Selective and Scalable Electrosynthesis of 2H‐2‐(Aryl)‐benzo[d]‐1,2,3‐triazoles and Their N‐Oxides by Using Leaded Bronze Cathodes
- Publication type:
- Journal article
- Metadata:
-
- Abstract
- <jats:title>Abstract</jats:title><jats:p>Electrosynthesis of <jats:italic>2H</jats:italic>‐2‐(aryl)benzo[<jats:italic>d</jats:italic>]‐1,2,3‐triazoles and their N‐oxides from 2‐nitroazobenzene derivatives is reported. The electrolysis is conducted in a very simple undivided cell under constant current conditions with a leaded bronze cathode and a glassy carbon anode. The product distribution between <jats:italic>2H</jats:italic>‐2‐(aryl)benzo[<jats:italic>d</jats:italic>]‐1,2,3‐triazoles and their N‐oxides can be guided by simply controlling the current density and the amount of the charge applied. The reaction tolerates several sensitive functional groups in reductive electrochemistry. The usefulness and the applicability of the synthetic method is demonstrated by a formal synthesis of an antiviral compound.</jats:p>
- Autoren
- Tom Wirtanen
- Eduardo Rodrigo
- Siegfried R Waldvogel
- DOI
- 10.1002/chem.201905874
- eISSN
- 1521-3765
- ISSN
- 0947-6539
- Ausgabe der Veröffentlichung
- 25
- Zeitschrift
- Chemistry – A European Journal
- Sprache
- en
- Online publication date
- 2020
- Paginierung
- 5592 - 5597
- Datum der Veröffentlichung
- 2020
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/chem.201905874
- Datum der Datenerfassung
- 2023
- Titel
- Selective and Scalable Electrosynthesis of <i>2H</i>‐2‐(Aryl)‐benzo[<i>d</i>]‐1,2,3‐triazoles and Their N‐Oxides by Using Leaded Bronze Cathodes
- Ausgabe der Zeitschrift
- 26
Data source: Crossref
- Other metadata sources:
-
- Author's licence
- CC-BY-NC-ND
- Autoren
- Tom Wirtanen
- Eduardo Rodrigo
- Siegfried R Waldvogel
- Hosting institution
- Universitätsbibliothek Mainz
- Sammlungen
- JGU-Publikationen
- Resource version
- Published version
- DOI
- 10.1002/chem.201905874
- File(s) embargoed
- false
- Open access
- true
- ISSN
- 1521-3765
- Ausgabe der Veröffentlichung
- 25
- Zeitschrift
- Chemistry - a European journal
- Schlüsselwörter
- 540 Chemie
- 540 Chemistry and allied sciences
- Sprache
- eng
- Open access status
- Open Access
- Paginierung
- 5597 - 5592
- Datum der Veröffentlichung
- 2020
- Public URL
- https://openscience.ub.uni-mainz.de/handle/20.500.12030/6268
- Herausgeber
- Wiley-VCH
- Herausgeber URL
- https://doi.org/10.1002/chem.201905874
- Datum der Datenerfassung
- 2021
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2021
- Zugang
- Public
- Titel
- Selective and scalable electrosynthesis of 2H-2-(aryl)-benzo[d]-1,2,3-triazoles and their N-oxides by using leaded bronze cathodes
- Ausgabe der Zeitschrift
- 26
Files
dr._wirtanen_tom-selective_and_-20210804151231372.pdf
Data source: OPENSCIENCE.UB