Selective Electrochemical Dibromination of Terpenes and Naturally Derived Olefins
- Publikationstyp:
- Zeitschriftenaufsatz
- Metadaten:
-
- Abstract
- <jats:title>Abstract</jats:title><jats:p>A simple electrochemical protocol is established for the selective alkene dibromination of naturally derived olefins, such as terpenes. The use of hazardous Br<jats:sub>2</jats:sub> or its analogues have been elegantly avoided by employing readily available, inexpensive, and harmless sodium bromide with a dual role as reagent and supporting electrolyte in combination with sustainable carbon‐based electrodes. This electrochemical protocol provides the desired products with good to excellent yields up to 82 % with 10 examples. Scalability has been proved by a 5‐fold scale‐up. Notably, higher yields and selectivity were achieved in comparison to conventional bromination by Br<jats:sub>2</jats:sub> and DMSO/HBr system and the dibrominated compound was eligible for further functionalization, such as cyanation according to the Kolbe nitrile synthesis protocol.</jats:p>
- Autoren
- Lilla G Gombos
- Leo Werner
- Dieter Schollmeyer
- Carlos A Martínez‐Huitle
- Siegfried R Waldvogel
- DOI
- 10.1002/ejoc.202200857
- eISSN
- 1099-0690
- ISSN
- 1434-193X
- Ausgabe der Veröffentlichung
- 47
- Zeitschrift
- European Journal of Organic Chemistry
- Sprache
- en
- Online publication date
- 2022
- Datum der Veröffentlichung
- 2022
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/ejoc.202200857
- Datum der Datenerfassung
- 2023
- Titel
- Selective Electrochemical Dibromination of Terpenes and Naturally Derived Olefins
- Ausgabe der Zeitschrift
- 2022
Datenquelle: Crossref
- Andere Metadatenquellen:
-
- Author's licence
- CC-BY-NC-ND
- Autoren
- Lilla G Gombos
- Leo Werner
- Dieter Schollmeyer
- Carlos A Martínez-Huitle
- Siegfried R Waldvogel
- Hosting institution
- Universitätsbibliothek Mainz
- Sammlungen
- DFG-491381577-H
- Resource version
- Published version
- DOI
- 10.1002/ejoc.202200857
- Funding acknowledgements
- Gefördert durch die Deutsche Forschungsgemeinschaft (DFG) - Projektnummer 491381577
- File(s) embargoed
- false
- Open access
- true
- ISSN
- 1099-0690
- Ausgabe der Veröffentlichung
- 47
- Zeitschrift
- European journal of organic chemistry
- Schlüsselwörter
- 540 Chemie
- 540 Chemistry and allied sciences
- Sprache
- eng
- Open access status
- Open Access
- Paginierung
- e202200857
- Datum der Veröffentlichung
- 2022
- Public URL
- https://openscience.ub.uni-mainz.de/handle/20.500.12030/8711
- Herausgeber
- Wiley VCZ
- Datum der Datenerfassung
- 2023
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2023
- Zugang
- Public
- Titel
- Selective electrochemical dibromination of terpenes and naturally derived olefins
- Ausgabe der Zeitschrift
- 2022
Files
selective_electrochemical_dib-20230130110343444.pdf
Datenquelle: OPENSCIENCE.UB