Hydrogenation Catalysis by Hydrogen Spillover on Platinum-Functionalized Heterogeneous Boronic Acid-Polyoxometalates
- Publikationstyp:
- Zeitschriftenaufsatz
- Metadaten:
-
- Autoren
- Shujun Li
- Yubin Ma
- Yue Zhao
- Rongji Liu
- Yupeng Zhao
- Xusheng Dai
- Nana Ma
- Carsten Streb
- Xuenian Chen
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:001100709400001&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1002/anie.202314999
- eISSN
- 1521-3773
- Externe Identifier
- Clarivate Analytics Document Solution ID: CR5A4
- PubMed Identifier: 37889729
- ISSN
- 1433-7851
- Ausgabe der Veröffentlichung
- 50
- Zeitschrift
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Schlüsselwörter
- Boronic Acid
- Hydrogen Spillover
- Polyoxometalate
- Self-Assembly
- Supramolecular
- Datum der Veröffentlichung
- 2023
- Status
- Published
- Titel
- Hydrogenation Catalysis by Hydrogen Spillover on Platinum-Functionalized Heterogeneous Boronic Acid-Polyoxometalates
- Sub types
- Article
- Ausgabe der Zeitschrift
- 62
Datenquelle: Web of Science (Lite)
- Andere Metadatenquellen:
-
- Abstract
- <jats:title>Abstract</jats:title><jats:p>The activation of molecular hydrogen is a key process in catalysis. Here, we demonstrate how polyoxometalate (POM)‐based heterogeneous compounds functionalized with Platinum particles activate H<jats:sub>2</jats:sub> by synergism between a hydrogen spillover mechanism and electron‐proton transfer by the POM. This interplay facilitates the selective catalytic reduction of olefins and nitroarenes with high functional group tolerance. A family of polyoxotungstates covalently functionalized with boronic acids is reported. In the solid‐state, the compounds are held together by non‐covalent interactions (π–π stacking and hydrogen bonding). The resulting heterogeneous nanoscale particles form stable colloidal dispersions in acetonitrile and can be surface‐functionalized with platinum nanoparticles by in situ photoreduction. The resulting materials show excellent catalytic activity in hydrogenation of olefins and nitrobenzene derivatives under mild conditions (1 bar H<jats:sub>2</jats:sub> and room temperature).</jats:p>
- Autoren
- Shujun Li
- Yubin Ma
- Yue Zhao
- Rongji Liu
- Yupeng Zhao
- Xusheng Dai
- Nana Ma
- Carsten Streb
- Xuenian Chen
- DOI
- 10.1002/anie.202314999
- eISSN
- 1521-3773
- ISSN
- 1433-7851
- Ausgabe der Veröffentlichung
- 50
- Zeitschrift
- Angewandte Chemie International Edition
- Sprache
- en
- Online publication date
- 2023
- Datum der Veröffentlichung
- 2023
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/anie.202314999
- Datum der Datenerfassung
- 2023
- Titel
- Hydrogenation Catalysis by Hydrogen Spillover on Platinum‐Functionalized Heterogeneous Boronic Acid‐Polyoxometalates
- Ausgabe der Zeitschrift
- 62
Datenquelle: Crossref
- Abstract
- The activation of molecular hydrogen is a key process in catalysis. Here, we demonstrate how polyoxometalate (POM)-based heterogeneous compounds functionalized with Platinum particles activate H<sub>2</sub> by synergism between a hydrogen spillover mechanism and electron-proton transfer by the POM. This interplay facilitates the selective catalytic reduction of olefins and nitroarenes with high functional group tolerance. A family of polyoxotungstates covalently functionalized with boronic acids is reported. In the solid-state, the compounds are held together by non-covalent interactions (π-π stacking and hydrogen bonding). The resulting heterogeneous nanoscale particles form stable colloidal dispersions in acetonitrile and can be surface-functionalized with platinum nanoparticles by in situ photoreduction. The resulting materials show excellent catalytic activity in hydrogenation of olefins and nitrobenzene derivatives under mild conditions (1 bar H<sub>2</sub> and room temperature).
- Addresses
- Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, 453007, China.
