The “Green” Electrochemical Synthesis of Periodate
- Publication type:
- Journal article
- Metadata:
-
- Abstract
- <jats:title>Abstract</jats:title><jats:p>High‐grade periodate is relatively expensive, but is required for many sensitive applications such as the synthesis of active pharmaceutical ingredients. These high costs originate from using lead dioxide anodes in contemporary electrochemical methods and from expensive starting materials. A direct and cost‐efficient electrochemical synthesis of periodate from iodide, which is less costly and relies on a readily available starting material, is reported. The oxidation is conducted at boron‐doped diamond anodes, which are durable, metal‐free, and nontoxic. The avoidance of lead dioxide ultimately lowers the cost of purification and quality assurance. The electrolytic process was optimized by statistical methods and was scaled up in an electrolysis flow cell that enhanced the space–time yields by a cyclization protocol. An LC‐PDA analytical protocol was established enabling simple quantification of iodide, iodate, and periodate simultaneously with remarkable precision.</jats:p>
- Autoren
- Sebastian Arndt
- Dominik Weis
- Kai Donsbach
- Siegfried R Waldvogel
- DOI
- 10.1002/anie.202002717
- eISSN
- 1521-3773
- ISSN
- 1433-7851
- Ausgabe der Veröffentlichung
- 21
- Zeitschrift
- Angewandte Chemie International Edition
- Sprache
- en
- Online publication date
- 2020
- Paginierung
- 8036 - 8041
- Datum der Veröffentlichung
- 2020
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/anie.202002717
- Datum der Datenerfassung
- 2023
- Titel
- The “Green” Electrochemical Synthesis of Periodate
- Ausgabe der Zeitschrift
- 59
Data source: Crossref
- Other metadata sources:
-
- Author's licence
- CC-BY-NC
- Autoren
- Sebastian Arndt
- Dominik Weis
- Kai Donsbach
- Siegfried R Waldvogel
- Hosting institution
- Universitätsbibliothek Mainz
- Sammlungen
- JGU-Publikationen
- Resource version
- Published version
- DOI
- 10.1002/anie.202002717
- File(s) embargoed
- false
- Open access
- true
- ISSN
- 1521-3773
- Ausgabe der Veröffentlichung
- 21
- Zeitschrift
- Angewandte Chemie
- Schlüsselwörter
- 540 Chemie
- 540 Chemistry and allied sciences
- Sprache
- eng
- Open access status
- Open Access
- Paginierung
- 8036 - 8041
- Datum der Veröffentlichung
- 2020
- Public URL
- https://openscience.ub.uni-mainz.de/handle/20.500.12030/6264
- Herausgeber
- Wiley-VCH
- Herausgeber URL
- https://doi.org/10.1002/anie.202002717
- Datum der Datenerfassung
- 2021
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2021
- Zugang
- Public
- Titel
- The “green” electrochemical synthesis of periodate
- Ausgabe der Zeitschrift
- 59
Files
dr._arndt_sebastian-the_“green”_el-20210804145458267.pdf
Data source: OPENSCIENCE.UB