Photochemistry and Redox Chemistry of an Unsymmetrical Bimetallic Copper(I) Complex
- Publication type:
- Journal article
- Metadata:
-
- Autoren
- Oliver Back
- Jana Leppin
- Christoph Foerster
- Katja Heinze
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000384782600022&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1021/acs.inorgchem.6b01400
- eISSN
- 1520-510X
- Externe Identifier
- Clarivate Analytics Document Solution ID: DY0JH
- PubMed Identifier: 27622744
- ISSN
- 0020-1669
- Ausgabe der Veröffentlichung
- 19
- Zeitschrift
- INORGANIC CHEMISTRY
- Paginierung
- 9653 - 9662
- Datum der Veröffentlichung
- 2016
- Status
- Published
- Titel
- Photochemistry and Redox Chemistry of an Unsymmetrical Bimetallic Copper(I) Complex
- Sub types
- Article
- Ausgabe der Zeitschrift
- 55
Data source: Web of Science (Lite)
- Other metadata sources:
-
- Autoren
- Oliver Back
- Jana Leppin
- Christoph Förster
- Katja Heinze
- DOI
- 10.1021/acs.inorgchem.6b01400
- eISSN
- 1520-510X
- ISSN
- 0020-1669
- Ausgabe der Veröffentlichung
- 19
- Zeitschrift
- Inorganic Chemistry
- Sprache
- en
- Online publication date
- 2016
- Paginierung
- 9653 - 9662
- Datum der Veröffentlichung
- 2016
- Status
- Published
- Herausgeber
- American Chemical Society (ACS)
- Herausgeber URL
- http://dx.doi.org/10.1021/acs.inorgchem.6b01400
- Datum der Datenerfassung
- 2023
- Titel
- Photochemistry and Redox Chemistry of an Unsymmetrical Bimetallic Copper(I) Complex
- Ausgabe der Zeitschrift
- 55
Data source: Crossref
- Abstract
- The bimetallic copper(I) complex Cu<sub>2</sub>L<sub>2</sub> (cis-1) is formed with high diasteroselectivity from [Cu(NCCH<sub>3</sub>)<sub>4</sub>][BF<sub>4</sub>] and HL (4-tert-butyl phenyl(pyrrolato-2-yl-methylene)amine) in a kinetically controlled reaction. cis-1 features a rather short Cu···Cu distance of 2.4756(6) Å and is weakly emissive at room temperature in solution. Oxidatively triggered disproportionation of cis-1 yields elemental copper and the mononuclear copper(II) complex CuL<sub>2</sub> (trans-2). One-electron reduction of trans-2 gives cuprate [2]<sup>-</sup> with a bent bis(pyrrolato) coordinated copper(I) entity. The imine donor atoms of [2]<sup>-</sup> can insert an additional copper(I) ion giving exclusively the bimetallic complex cis-1 closing the oxidation-elimination-reduction-insertion cycle.
- Addresses
- Institute of Inorganic Chemistry and Analytical Chemistry, Johannes Gutenberg-University of Mainz , Duesbergweg 10-14, 55128 Mainz, Germany.
- Autoren
- Oliver Back
- Jana Leppin
- Christoph Förster
- Katja Heinze
- DOI
- 10.1021/acs.inorgchem.6b01400
- eISSN
- 1520-510X
- Externe Identifier
- PubMed Identifier: 27622744
- Open access
- false
- ISSN
- 0020-1669
- Ausgabe der Veröffentlichung
- 19
- Zeitschrift
- Inorganic chemistry
- Sprache
- eng
- Medium
- Print-Electronic
- Online publication date
- 2016
- Paginierung
- 9653 - 9662
- Datum der Veröffentlichung
- 2016
- Status
- Published
- Datum der Datenerfassung
- 2016
- Titel
- Photochemistry and Redox Chemistry of an Unsymmetrical Bimetallic Copper(I) Complex.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 55
Data source: Europe PubMed Central
- Abstract
- The bimetallic copper(I) complex Cu2L2 (cis-1) is formed with high diasteroselectivity from [Cu(NCCH3)4][BF4] and HL (4-tert-butyl phenyl(pyrrolato-2-yl-methylene)amine) in a kinetically controlled reaction. cis-1 features a rather short Cu···Cu distance of 2.4756(6) Å and is weakly emissive at room temperature in solution. Oxidatively triggered disproportionation of cis-1 yields elemental copper and the mononuclear copper(II) complex CuL2 (trans-2). One-electron reduction of trans-2 gives cuprate [2]- with a bent bis(pyrrolato) coordinated copper(I) entity. The imine donor atoms of [2]- can insert an additional copper(I) ion giving exclusively the bimetallic complex cis-1 closing the oxidation-elimination-reduction-insertion cycle.
- Autoren
- Oliver Back
- Jana Leppin
- Christoph Förster
- Katja Heinze
- Autoren-URL
- https://www.ncbi.nlm.nih.gov/pubmed/27622744
- DOI
- 10.1021/acs.inorgchem.6b01400
- eISSN
- 1520-510X
- Ausgabe der Veröffentlichung
- 19
- Zeitschrift
- Inorg Chem
- Sprache
- eng
- Country
- United States
- Paginierung
- 9653 - 9662
- Datum der Veröffentlichung
- 2016
- Status
- Published
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2018
- Titel
- Photochemistry and Redox Chemistry of an Unsymmetrical Bimetallic Copper(I) Complex.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 55
Data source: PubMed
- Beziehungen:
-