The Crystal Structure of the THF Adduct of Monolithioferrocene
- Publication type:
- Journal article
- Metadata:
-
- Autoren
- Christoph Foerster
- Katja Heinze
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000351445600001&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1002/zaac.201400548
- eISSN
- 1521-3749
- Externe Identifier
- Clarivate Analytics Document Solution ID: CD9UZ
- ISSN
- 0044-2313
- Ausgabe der Veröffentlichung
- 3-4
- Zeitschrift
- ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
- Schlüsselwörter
- Ferrocene
- Crystal structure
- Lithium
- Organolithium compound
- X-ray diffraction
- Paginierung
- 517 - 520
- Datum der Veröffentlichung
- 2015
- Status
- Published
- Titel
- The Crystal Structure of the THF Adduct of Monolithioferrocene
- Sub types
- Article
- Ausgabe der Zeitschrift
- 641
Data source: Web of Science (Lite)
- Other metadata sources:
-
- Abstract
- <jats:title>Abstract</jats:title><jats:p>Single crystals of [Fe(η<jats:sup>5</jats:sup>‐C<jats:sub>5</jats:sub>H<jats:sub>4</jats:sub>)(η<jats:sup>5</jats:sup>‐C<jats:sub>5</jats:sub>H<jats:sub>5</jats:sub>)]<jats:sub>2</jats:sub>Li<jats:sub>2</jats:sub>(thf)<jats:sub>4</jats:sub> (<jats:bold>1</jats:bold>) were obtained from a tetrahydrofuran solution containing monolithioferrocene. The title compound crystallizes in the monoclinic space group <jats:italic>P</jats:italic>2<jats:sub>1</jats:sub> with <jats:italic>a</jats:italic> = 9.6589(5) Å, <jats:italic>b</jats:italic> = 17.4285(9) Å, <jats:italic>c</jats:italic> = 30.3116(15) Å, <jats:italic>β</jats:italic> = 91.911(2)° and <jats:italic>V</jats:italic> = 5099.8(5) Å<jats:sup>3</jats:sup> with three independent molecules of <jats:bold>1</jats:bold>. All individual molecules feature a non‐ symmetric almost planar Li<jats:sub>2</jats:sub>C<jats:sub>2</jats:sub> four‐membered ring with two shorter (2.118–2.215 Å) and two longer Li–C distances (2.257–2.309 Å). The lithium cations are each coordinated by two carbanionic atoms of two ferrocenyl substituents and two tetrahydrofuran molecules in a distorted tetrahedral fashion. All ferrocenyl moieties display an eclipsed conformation of the C<jats:sub>5</jats:sub> rings.</jats:p>
- Autoren
- Christoph Förster
- Katja Heinze
- DOI
- 10.1002/zaac.201400548
- eISSN
- 1521-3749
- ISSN
- 0044-2313
- Ausgabe der Veröffentlichung
- 3-4
- Zeitschrift
- Zeitschrift für anorganische und allgemeine Chemie
- Sprache
- en
- Online publication date
- 2015
- Paginierung
- 517 - 520
- Datum der Veröffentlichung
- 2015
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/zaac.201400548
- Datum der Datenerfassung
- 2023
- Titel
- The Crystal Structure of the THF Adduct of Monolithioferrocene
- Ausgabe der Zeitschrift
- 641
Data source: Crossref
- Beziehungen:
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