Conductive Fused Porphyrin Tapes on Sensitive Substrates by a Chemical Vapor Deposition Approach

Publication type:
Journal article
Metadata:
Autoren
  • Giuseppe Bengasi
  • Kamal Baba
  • Gilles Frache
  • Jessica Desport
  • Paul Gratia
  • Katja Heinze
  • Nicolas D Boscher
Autoren-URL
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000458828000040&DestLinkType=FullRecord&DestApp=WOS_CPL
DOI
10.1002/anie.201814034
eISSN
1521-3773
Externe Identifier
  • Clarivate Analytics Document Solution ID: HL6FA
  • PubMed Identifier: 30556943
ISSN
1433-7851
Ausgabe der Veröffentlichung
7
Zeitschrift
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Schlüsselwörter
  • chemical vapor deposition
  • oxidative coupling
  • polymerization
  • porphyrins
  • thin films
Paginierung
2103 - 2108
Datum der Veröffentlichung
2019
Status
Published
Titel
Conductive Fused Porphyrin Tapes on Sensitive Substrates by a Chemical Vapor Deposition Approach
Sub types
  • Article
Ausgabe der Zeitschrift
58

Data source: Web of Science (Lite)

Other metadata sources:
Abstract
<jats:title>Abstract</jats:title><jats:p>Oxidative polymerization of nickel(II) 5,15‐diphenyl porphyrin and nickel(II) 5,15‐bis(di‐3,5‐tert‐butylphenyl) porphyrin by oxidative chemical vapor deposition (oCVD) yields multiply fused porphyrin oligomers in thin film form. The oCVD technique enables one‐step formation, deposition, and p‐doping of conjugated poly(porphyrins) coatings without solvents or post‐treatments. The decisive reactions and side reactions during the oCVD process are shown by high‐resolution mass spectrometry. Owing to the highly conjugated structure of the fused tapes, the thin films exhibit an electrical conductivity of 3.6×10<jats:sup>−2</jats:sup> S cm<jats:sup>−1</jats:sup> and strong absorption in the visible to near‐infrared spectral region. The formation of smooth conjugated poly(porphyrins) coatings, even on sensitive substrates, is demonstrated by deposition and patterning on glass, silicon, and paper. Formation of conductive poly(porphyrins) thin films could enable the design of new optoelectronic devices using the oCVD approach.</jats:p>
Autoren
  • Giuseppe Bengasi
  • Kamal Baba
  • Gilles Frache
  • Jessica Desport
  • Paul Gratia
  • Katja Heinze
  • Nicolas D Boscher
DOI
10.1002/anie.201814034
eISSN
1521-3773
ISSN
1433-7851
Ausgabe der Veröffentlichung
7
Zeitschrift
Angewandte Chemie International Edition
Sprache
en
Online publication date
2019
Paginierung
2103 - 2108
Datum der Veröffentlichung
2019
Status
Published
Herausgeber
Wiley
Herausgeber URL
http://dx.doi.org/10.1002/anie.201814034
Datum der Datenerfassung
2023
Titel
Conductive Fused Porphyrin Tapes on Sensitive Substrates by a Chemical Vapor Deposition Approach
Ausgabe der Zeitschrift
58

