Synthesis and Characterization of Extended Bis(terpyridine)ruthenium Amino Acids
- Publication type:
- Journal article
- Metadata:
-
- Abstract
- <jats:title>Abstract</jats:title><jats:p>(Oligopyridine)ruthenium(II) complexes have been widely used in dye sensitized solar cells and other sophisticated optical devices due to their outstanding photophysical properties and their chemical stability. Herein, we describe the longitudinal extension of our previously reported bis(terpyridine)ruthenium(II) amino acid [Ru(tpy–NH<jats:sub>2</jats:sub>)(tpy–COOH)]<jats:sup>2+</jats:sup> (tpy = 4′‐substituted 2,2′:6′,2″‐terpyridine) by insertion of <jats:italic>para</jats:italic>‐phenylene spacers –C<jats:sub>6</jats:sub>H<jats:sub>4</jats:sub>– between the terpyridine and the functional groups. The influence of the <jats:italic>para</jats:italic>‐phenylene spacer on the absorption and emission properties is investigated using UV/Vis absorption and emission spectroscopy and is discussed within a qualitative molecular orbital picture.</jats:p>
- Autoren
- Katja Heinze
- Klaus Hempel
- Aaron Breivogel
- DOI
- 10.1002/zaac.200900303
- eISSN
- 1521-3749
- ISSN
- 0044-2313
- Ausgabe der Veröffentlichung
- 15
- Zeitschrift
- Zeitschrift für anorganische und allgemeine Chemie
- Sprache
- en
- Online publication date
- 2009
- Paginierung
- 2541 - 2549
- Datum der Veröffentlichung
- 2009
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/zaac.200900303
- Datum der Datenerfassung
- 2023
- Titel
- Synthesis and Characterization of Extended Bis(terpyridine)ruthenium Amino Acids
- Ausgabe der Zeitschrift
- 635
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