Experimental studies of crystal nucleation: metals and colloids
- Publikationstyp:
- Zeitschriftenaufsatz
- Metadaten:
-
- Autoren
- Dieter M Herlach
- Thomas Palberg
- Ina Klassen
- Stefan Klein
- Raphael Koboldl
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000390603500004&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1063/1.4963684
- eISSN
- 1089-7690
- Externe Identifier
- Clarivate Analytics Document Solution ID: EF8TU
- PubMed Identifier: 28799394
- ISSN
- 0021-9606
- Ausgabe der Veröffentlichung
- 21
- Zeitschrift
- JOURNAL OF CHEMICAL PHYSICS
- Artikelnummer
- ARTN 211703
- Datum der Veröffentlichung
- 2016
- Status
- Published
- Titel
- Overview: Experimental studies of crystal nucleation: Metals and colloids
- Sub types
- Article
- Ausgabe der Zeitschrift
- 145
Datenquelle: Web of Science (Lite)
- Andere Metadatenquellen:
-
- Abstract
- <jats:p>Crystallization is one of the most important phase transformations of first order. In the case of metals and alloys, the liquid phase is the parent phase of materials production. The conditions of the crystallization process control the as-solidified material in its chemical and physical properties. Nucleation initiates the crystallization of a liquid. It selects the crystallographic phase, stable or meta-stable. Its detailed knowledge is therefore mandatory for the design of materials. We present techniques of containerless processing for nucleation studies of metals and alloys. Experimental results demonstrate the power of these methods not only for crystal nucleation of stable solids but in particular also for investigations of crystal nucleation of metastable solids at extreme undercooling. This concerns the physical nature of heterogeneous versus homogeneous nucleation and nucleation of phases nucleated under non-equilibrium conditions. The results are analyzed within classical nucleation theory that defines the activation energy of homogeneous nucleation in terms of the interfacial energy and the difference of Gibbs free energies of solid and liquid. The interfacial energy acts as barrier for the nucleation process. Its experimental determination is difficult in the case of metals. In the second part of this work we therefore explore the potential of colloidal suspensions as model systems for the crystallization process. The nucleation process of colloids is observed in situ by optical observation and ultra-small angle X-ray diffraction using high intensity synchrotron radiation. It allows an unambiguous discrimination of homogeneous and heterogeneous nucleation as well as the determination of the interfacial free energy of the solid-liquid interface. Our results are used to construct Turnbull plots of colloids, which are discussed in relation to Turnbull plots of metals and support the hypothesis that colloids are useful model systems to investigate crystal nucleation.</jats:p>
- Autoren
- Dieter M Herlach
- Thomas Palberg
- Ina Klassen
- Stefan Klein
- Raphael Kobold
- DOI
- 10.1063/1.4963684
- eISSN
- 1089-7690
- ISSN
- 0021-9606
- Ausgabe der Veröffentlichung
- 21
- Zeitschrift
- The Journal of Chemical Physics
- Sprache
- en
- Online publication date
- 2016
- Datum der Veröffentlichung
- 2016
- Status
- Published
- Herausgeber
- AIP Publishing
- Herausgeber URL
- http://dx.doi.org/10.1063/1.4963684
- Datum der Datenerfassung
- 2023
- Titel
- Overview: Experimental studies of crystal nucleation: Metals and colloids
- Ausgabe der Zeitschrift
- 145
Datenquelle: Crossref
- Abstract
- Crystallization is one of the most important phase transformations of first order. In the case of metals and alloys, the liquid phase is the parent phase of materials production. The conditions of the crystallization process control the as-solidified material in its chemical and physical properties. Nucleation initiates the crystallization of a liquid. It selects the crystallographic phase, stable or meta-stable. Its detailed knowledge is therefore mandatory for the design of materials. We present techniques of containerless processing for nucleation studies of metals and alloys. Experimental results demonstrate the power of these methods not only for crystal nucleation of stable solids but in particular also for investigations of crystal nucleation of metastable solids at extreme undercooling. This concerns the physical nature of heterogeneous versus homogeneous nucleation and nucleation of phases nucleated under non-equilibrium conditions. The results are analyzed within classical nucleation theory that defines the activation energy of homogeneous nucleation in terms of the interfacial energy and the difference of Gibbs free energies of solid and liquid. The interfacial energy acts as barrier for the nucleation process. Its experimental determination is difficult in the case of metals. In the second part of this work we therefore explore the potential of colloidal suspensions as model systems for the crystallization process. The nucleation process of colloids is observed in situ by optical observation and ultra-small angle X-ray diffraction using high intensity synchrotron radiation. It allows an unambiguous discrimination of homogeneous and heterogeneous nucleation as well as the determination of the interfacial free energy of the solid-liquid interface. Our results are used to construct Turnbull plots of colloids, which are discussed in relation to Turnbull plots of metals and support the hypothesis that colloids are useful model systems to investigate crystal nucleation.
