207
- Datum der Veröffentlichung
- 2018
- Status
- Published
- Titel
- Synthesis and Unusual NMR-Spectroscopic Behavior of a Strained Bicyclic Ammonium Salt
- Sub types
- Article
- Ausgabe der Zeitschrift
- 2018
Data source: Web of Science (Lite)
- Other metadata sources:
-
- Abstract
- <jats:p>The first synthesis of a 2‐azabicyclo[2.2.0]hexenium salt is described. It is available from pyridine in four steps. This strained bicyclic ammonium salt was characterized by <jats:sup>1</jats:sup>H, <jats:sup>13</jats:sup>C, and 2D NMR spectroscopy as well as by XRD. Due to its unusual NMR spectroscopic characteristics, DFT calculations were performed to additionally support the proposed structure. The strained cation shows significant hyperconjugative stabilization.</jats:p>
- Autoren
- Stefan Pusch
- Dieter Schollmeyer
- Till Opatz
- DOI
- 10.1002/ejoc.201701594
- eISSN
- 1099-0690
- ISSN
- 1434-193X
- Ausgabe der Veröffentlichung
- 10
- Zeitschrift
- European Journal of Organic Chemistry
- Sprache
- en
- Online publication date
- 2018
- Paginierung
- 1204 - 1207
- Datum der Veröffentlichung
- 2018
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/ejoc.201701594
- Datum der Datenerfassung
- 2023
- Titel
- Synthesis and Unusual NMR‐Spectroscopic Behavior of a Strained Bicyclic Ammonium Salt
- Ausgabe der Zeitschrift
- 2018
Data source: Crossref
- Beziehungen:
- Property of