New Methods for the Functionalization of Polymer Matrices with Thiomolybdate Clusters Applied for Hydrogen Evolution Reaction Catalysis

Publikationstyp:
Zeitschriftenaufsatz
Metadaten:
Autoren
  • Nadine Hannewald
  • Julian Hniopek
  • Magdalena Heiland
  • Stefan Zechel
  • Michael Schmitt
  • Carsten Streb
  • Juergen Popp
  • Martin D Hager
  • Ulrich S Schubert
Autoren-URL
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000783863100013&DestLinkType=FullRecord&DestApp=WOS_CPL
DOI
10.1002/aesr.202100085
Externe Identifier
  • Clarivate Analytics Document Solution ID: 0O9SH
ISSN
2699-9412
Ausgabe der Veröffentlichung
11
Zeitschrift
ADVANCED ENERGY AND SUSTAINABILITY RESEARCH
Schlüsselwörter
  • hydrogen evolution reaction
  • hydrogen generation
  • polymer catalysts
Artikelnummer
ARTN 2100085
Datum der Veröffentlichung
2021
Status
Published
Titel
New Methods for the Functionalization of Polymer Matrices with Thiomolybdate Clusters Applied for Hydrogen Evolution Reaction Catalysis
Sub types
  • Article
Ausgabe der Zeitschrift
2

Datenquelle: Web of Science (Lite)

Andere Metadatenquellen:
Abstract
<jats:sec><jats:label /><jats:p>The embedding of molecular reactive species such as catalysts into polymers opens up new avenues for advanced composite design for energy technologies and beyond. Herein, two new approaches for the connection of molecular molybdenum sulfide clusters and synthetic polymers are presented. The approach one is based on the utilization of a molecular molybdenum sulfide cluster as a potential chain transfer agent in a free radical polymerization process. The second one is a postpolymerization functionalization of a thiol end‐functionalized polymer with a thiomolybdate cluster. Detailed characterization using Raman spectroscopy reveals the successful functionalization in the latter approach, whereas in the other one, a noncovalent interaction is suggested. Furthermore, visible light‐driven hydrogen evolution demonstrates that the molecular molybdenum sulfide cluster retains its catalytic activity after the combination with polymers.</jats:p></jats:sec>
Autoren
  • Nadine Hannewald
  • Julian Hniopek
  • Magdalena Heiland
  • Stefan Zechel
  • Michael Schmitt
  • Carsten Streb
  • Jürgen Popp
  • Martin D Hager
  • Ulrich S Schubert
DOI
10.1002/aesr.202100085
eISSN
2699-9412
ISSN
2699-9412
Ausgabe der Veröffentlichung
11
Zeitschrift
Advanced Energy and Sustainability Research
Sprache
en
Online publication date
2021
Datum der Veröffentlichung
2021
Status
Published
Herausgeber
Wiley
Herausgeber URL
http://dx.doi.org/10.1002/aesr.202100085
Datum der Datenerfassung
2023
Titel
New Methods for the Functionalization of Polymer Matrices with Thiomolybdate Clusters Applied for Hydrogen Evolution Reaction Catalysis
Ausgabe der Zeitschrift
2

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