- Addresses
- Institut für Materialphysik im Weltraum, Deutsches Zentrum für Luft- und Raumfahrt (DLR), 51170 Köln, Germany.
- Autoren
- Dieter M Herlach
- Thomas Palberg
- Ina Klassen
- Stefan Klein
- Raphael Kobold
- DOI
- 10.1063/1.4963684
- eISSN
- 1089-7690
- Externe Identifier
- PubMed Identifier: 28799394
- Funding acknowledgements
- Deutsche Forschungsgemeinschaft: HE1601/24
- Deutsche Forschungsgemeinschaft: Pa459/16
- European Space Agency: 15236/02/NL/SH
- Deutsche Forschungsgemeinschaft: HE1601/21
- Deutsche Forschungsgemeinschaft: Pa459/17
- German Aerospace Center Space Management: 50WM1140
- Open access
- false
- ISSN
- 0021-9606
- Ausgabe der Veröffentlichung
- 21
- Zeitschrift
- The Journal of chemical physics
- Sprache
- eng
- Medium
- Paginierung
- 211703
- Datum der Veröffentlichung
- 2016
- Status
- Published
- Datum der Datenerfassung
- 2017
- Titel
- Overview: Experimental studies of crystal nucleation: Metals and colloids.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 145
Datenquelle: Europe PubMed Central
- Abstract
- Crystallization is one of the most important phase transformations of first order. In the case of metals and alloys, the liquid phase is the parent phase of materials production. The conditions of the crystallization process control the as-solidified material in its chemical and physical properties. Nucleation initiates the crystallization of a liquid. It selects the crystallographic phase, stable or meta-stable. Its detailed knowledge is therefore mandatory for the design of materials. We present techniques of containerless processing for nucleation studies of metals and alloys. Experimental results demonstrate the power of these methods not only for crystal nucleation of stable solids but in particular also for investigations of crystal nucleation of metastable solids at extreme undercooling. This concerns the physical nature of heterogeneous versus homogeneous nucleation and nucleation of phases nucleated under non-equilibrium conditions. The results are analyzed within classical nucleation theory that defines the activation energy of homogeneous nucleation in terms of the interfacial energy and the difference of Gibbs free energies of solid and liquid. The interfacial energy acts as barrier for the nucleation process. Its experimental determination is difficult in the case of metals. In the second part of this work we therefore explore the potential of colloidal suspensions as model systems for the crystallization process. The nucleation process of colloids is observed in situ by optical observation and ultra-small angle X-ray diffraction using high intensity synchrotron radiation. It allows an unambiguous discrimination of homogeneous and heterogeneous nucleation as well as the determination of the interfacial free energy of the solid-liquid interface. Our results are used to construct Turnbull plots of colloids, which are discussed in relation to Turnbull plots of metals and support the hypothesis that colloids are useful model systems to investigate crystal nucleation.