- Autoren
- Shujun Li
- Yubin Ma
- Yue Zhao
- Rongji Liu
- Yupeng Zhao
- Xusheng Dai
- Nana Ma
- Carsten Streb
- Xuenian Chen
- DOI
- 10.1002/anie.202314999
- eISSN
- 1521-3773
- Externe Identifier
- PubMed Identifier: 37889729
- Funding acknowledgements
- Science and Technology Innovation Talents in Universities of Henan Province: 23HASTIT005
- Ministeriums für Wissenschaft, Weiterbildung und Kultur, Rheinland-Pfalz: SusInnoScience
- Deutsche Forschungsgemeinschaft: 364549901; SFB1633
- National Natural Science Foundation of China: 22171073; 22171246
- Open access
- false
- ISSN
- 1433-7851
- Ausgabe der Veröffentlichung
- 50
- Zeitschrift
- Angewandte Chemie (International ed. in English)
- Sprache
- eng
- Medium
- Print-Electronic
- Online publication date
- 2023
- Paginierung
- e202314999
- Datum der Veröffentlichung
- 2023
- Status
- Published
- Publisher licence
- CC BY
- Datum der Datenerfassung
- 2023
- Titel
- Hydrogenation Catalysis by Hydrogen Spillover on Platinum-Functionalized Heterogeneous Boronic Acid-Polyoxometalates.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 62
Datenquelle: Europe PubMed Central
- Abstract
- The activation of molecular hydrogen is a key process in catalysis. Here, we demonstrate how polyoxometalate (POM)-based heterogeneous compounds functionalized with Platinum particles activate H2 by synergism between a hydrogen spillover mechanism and electron-proton transfer by the POM. This interplay facilitates the selective catalytic reduction of olefins and nitroarenes with high functional group tolerance. A family of polyoxotungstates covalently functionalized with boronic acids is reported. In the solid-state, the compounds are held together by non-covalent interactions (π-π stacking and hydrogen bonding). The resulting heterogeneous nanoscale particles form stable colloidal dispersions in acetonitrile and can be surface-functionalized with platinum nanoparticles by in situ photoreduction. The resulting materials show excellent catalytic activity in hydrogenation of olefins and nitrobenzene derivatives under mild conditions (1 bar H2 and room temperature).
- Autoren
- Shujun Li
- Yubin Ma
- Yue Zhao
- Rongji Liu
- Yupeng Zhao
- Xusheng Dai
- Nana Ma
- Carsten Streb
- Xuenian Chen
- Autoren-URL
- https://www.ncbi.nlm.nih.gov/pubmed/37889729
- DOI
- 10.1002/anie.202314999
- eISSN
- 1521-3773
- Funding acknowledgements
- National Natural Science Foundation of China: 22171073; 22171246
- Science and Technology Innovation Talents in Universities of Henan Province: 23HASTIT005
- Ministeriums für Wissenschaft, Weiterbildung und Kultur, Rheinland-Pfalz: SusInnoScience
- Deutsche Forschungsgemeinschaft: 364549901; SFB1633
- Ausgabe der Veröffentlichung
- 50
- Zeitschrift
- Angew Chem Int Ed Engl
- Schlüsselwörter
- Boronic Acid
- Hydrogen Spillover
- Polyoxometalate
- Self-Assembly
- Supramolecular
- Sprache
- eng
- Country
- Germany
- Paginierung
- e202314999
- Datum der Veröffentlichung
- 2023
- Status
- Published
- Titel
- Hydrogenation Catalysis by Hydrogen Spillover on Platinum-Functionalized Heterogeneous Boronic Acid-Polyoxometalates.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 62
Datenquelle: PubMed
- Author's licence
- CC-BY
- Autoren
- Shujun Li
- Yubin Ma
- Yue Zhao
- Rongji Liu
- Yupeng Zhao
- Xusheng Dai
- Nana Ma
- Carsten Streb
- Xuenian Chen
- Hosting institution
- Universitätsbibliothek Mainz
- Sammlungen
- DFG-491381577-H
- Resource version
- Published version
- DOI
- 10.1002/anie.202314999
- File(s) embargoed
- false
- Open access
- true
- ISSN
- 1521-3773
- Zeitschrift
- Angewandte Chemie : international edition
- Schlüsselwörter
- 540 Chemie
- 540 Chemistry and allied sciences
- Sprache
- eng
- Open access status
- Open Access
- Paginierung
- e202314999
- Datum der Veröffentlichung
- 2023
- Public URL
- https://openscience.ub.uni-mainz.de/handle/20.500.12030/9777
- Herausgeber
- Wiley-VCH
- Datum der Datenerfassung
- 2023
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2023
- Zugang
- Public
- Titel
- Hydrogenation catalysis by hydrogen spillover on platinum-functionalized heterogeneous boronic acid-polyoxometalates
- Ausgabe der Zeitschrift
- Version of Record (VoR)
Files
hydrogenation_catalysis_by_hy-20231206105458051.pdf
Datenquelle: OPENSCIENCE.UB
- Beziehungen:
- Eigentum von