Crystallization kinetics of colloidal binary mixtures with depletion attraction

Publikationstyp:
Zeitschriftenaufsatz
Metadaten:
Autoren
  • Anna Kozina
  • Pedro Diaz-Leyva
  • Thomas Palberg
  • Eckhard Bartsch
Autoren-URL
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000345090400015&DestLinkType=FullRecord&DestApp=WOS_CPL
DOI
10.1039/c4sm02193b
eISSN
1744-6848
Externe Identifier
  • Clarivate Analytics Document Solution ID: AT7BE
  • PubMed Identifier: 25354340
ISSN
1744-683X
Ausgabe der Veröffentlichung
47
Zeitschrift
SOFT MATTER
Paginierung
9523 - 9533
Datum der Veröffentlichung
2014
Status
Published
Titel
Crystallization kinetics of colloidal binary mixtures with depletion attraction
Sub types
  • Article
Ausgabe der Zeitschrift
10

Datenquelle: Web of Science (Lite)

Andere Metadatenquellen:
Autoren
  • Anna Kozina
  • Pedro Díaz-Leyva
  • Thomas Palberg
  • Eckhard Bartsch
DOI
10.1039/c4sm02193b
eISSN
1744-6848
ISSN
1744-683X
Ausgabe der Veröffentlichung
47
Zeitschrift
Soft Matter
Sprache
en
Online publication date
2014
Paginierung
9523 - 9533
Status
Published online
Herausgeber
Royal Society of Chemistry (RSC)
Herausgeber URL
http://dx.doi.org/10.1039/c4sm02193b
Datum der Datenerfassung
2024
Titel
Crystallization kinetics of colloidal binary mixtures with depletion attraction
Ausgabe der Zeitschrift
10

Datenquelle: Crossref

Abstract
In this work the crystallization kinetics of colloidal binary mixtures with attractive interaction potential (Asakura-Oosawa) has been addressed. Parameters such as fraction of crystals, linear crystal dimension and crystal packing have been quantified in order to understand how the crystal formation is driven in terms of the depth of the attractive potential and the composition of the binary mixture (described by the number ratio). It was found that inside the eutectic triangle, crystallization is mainly governed by nucleation and the crystal packing is close to the close-packing of hard spheres. Moving out from the eutectic triangle towards small component results in the crystallization of small spheres. Enrichment of the eutectic mixture with large component results in the crystallization of both large and small spheres, however, the kinetics are completely different from those of the eutectic composition. Crosslinked polystyrene microgels with nearly hard sphere interactions were used as model systems. Attraction was introduced by addition of linear polystyrene. The time evolution of crystallization has been followed by static light scattering.
Addresses
  • Institut für Makromolekulare Chemie, Albert-Ludwigs-Universität Freiburg, Stefan-Meier-Str. 31, 79104 Freiburg, Germany. akozina@unam.mx.
Autoren
  • Anna Kozina
  • Pedro Díaz-Leyva
  • Thomas Palberg
  • Eckhard Bartsch
DOI
10.1039/c4sm02193b
eISSN
1744-6848
Externe Identifier
  • PubMed Identifier: 25354340
Funding acknowledgements
  • Consejo Nacional de Ciencia y TecnologÃ-a: Red Temática de la Materia Condensada Blanda
Open access
false
ISSN
1744-683X
Ausgabe der Veröffentlichung
47
Zeitschrift
Soft matter
Sprache
eng
Medium
Print-Electronic
Online publication date
2014
Paginierung
9523 - 9533
Datum der Veröffentlichung
2014
Status
Published
Datum der Datenerfassung
2014
Titel
Crystallization kinetics of colloidal binary mixtures with depletion attraction.
Sub types
  • Research Support, Non-U.S. Gov't
  • Journal Article
Ausgabe der Zeitschrift
10

Datenquelle: Europe PubMed Central

Abstract
In this work the crystallization kinetics of colloidal binary mixtures with attractive interaction potential (Asakura-Oosawa) has been addressed. Parameters such as fraction of crystals, linear crystal dimension and crystal packing have been quantified in order to understand how the crystal formation is driven in terms of the depth of the attractive potential and the composition of the binary mixture (described by the number ratio). It was found that inside the eutectic triangle, crystallization is mainly governed by nucleation and the crystal packing is close to the close-packing of hard spheres. Moving out from the eutectic triangle towards small component results in the crystallization of small spheres. Enrichment of the eutectic mixture with large component results in the crystallization of both large and small spheres, however, the kinetics are completely different from those of the eutectic composition. Crosslinked polystyrene microgels with nearly hard sphere interactions were used as model systems. Attraction was introduced by addition of linear polystyrene. The time evolution of crystallization has been followed by static light scattering.
Autoren
  • Anna Kozina
  • Pedro Díaz-Leyva
  • Thomas Palberg
  • Eckhard Bartsch
Autoren-URL
https://www.ncbi.nlm.nih.gov/pubmed/25354340
DOI
10.1039/c4sm02193b
eISSN
1744-6848
Ausgabe der Veröffentlichung
47
Zeitschrift
Soft Matter
Sprache
eng
Country
England
Paginierung
9523 - 9533
Datum der Veröffentlichung
2014
Status
Published
Datum, an dem der Datensatz öffentlich gemacht wurde
2015
Titel
Crystallization kinetics of colloidal binary mixtures with depletion attraction.
Sub types
  • Journal Article
  • Research Support, Non-U.S. Gov't
Ausgabe der Zeitschrift
10

Datenquelle: PubMed

Autoren
  • Anna Kozina
  • Pedro Díaz-Leyva
  • Thomas Palberg
  • Eckhard Bartsch
DOI
10.1039/C4SM02193B
Zeitschrift
Soft matter
Artikelnummer
47
Paginierung
9523 - 9533
Datum der Veröffentlichung
2014
Datum der Datenerfassung
2020
Titel
Crystallization kinetics of colloidal binary mixtures with depletion attraction
Sub types
  • article
Ausgabe der Zeitschrift
10

Datenquelle: Manual

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