Crystalline Non-Equilibrium Phase of a Cobalt(II) Complex with Tridentate Ligands

Publication type:
Journal article
Metadata:
Autoren
  • Christoph Foerster
  • Tatiana E Gorelik
  • Ute Kolb
  • Vadim Ksenofontov
  • Katja Heinze
Autoren-URL
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000349976200003&DestLinkType=FullRecord&DestApp=WOS_CPL
DOI
10.1002/ejic.201403200
eISSN
1099-0682
Externe Identifier
  • Clarivate Analytics Document Solution ID: CB9TP
ISSN
1434-1948
Ausgabe der Veröffentlichung
6
Zeitschrift
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Schlüsselwörter
  • Cobalt complexes
  • Electron diffraction
  • Isomerism
  • Structure elucidation
  • Tridentate ligands
Paginierung
920 - 924
Datum der Veröffentlichung
2015
Status
Published
Titel
Crystalline Non-Equilibrium Phase of a Cobalt(II) Complex with Tridentate Ligands
Sub types
  • Article

Data source: Web of Science (Lite)

Other metadata sources:
Abstract
<jats:title>Abstract</jats:title><jats:p>In six‐coordinate complexes, flexible tridentate ligands enable <jats:italic>mer</jats:italic>, <jats:italic>cis</jats:italic>‐<jats:italic>fac</jats:italic>, and <jats:italic>trans</jats:italic>‐<jats:italic>fac</jats:italic> stereoisomers. With labile metal ions of the first transition metal series, typically only the final thermodynamic product is available because of the rapid isomerization processes. Here we report on the structural characterization of a so far elusive kinetic intermediate of [Co(ddpd)<jats:sub>2</jats:sub>](BF<jats:sub>4</jats:sub>)<jats:sub>2</jats:sub> (<jats:bold>1</jats:bold>; ddpd = <jats:italic>N</jats:italic>,<jats:italic>N′</jats:italic>‐dimethyl‐<jats:italic>N</jats:italic>,<jats:italic>N′</jats:italic>‐dipyridine‐2‐yl‐pyridine‐2,6‐diamine). Microcrystals of the <jats:italic>cis</jats:italic>‐<jats:italic>fac</jats:italic> isomer of <jats:bold>1</jats:bold> were obtained by rapid precipitation. The solid‐state structure of <jats:bold><jats:italic>cis</jats:italic>‐<jats:italic>fac</jats:italic>‐1</jats:bold> was determined from electron diffraction data.</jats:p>
Autoren
  • Christoph Förster
  • Tatiana E Gorelik
  • Ute Kolb
  • Vadim Ksenofontov
  • Katja Heinze
DOI
10.1002/ejic.201403200
eISSN
1099-0682
ISSN
1434-1948
Ausgabe der Veröffentlichung
6
Zeitschrift
European Journal of Inorganic Chemistry
Sprache
en
Online publication date
2015
Paginierung
920 - 924
Datum der Veröffentlichung
2015
Status
Published
Herausgeber
Wiley
Herausgeber URL
http://dx.doi.org/10.1002/ejic.201403200
Datum der Datenerfassung
2023
Titel
Crystalline Non‐Equilibrium Phase of a Cobalt(II) Complex with Tridentate Ligands
Ausgabe der Zeitschrift
2015

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