1,2-DIMETHOXYETHANE COMPLEXES OF MONCL3 AND WNCL3 - THE CRYSTAL-STRUCTURE OF [MONCL3-CENTER-DOT-DME]
- Publication type:
- Journal article
- Metadata:
-
- Autoren
- E RENTSCHLER
- K DEHNICKE
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:A1993MQ18400025&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1515/znb-1993-1225
- Externe Identifier
- Clarivate Analytics Document Solution ID: MQ184
- ISSN
- 0932-0776
- Ausgabe der Veröffentlichung
- 12
- Zeitschrift
- ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
- Schlüsselwörter
- DME COMPLEXES
- NITRIDE CHLORIDES OF MOLYBDENUM AND TUNGSTEN
- SYNTHESIS
- CRYSTAL STRUCTURE
- Paginierung
- 1841 - 1844
- Datum der Veröffentlichung
- 1993
- Status
- Published
- Titel
- 1,2-DIMETHOXYETHANE COMPLEXES OF MONCL3 AND WNCL3 - THE CRYSTAL-STRUCTURE OF [MONCL3-CENTER-DOT-DME]
- Sub types
- Note
- Ausgabe der Zeitschrift
- 48
Data source: Web of Science (Lite)
- Other metadata sources:
-
- Abstract
- <jats:p>The complexes [MoNCl<jats:sub>3</jats:sub>·DME] and [WNCl<jats:sub>3</jats:sub>·DME] (DME = 1,2-dimethoxyethane) have been prepared by the reaction of the nitride chlorides MNC1<jats:sub>3</jats:sub> with equimolar amounts of DME in CH<jats:sub>2</jats:sub>Cl<jats:sub>2</jats:sub> suspensions. They form orangered, moisture sensitive crystals, which are soluble in organic solvents. The molybdenum complex has been characterized by a crystal structure determination. Space group Pbca, Z = 8, structure solution with 1781 observed unique reflections, R = 0.031. Lattice dimensions at –60°C: a = 738.6(1), b = 1182.2(1), c = 2314.1(1) pm. [MoNCl<jats:sub>3</jats:sub>·DME] forms monomeric complexes with chelating DME molecules and Mo–O bond lengths of 215.4(4) and 247.4(4) pm, the longer one being in trans-position of the nitrido ligand. The MoN bond length of 163.3(5) pm suggests a triple bond.</jats:p>
- Autoren
- Eva Rentschler
- Kurt Dehnicke
- DOI
- 10.1515/znb-1993-1225
- eISSN
- 1865-7117
- ISSN
- 0932-0776
- Ausgabe der Veröffentlichung
- 12
- Zeitschrift
- Zeitschrift für Naturforschung B
- Sprache
- en
- Online publication date
- 2014
- Paginierung
- 1841 - 1844
- Datum der Veröffentlichung
- 1993
- Status
- Published
- Herausgeber
- Walter de Gruyter GmbH
- Herausgeber URL
- http://dx.doi.org/10.1515/znb-1993-1225
- Datum der Datenerfassung
- 2021
- Titel
- Notizen: 1,2-Dimethoxyethan-Komplexe von MoNCl<sub>3</sub> und WNCl<sub>3</sub>. Die Kristallstruktur von [MoNCl<sub>3</sub> · DME] / 1,2-Dimethoxyethane Complexes of MoNCl<sub>3</sub> and WNCl<sub>3</sub>. The Crystal Structure of [MoNCl<sub>3</sub> · DME]
- Ausgabe der Zeitschrift
- 48
Data source: Crossref
- Beziehungen:
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