Data source: Crossref

Abstract
Oxidative polymerization of nickel(II) 5,15-diphenyl porphyrin and nickel(II) 5,15-bis(di-3,5-tert-butylphenyl) porphyrin by oxidative chemical vapor deposition (oCVD) yields multiply fused porphyrin oligomers in thin film form. The oCVD technique enables one-step formation, deposition, and p-doping of conjugated poly(porphyrins) coatings without solvents or post-treatments. The decisive reactions and side reactions during the oCVD process are shown by high-resolution mass spectrometry. Owing to the highly conjugated structure of the fused tapes, the thin films exhibit an electrical conductivity of 3.6×10<sup>-2</sup>  S cm<sup>-1</sup> and strong absorption in the visible to near-infrared spectral region. The formation of smooth conjugated poly(porphyrins) coatings, even on sensitive substrates, is demonstrated by deposition and patterning on glass, silicon, and paper. Formation of conductive poly(porphyrins) thin films could enable the design of new optoelectronic devices using the oCVD approach.
Addresses
  • Materials Research and Technology, Luxembourg Institute of Science and Technology (LIST), 5 Avenue des Hauts-Fourneaux, 4362, Esch/Alzette, Luxembourg.
Autoren
  • Giuseppe Bengasi
  • Kamal Baba
  • Gilles Frache
  • Jessica Desport
  • Paul Gratia
  • Katja Heinze
  • Nicolas D Boscher
DOI
10.1002/anie.201814034
eISSN
1521-3773
Externe Identifier
  • PubMed Identifier: 30556943
  • PubMed Central ID: PMC6582438
Funding acknowledgements
  • Fonds National de la Recherche Luxembourg: C15/MS/10340560/POLYPORH/Boscher
Open access
true
ISSN
1433-7851
Ausgabe der Veröffentlichung
7
Zeitschrift
Angewandte Chemie (International ed. in English)
Sprache
eng
Medium
Print-Electronic
Online publication date
2019
Open access status
Open Access
Paginierung
2103 - 2108
Datum der Veröffentlichung
2019
Status
Published
Publisher licence
CC BY-NC-ND
Datum der Datenerfassung
2018
Titel
Conductive Fused Porphyrin Tapes on Sensitive Substrates by a Chemical Vapor Deposition Approach.
Sub types
  • brief-report
  • Journal Article
Ausgabe der Zeitschrift
58

Files

https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.201814034 https://europepmc.org/articles/PMC6582438?pdf=render

Data source: Europe PubMed Central

Abstract
Oxidative polymerization of nickel(II) 5,15-diphenyl porphyrin and nickel(II) 5,15-bis(di-3,5-tert-butylphenyl) porphyrin by oxidative chemical vapor deposition (oCVD) yields multiply fused porphyrin oligomers in thin film form. The oCVD technique enables one-step formation, deposition, and p-doping of conjugated poly(porphyrins) coatings without solvents or post-treatments. The decisive reactions and side reactions during the oCVD process are shown by high-resolution mass spectrometry. Owing to the highly conjugated structure of the fused tapes, the thin films exhibit an electrical conductivity of 3.6×10-2  S cm-1 and strong absorption in the visible to near-infrared spectral region. The formation of smooth conjugated poly(porphyrins) coatings, even on sensitive substrates, is demonstrated by deposition and patterning on glass, silicon, and paper. Formation of conductive poly(porphyrins) thin films could enable the design of new optoelectronic devices using the oCVD approach.
Autoren
  • Giuseppe Bengasi
  • Kamal Baba
  • Gilles Frache
  • Jessica Desport
  • Paul Gratia
  • Katja Heinze
  • Nicolas D Boscher
Autoren-URL
https://www.ncbi.nlm.nih.gov/pubmed/30556943
DOI
10.1002/anie.201814034
eISSN
1521-3773
Externe Identifier
  • PubMed Central ID: PMC6582438
Funding acknowledgements
  • Fonds National de la Recherche Luxembourg: C15/MS/10340560/POLYPORH/Boscher
Ausgabe der Veröffentlichung
7
Zeitschrift
Angew Chem Int Ed Engl
Schlüsselwörter
  • chemical vapor deposition
  • oxidative coupling
  • polymerization
  • porphyrins
  • thin films
Sprache
eng
Country
Germany
Paginierung
2103 - 2108
Datum der Veröffentlichung
2019
Status
Published
Titel
Conductive Fused Porphyrin Tapes on Sensitive Substrates by a Chemical Vapor Deposition Approach.
Sub types
  • Journal Article
Ausgabe der Zeitschrift
58

Data source: PubMed

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