Conformational Switching of Multi-Responsive Ferrocenyl-Phenol Conjugates
- Publication type:
- Journal article
- Metadata:
-
- Autoren
- Andreas Neidlinger
- Christoph Foerster
- Katja Heinze
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000386920100015&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1002/ejoc.201600774
- eISSN
- 1099-0690
- Externe Identifier
- Clarivate Analytics Document Solution ID: EA8WI
- ISSN
- 1434-193X
- Ausgabe der Veröffentlichung
- 28
- Zeitschrift
- EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
- Schlüsselwörter
- Charge transfer
- EPR spectroscopy
- Structure elucidation
- Density functional calculations
- Sandwich complexes
- Phenols
- Paginierung
- 4852 - 4864
- Datum der Veröffentlichung
- 2016
- Status
- Published
- Titel
- Conformational Switching of Multi-Responsive Ferrocenyl-Phenol Conjugates
- Sub types
- Article
- Ausgabe der Zeitschrift
- 2016
Data source: Web of Science (Lite)
- Other metadata sources:
-
- Abstract
- <jats:p>Multifunctional conformational switches based on the ferrocenyl‐salicylic acid amide motif with increasing additional complexity at the Fc moiety (R = COOMe, CONHEt, CONHFc; <jats:bold>H‐2</jats:bold>–<jats:bold>H‐4</jats:bold>; Fc = ferrocenyl) have been prepared and their preferred secondary structures in solution have been elucidated by NMR and IR spectroscopy in combination with conformational searches based on DFT calculations. Their distinct conformational responses to deprotonation ([<jats:bold>2</jats:bold>]<jats:sup>–</jats:sup>–[<jats:bold>4</jats:bold>]<jats:sup>–</jats:sup>) and oxidation ([<jats:bold>H‐2</jats:bold>]<jats:sup>+<jats:bold>·</jats:bold></jats:sup>–[<jats:bold>H‐4</jats:bold>]<jats:sup>+<jats:bold>·</jats:bold></jats:sup>) have been revealed by IR, EPR, and UV/Vis spectroscopy as well as by DFT calculations. Deprotonation inverts all amide units (double amide twist) whereas oxidation selectively flips the terminal amide unit (single amide twist). The combined action of deprotonation and oxidation has also been explored.</jats:p>
- Autoren
- Andreas Neidlinger
- Christoph Förster
- Katja Heinze
- DOI
- 10.1002/ejoc.201600774
- eISSN
- 1099-0690
- ISSN
- 1434-193X
- Ausgabe der Veröffentlichung
- 28
- Zeitschrift
- European Journal of Organic Chemistry
- Sprache
- en
- Online publication date
- 2016
- Paginierung
- 4852 - 4864
- Datum der Veröffentlichung
- 2016
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/ejoc.201600774
- Datum der Datenerfassung
- 2023
- Titel
- Conformational Switching of Multi‐Responsive Ferrocenyl‐Phenol Conjugates
- Ausgabe der Zeitschrift
- 2016
Data source: Crossref
- Beziehungen:
-