Solution Conformation and Self-Assembly of Ferrocenyl(thio)ureas
- Publication type:
- Journal article
- Metadata:
-
- Autoren
- Kristina Hanauer
- Thu Pham Minh
- Christoph Foerster
- Katja Heinze
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000393404400030&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1002/ejic.201600918
- eISSN
- 1099-0682
- Externe Identifier
- Clarivate Analytics Document Solution ID: EJ7LY
- ISSN
- 1434-1948
- Ausgabe der Veröffentlichung
- 2
- Zeitschrift
- EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
- Schlüsselwörter
- Ferrocene
- (Thio)ureas
- Hydrogen bonds
- Self-assembly
- Conformation analysis
- Density functional calculations
- Solid-state structures
- Paginierung
- 433 - 445
- Datum der Veröffentlichung
- 2017
- Status
- Published
- Titel
- Solution Conformation and Self-Assembly of Ferrocenyl(thio)ureas
- Sub types
- Article
Data source: Web of Science (Lite)
- Other metadata sources:
-
- Abstract
- <jats:p>Conformations and (dis)assembly processes of ureas and thioureas are of fundamental importance in supramolecular chemistry, anion binding, or crystal engineering, both in solution and in the solid state. For sensing and switching processes a redox‐active unit, such as the ferrocene/ferrocenium couple, is especially suitable. Here, self‐assembly processes of redox‐active ferrocenyl(thio)ureas FcNHC(X)NHR [X = O, R = Fc (<jats:bold>1</jats:bold>), Ph (<jats:bold>2</jats:bold>), 1‐naphthyl (<jats:bold>3</jats:bold>), Me (<jats:bold>4</jats:bold>), Et (<jats:bold>5</jats:bold>); X = S, R = Fc (<jats:bold>6</jats:bold>), 1‐anthracenyl (<jats:bold>7</jats:bold>)] through hydrogen bonds – both in the solid state and in THF and CH<jats:sub>2</jats:sub>Cl<jats:sub>2</jats:sub> solution – are reported. Special emphasis is placed on the impact of nonclassical intramolecular NH<jats:bold>···</jats:bold>Fe hydrogen bonds in these organometallic systems [these are absent in conventional organic (thio)ureas] on conformation and assembly. Furthermore, conformational switching and disassembly of <jats:bold>1</jats:bold>–<jats:bold>6</jats:bold> is induced by oxidation of <jats:bold>1</jats:bold>–<jats:bold>6</jats:bold> to the corresponding ferrocenium cations <jats:bold>1<jats:sup>+</jats:sup></jats:bold>–<jats:bold>6<jats:sup>+</jats:sup></jats:bold> (redox switch).</jats:p>
- Autoren
- Kristina Hanauer
- Minh Thu Pham
- Christoph Förster
- Katja Heinze
- DOI
- 10.1002/ejic.201600918
- eISSN
- 1099-0682
- ISSN
- 1434-1948
- Ausgabe der Veröffentlichung
- 2
- Zeitschrift
- European Journal of Inorganic Chemistry
- Sprache
- en
- Online publication date
- 2016
- Paginierung
- 433 - 445
- Datum der Veröffentlichung
- 2017
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/ejic.201600918
- Datum der Datenerfassung
- 2023
- Titel
- Solution Conformation and Self‐Assembly of Ferrocenyl(thio)ureas
- Ausgabe der Zeitschrift
- 2017
Data source: Crossref
- Beziehungen:
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