Single-Chain Folding of Polymers for Catalytic Systems in Water
- Publikationstyp:
- Zeitschriftenaufsatz
- Metadaten:
-
- Autoren
- Takaya Terashima
- Tristan Mes
- Tom FA De Greef
- Martijn AJ Gillissen
- Pol Besenius
- Anja RA Palmans
- EW Meijer
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000289492700022&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1021/ja2004494
- Externe Identifier
- Clarivate Analytics Document Solution ID: 749TJ
- PubMed Identifier: 21405022
- ISSN
- 0002-7863
- Ausgabe der Veröffentlichung
- 13
- Zeitschrift
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Paginierung
- 4742 - 4745
- Datum der Veröffentlichung
- 2011
- Status
- Published
- Titel
- Single-Chain Folding of Polymers for Catalytic Systems in Water
- Sub types
- Article
- Ausgabe der Zeitschrift
- 133
Datenquelle: Web of Science (Lite)
- Andere Metadatenquellen:
-
- Autoren
- Takaya Terashima
- Tristan Mes
- Tom FA De Greef
- Martijn AJ Gillissen
- Pol Besenius
- Anja RA Palmans
- EW Meijer
- DOI
- 10.1021/ja2004494
- eISSN
- 1520-5126
- ISSN
- 0002-7863
- Ausgabe der Veröffentlichung
- 13
- Zeitschrift
- Journal of the American Chemical Society
- Sprache
- en
- Online publication date
- 2011
- Paginierung
- 4742 - 4745
- Datum der Veröffentlichung
- 2011
- Status
- Published
- Herausgeber
- American Chemical Society (ACS)
- Herausgeber URL
- http://dx.doi.org/10.1021/ja2004494
- Datum der Datenerfassung
- 2023
- Titel
- Single-Chain Folding of Polymers for Catalytic Systems in Water
- Ausgabe der Zeitschrift
- 133
Datenquelle: Crossref
- Abstract
- Enzymes are a source of inspiration for chemists attempting to create versatile synthetic catalysts. In order to arrive at a polymeric chain carrying catalytic units separated spatially, it is a prerequisite to fold these polymers in water into well-defined compartmentalized architectures thus creating a catalytic core. Herein, we report the synthesis, physical properties, and catalytic activity of a water-soluble segmented terpolymer in which a helical structure in the apolar core is created around a ruthenium-based catalyst. The supramolecular chirality of this catalytic system is the result of the self-assembly of benzene-1,3,5-tricarboxamide side chains, while the catalyst arises from the sequential ruthenium-catalyzed living radical polymerization of the different monomers followed by ligand exchange. The polymers exhibit a two-state folding process and show transfer hydrogenation in water.
- Addresses
- Institute for Complex Molecular Systems, Laboratory of Macromolecular and Organic Chemistry, Laboratory of Chemical Biology, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.
- Autoren
- Takaya Terashima
- Tristan Mes
- Tom FA De Greef
- Martijn AJ Gillissen
- Pol Besenius
- Anja RA Palmans
- EW Meijer
- DOI
- 10.1021/ja2004494
- eISSN
- 1520-5126
- Externe Identifier
- PubMed Identifier: 21405022
- Open access
- false
- ISSN
- 0002-7863
- Ausgabe der Veröffentlichung
- 13
- Zeitschrift
- Journal of the American Chemical Society
- Schlüsselwörter
- Ruthenium
- Water
- Benzamides
- Organometallic Compounds
- Polymers
- Molecular Structure
- Catalysis
- Hydrogen Bonding
- Particle Size
- Solubility
- Surface Properties
- Sprache
- eng
- Medium
- Print-Electronic
- Online publication date
- 2011
- Paginierung
- 4742 - 4745
- Datum der Veröffentlichung
- 2011
- Status
- Published
- Datum der Datenerfassung
- 2011
- Titel
- Single-chain folding of polymers for catalytic systems in water.
- Sub types
- Research Support, Non-U.S. Gov't
- Journal Article
- Ausgabe der Zeitschrift
- 133
Datenquelle: Europe PubMed Central
- Abstract
- Enzymes are a source of inspiration for chemists attempting to create versatile synthetic catalysts. In order to arrive at a polymeric chain carrying catalytic units separated spatially, it is a prerequisite to fold these polymers in water into well-defined compartmentalized architectures thus creating a catalytic core. Herein, we report the synthesis, physical properties, and catalytic activity of a water-soluble segmented terpolymer in which a helical structure in the apolar core is created around a ruthenium-based catalyst. The supramolecular chirality of this catalytic system is the result of the self-assembly of benzene-1,3,5-tricarboxamide side chains, while the catalyst arises from the sequential ruthenium-catalyzed living radical polymerization of the different monomers followed by ligand exchange. The polymers exhibit a two-state folding process and show transfer hydrogenation in water.
- Autoren
- Takaya Terashima
- Tristan Mes
- Tom FA De Greef
- Martijn AJ Gillissen
- Pol Besenius
- Anja RA Palmans
- EW Meijer
- Autoren-URL
- https://www.ncbi.nlm.nih.gov/pubmed/21405022
- DOI
- 10.1021/ja2004494
- eISSN
- 1520-5126
- Ausgabe der Veröffentlichung
- 13
- Zeitschrift
- J Am Chem Soc
- Schlüsselwörter
- Benzamides
- Catalysis
- Hydrogen Bonding
- Molecular Structure
- Organometallic Compounds
- Particle Size
- Polymers
- Ruthenium
- Solubility
- Surface Properties
- Water
- Sprache
- eng
- Country
- United States
- Paginierung
- 4742 - 4745
- Datum der Veröffentlichung
- 2011
- Status
- Published
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2011
- Titel
- Single-chain folding of polymers for catalytic systems in water.
- Sub types
- Journal Article
- Research Support, Non-U.S. Gov't
- Ausgabe der Zeitschrift
- 133
Datenquelle: PubMed
- Beziehungen:
-