Main chain ferrocenyl amides from 1-aminoferrocene-1′-carboxylic acid

Publication type:
Journal article
Metadata:
Autoren
  • K Heinze
  • M Schlenker
Autoren-URL
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000222895000023&DestLinkType=FullRecord&DestApp=WOS_CPL
DOI
10.1002/ejic.200300897
eISSN
1099-0682
Externe Identifier
  • Clarivate Analytics Document Solution ID: 840YA
ISSN
1434-1948
Ausgabe der Veröffentlichung
14
Zeitschrift
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Schlüsselwörter
  • metallocenes
  • hydrogen bonds
  • peptides
  • conformation analysis
Paginierung
2974 - 2988
Datum der Veröffentlichung
2004
Status
Published
Titel
Main chain ferrocenyl amides from 1-aminoferrocene-1′-carboxylic acid
Sub types
  • Article

Data source: Web of Science (Lite)

Other metadata sources:
Abstract
<jats:title>Abstract</jats:title><jats:p>The non‐natural amino acid 1‐aminoferrocene‐1′‐carboxylic acid is synthesised from ferrocene in eight steps. The folding and association phenomena of amido‐substituted ferrocenes in the crystal as well as in solution are studied by X‐ray crystallography, IR and NMR spectroscopy and DFT calculations. The amino acid is selectively protected at the amino group with the use of the fluorenyl‐9‐methoxycarbonyl (Fmoc) group. An amide‐linked ferrocene dimer is prepared using the HOBt/DCC protocol for amide formation. In the crystal the dimer forms a hydrogen‐bonded sheet structure, while in solution dynamic intramolecular hydrogen bonds are observed by VT <jats:sup>1</jats:sup>H NMR and IR spectroscopy. The dynamic flipping process has been rationalised by DFT calculations. (© Wiley‐VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2004)</jats:p>
Autoren
  • Katja Heinze
  • Manuela Schlenker
DOI
10.1002/ejic.200300897
eISSN
1099-0682
ISSN
1434-1948
Ausgabe der Veröffentlichung
14
Zeitschrift
European Journal of Inorganic Chemistry
Sprache
en
Online publication date
2004
Paginierung
2974 - 2988
Datum der Veröffentlichung
2004
Status
Published
Herausgeber
Wiley
Herausgeber URL
http://dx.doi.org/10.1002/ejic.200300897
Datum der Datenerfassung
2023
Titel
Main Chain Ferrocenyl Amides from 1‐Aminoferrocene‐1′‐carboxylic Acid
Ausgabe der Zeitschrift
2004

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