A Click-Functionalized Single-Molecule Magnet Based on Cobalt(II) and Its Analogous Manganese(II) and Zinc(II) Compounds

Publication type:
Journal article
Metadata:
Autoren
  • Christian Plenk
  • Jasmin Krause
  • Eva Rentschler
Autoren-URL
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000349153500001&DestLinkType=FullRecord&DestApp=WOS_CPL
DOI
10.1002/ejic.201402955
eISSN
1099-0682
Externe Identifier
  • Clarivate Analytics Document Solution ID: CA8FS
ISSN
1434-1948
Ausgabe der Veröffentlichung
3
Zeitschrift
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Schlüsselwörter
  • Magnetic properties
  • Click chemistry
  • Cobalt
  • Azides
  • NMR spectroscopy
Paginierung
370 - 374
Datum der Veröffentlichung
2015
Status
Published
Titel
A Click-Functionalized Single-Molecule Magnet Based on Cobalt(II) and Its Analogous Manganese(II) and Zinc(II) Compounds
Sub types
  • Article

Data source: Web of Science (Lite)

Other metadata sources:
Abstract
<jats:title>Abstract</jats:title><jats:p>A mononuclear Co<jats:sup>II</jats:sup> single‐molecule magnet suitable for click chemistry was investigated. [M(oda)(aterpy)] complexes (oda<jats:sup>2–</jats:sup> = oxodiacetate, aterpy = 4′‐azido‐2,2′:6′,2″‐terpyridine) with M = Mn<jats:sup>II</jats:sup>, Zn<jats:sup>II</jats:sup>, and Co<jats:sup>II</jats:sup> were synthesized as azide‐functionalized building blocks for the copper‐catalyzed azide–alkyne cycloaddition reaction. The required structural integrity of the complexes in solution was proven in great detail by using ESI‐MS and NMR spectroscopy. For the six‐coordinate [Co(oda)(aterpy)] complex, single‐molecule magnet behavior was confirmed with an effective energy barrier of 4.2 cm<jats:sup>–1</jats:sup>.</jats:p>
Autoren
  • Christian Plenk
  • Jasmin Krause
  • Eva Rentschler
DOI
10.1002/ejic.201402955
eISSN
1099-0682
ISSN
1434-1948
Ausgabe der Veröffentlichung
3
Zeitschrift
European Journal of Inorganic Chemistry
Sprache
en
Online publication date
2014
Paginierung
370 - 374
Datum der Veröffentlichung
2015
Status
Published
Herausgeber
Wiley
Herausgeber URL
http://dx.doi.org/10.1002/ejic.201402955
Datum der Datenerfassung
2023
Titel
A Click‐Functionalized Single‐Molecule Magnet Based on Cobalt(II) and Its Analogous Manganese(II) and Zinc(II) Compounds
Ausgabe der Zeitschrift
2015

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