- Autoren
- Dieter M Herlach
- Thomas Palberg
- Ina Klassen
- Stefan Klein
- Raphael Kobold
- Autoren-URL
- https://www.ncbi.nlm.nih.gov/pubmed/28799394
- DOI
- 10.1063/1.4963684
- eISSN
- 1089-7690
- Ausgabe der Veröffentlichung
- 21
- Zeitschrift
- J Chem Phys
- Sprache
- eng
- Country
- United States
- Paginierung
- 211703
- Datum der Veröffentlichung
- 2016
- Status
- Published
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2018
- Titel
- Overview: Experimental studies of crystal nucleation: Metals and colloids.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 145
Datenquelle: PubMed
- Abstract
- Crystallization is one of the most important phase transformations of first order. In the case of metals and alloys, the liquid phase is the parent phase of materials production. The conditions of the crystallization process control the as-solidified material in its chemical and physical properties. Nucleation initiates the crystallization of a liquid. It selects the crystallographic phase, stable or meta-stable. Its detailed knowledge is therefore mandatory for the design of materials. We present techniques of containerless processing for nucleation studies of metals and alloys. We demonstrate the power of these methods for crystal nucleation of stable solids but in particular also for investigations of crystal nucleation of metastable solids at extreme undercooling. This concerns the issue of heterogeneous versus homogeneous nucleation and non-equilibrium conditions. The results are analyzed within classical nucleation theory, where the activation energy of homogeneous nucleation depends on the interfacial energy and the difference of Gibbs free energies of solid and liquid. The interfacial energy acts as barrier for the nucleation process. Its experimental determination is difficult in the case of metals. In the second part of this work we therefore explore the use of colloidal suspensions as models for the crystallization process. Their nucleation process is observed in situ by optical techniques and ultra-small angle X-ray diffraction using high intensity synchrotron radiation. It allows an unambiguous discrimination of homogeneous and heterogeneous nucleation as well as the determination of the interfacial free energy of the solid-liquid interface. Our results are used to construct Turnbull plots of colloids, which are discussed in relation to Turnbull plots of metals and support the hypothesis that colloids are useful model systems to investigate crystal nucleation.
- Autoren
- Diter M Herlach
- Thomas Palberg
- Autoren-URL
- http://arxiv.org/abs/1605.03511v2
- Schlüsselwörter
- cond-mat.mtrl-sci
- cond-mat.mtrl-sci
- Notes
- Invited review submitted for a special issue of J. Chem. Phys. "Overview Articles - Special Topic: Nucleation: New Concepts and Discoveries on the physics of nucleation". Submitted 2016 May 10. 61 pages 189 References 25 Figures. Abstract above is slightly shoretened to match ArXive rules v2 - added reprint permissions to all figures
- Datum der Veröffentlichung
- 2016
- Herausgeber URL
- http://dx.doi.org/10.1063/1.4963684
- Datum der Datenerfassung
- 2016
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2016
- Titel
- Experimental studies of crystal nucleation: metals and colloids
Files
1605.03511v2.pdf
Datenquelle: arXiv
- Abstract
- Crystallization is one of the most important phase transformations of first order. In the case of metals and alloys, the liquid phase is the parent phase of materials production. The conditions of the crystallization process control the as-solidified material in its chemical and physical properties. Nucleation initiates the crystallization of a liquid. It selects the crystallographic phase, stable or meta-stable. Its detailed knowledge is therefore mandatory for the design of materials. We present techniques of containerless processing for nucleation studies of metals and alloys. We demonstrate the power of these methods for crystal nucleation of stable solids but in particular also for investigations of crystal nucleation of metastable solids at extreme undercooling. This concerns the issue of heterogeneous versus homogeneous nucleation and non-equilibrium conditions. The results are analyzed within classical nucleation theory, where the activation energy of homogeneous nucleation depends on the interfacial energy and the difference of Gibbs free energies of solid and liquid. The interfacial energy acts as barrier for the nucleation process. Its experimental determination is difficult in the case of metals. In the second part of this work we therefore explore the use of colloidal suspensions as models for the crystallization process. Their nucleation process is observed in situ by optical techniques and ultra-small angle X-ray diffraction using high intensity synchrotron radiation. It allows an unambiguous discrimination of homogeneous and heterogeneous nucleation as well as the determination of the interfacial free energy of the solid-liquid interface. Our results are used to construct Turnbull plots of colloids, which are discussed in relation to Turnbull plots of metals and support the hypothesis that colloids are useful model systems to investigate crystal nucleation.
- Autoren
- Diter M Herlach
- Thomas Palberg
- DOI
- 10.1063/1.4963684
- ISSN
- 0021-9606
- Zeitschrift
- The Journal of Chemical Physics
- Notes
- keywords: Physics - Materials Science file: https://arxiv.org/pdf/1605.03511v2.pdf file: https://arxiv.org/pdf/1605.03511v2.pdf
- Artikelnummer
- 21
- Paginierung
- 211703 - 211703
- Datum der Veröffentlichung
- 2016
- Herausgeber URL
- http://arxiv.org/pdf/1605.03511v2
- Datum der Datenerfassung
- 2020
- Titel
- Experimental studies of crystal nucleation: metals and colloids
- Sub types
- article
- Ausgabe der Zeitschrift
- 145
Datenquelle: Manual
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