Structural and photophysical studies of trans-AB2C-substituted porphyrin ligands and their zinc and copper complexes
- Publication type:
- Journal article
- Metadata:
-
- Autoren
- Katja Heinze
- Anja Reinhart
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000252254300009&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1039/b713779f
- Externe Identifier
- Clarivate Analytics Document Solution ID: 249UC
- PubMed Identifier: 18185863
- ISSN
- 1477-9226
- Ausgabe der Veröffentlichung
- 4
- Zeitschrift
- DALTON TRANSACTIONS
- Paginierung
- 469 - 480
- Datum der Veröffentlichung
- 2008
- Status
- Published
- Titel
- Structural and photophysical studies of <i>trans</i>-AB<sub>2</sub>C-substituted porphyrin ligands and their zinc and copper complexes
- Sub types
- Article
Data source: Web of Science (Lite)
- Other metadata sources:
-
- Autoren
- Katja Heinze
- Anja Reinhart
- DOI
- 10.1039/b713779f
- eISSN
- 1477-9234
- ISSN
- 1477-9226
- Ausgabe der Veröffentlichung
- 4
- Zeitschrift
- Dalton Trans.
- Sprache
- en
- Online publication date
- 2008
- Paginierung
- 469 - 480
- Status
- Published online
- Herausgeber
- Royal Society of Chemistry (RSC)
- Herausgeber URL
- http://dx.doi.org/10.1039/b713779f
- Datum der Datenerfassung
- 2024
- Titel
- Structural and photophysical studies of trans-AB<sub>2</sub>C-substituted porphyrinligands and their zinc and copper complexes
Data source: Crossref
- Abstract
- trans-AB(2)C porphyrins with A = C(6)H(4)-COOR, C = C(6)H(4)-NX(2) and B = C(6)H(5) (R = CH(3), H; X = O, H) have been synthesised by a rational high-yield procedure (1a-1d) and their zinc(ii) and copper(ii) complexes have been prepared (2a-2d, 3a-3d ).1a, 2a .THF and 3a display different distortions of the porphyrin core as shown by single crystal X-ray crystallography and NSD analyses. The Soret and Q bands of free-base and metalated porphyrins with mixed electron donating and withdrawing substituents (NH(2)/COOR) are red-shifted as are the corresponding emission bands of free-base and zinc porphyrins. The electronic asymmetry revealed by spectrocopy is rationalised by DFT calculations.
- Addresses
- Department of Inorganic Chemistry, University of Heidelberg, Im Neuenheimer Feld 270, 69120, Heidelberg, Germany. katja.heinze@urz.uni-heidelberg.de
- Autoren
- Katja Heinze
- Anja Reinhart
- DOI
- 10.1039/b713779f
- eISSN
- 1477-9234
- Externe Identifier
- PubMed Identifier: 18185863
- Open access
- false
- ISSN
- 1477-9226
- Ausgabe der Veröffentlichung
- 4
- Zeitschrift
- Dalton transactions (Cambridge, England : 2003)
- Schlüsselwörter
- Copper
- Zinc
- Porphyrins
- Peptides
- Ligands
- Calorimetry, Differential Scanning
- Spectrophotometry, Infrared
- Magnetic Resonance Spectroscopy
- Molecular Structure
- Electrochemistry
- Photochemistry
- Models, Molecular
- Sprache
- eng
- Medium
- Print-Electronic
- Online publication date
- 2007
- Paginierung
- 469 - 480
- Datum der Veröffentlichung
- 2008
- Status
- Published
- Datum der Datenerfassung
- 2008
- Titel
- Structural and photophysical studies of trans-AB(2)C-substituted porphyrin ligands and their zinc and copper complexes.
- Sub types
- Research Support, Non-U.S. Gov't
- Journal Article
Data source: Europe PubMed Central
- Abstract
- trans-AB(2)C porphyrins with A = C(6)H(4)-COOR, C = C(6)H(4)-NX(2) and B = C(6)H(5) (R = CH(3), H; X = O, H) have been synthesised by a rational high-yield procedure (1a-1d) and their zinc(ii) and copper(ii) complexes have been prepared (2a-2d, 3a-3d ).1a, 2a .THF and 3a display different distortions of the porphyrin core as shown by single crystal X-ray crystallography and NSD analyses. The Soret and Q bands of free-base and metalated porphyrins with mixed electron donating and withdrawing substituents (NH(2)/COOR) are red-shifted as are the corresponding emission bands of free-base and zinc porphyrins. The electronic asymmetry revealed by spectrocopy is rationalised by DFT calculations.
- Autoren
- Katja Heinze
- Anja Reinhart
- Autoren-URL
- https://www.ncbi.nlm.nih.gov/pubmed/18185863
- DOI
- 10.1039/b713779f
- ISSN
- 1477-9226
- Ausgabe der Veröffentlichung
- 4
- Zeitschrift
- Dalton Trans
- Schlüsselwörter
- Calorimetry, Differential Scanning
- Copper
- Electrochemistry
- Ligands
- Magnetic Resonance Spectroscopy
- Models, Molecular
- Molecular Structure
- Peptides
- Photochemistry
- Porphyrins
- Spectrophotometry, Infrared
- Zinc
- Sprache
- eng
- Country
- England
- Paginierung
- 469 - 480
- Datum der Veröffentlichung
- 2008
- Status
- Published
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2008
- Titel
- Structural and photophysical studies of trans-AB(2)C-substituted porphyrin ligands and their zinc and copper complexes.
- Sub types
- Journal Article
- Research Support, Non-U.S. Gov't
Data source: PubMed
- Beziehungen:
-