A Discrete μ4-Oxido Tetranuclear Iron(III) Cluster
- Publication type:
- Journal article
- Metadata:
-
- Autoren
- Manas Sutradhar
- Luca M Carrella
- Eva Rentschler
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000308590000004&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1002/ejic.201200396
- eISSN
- 1099-0682
- Externe Identifier
- Clarivate Analytics Document Solution ID: 003EC
- ISSN
- 1434-1948
- Ausgabe der Veröffentlichung
- 27
- Zeitschrift
- EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
- Schlüsselwörter
- Tetranuclear Iron(III)
- Schiff bases
- X-ray diffraction
- Magnetic properties
- Cluster compounds
- Paginierung
- 4273 - 4278
- Datum der Veröffentlichung
- 2012
- Status
- Published
- Titel
- A Discrete μ4-Oxido Tetranuclear Iron(III) Cluster
- Sub types
- Article
Data source: Web of Science (Lite)
- Other metadata sources:
-
- Abstract
- <jats:title>Abstract</jats:title><jats:p>Reaction of a Schiff base ligand derived from salicyloyl hydrazide and diacetyl monooxime (H<jats:sub>2</jats:sub>L) with a triangular μ<jats:sub>3</jats:sub>‐oxido‐centered [Fe<jats:sub>3</jats:sub>(μ<jats:sub>3</jats:sub>‐O)]<jats:sup>7+</jats:sup> core yields a new tetranuclear iron(III) complex. Fe<jats:sup>III</jats:sup><jats:sub>4</jats:sub>(μ<jats:sub>4</jats:sub>‐O) crystallizes in the triclinic space group <jats:italic>P</jats:italic><jats:styled-content>$\bar {1}$<jats:inline-graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="graphic/tex2gif-ueqn-1.gif" xlink:title="equation image" /></jats:styled-content>. Structural studies reveal that this tetranuclear iron(III) complex is a new structure type of an uncharged (alkoxido)(oxido)iron(III) cluster in which the four iron(III) ions are located at the corners of a distorted tetrahedron. A study of the magnetic properties supports the presence of antiferromagnetic interactions through the central μ<jats:sub>4</jats:sub>‐oxido ion as well as the μ<jats:sub>2</jats:sub>‐methoxy groups present, giving an an <jats:italic>S</jats:italic> = 0 ground state. Mössbauer spectroscopy confirms the presence of high‐spin iron(III) ions in this complex.</jats:p>
- Autoren
- Manas Sutradhar
- Luca M Carrella
- Eva Rentschler
- DOI
- 10.1002/ejic.201200396
- eISSN
- 1099-0682
- ISSN
- 1434-1948
- Ausgabe der Veröffentlichung
- 27
- Zeitschrift
- European Journal of Inorganic Chemistry
- Sprache
- en
- Online publication date
- 2012
- Paginierung
- 4273 - 4278
- Datum der Veröffentlichung
- 2012
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/ejic.201200396
- Datum der Datenerfassung
- 2023
- Titel
- A Discrete μ<sub>4</sub>‐Oxido Tetranuclear Iron(III) Cluster
- Ausgabe der Zeitschrift
- 2012
Data source: Crossref
- Beziehungen:
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