"Bottom-Up" Meets "Top-Down" Assembly in Nanoscale Polyoxometalate Clusters: Self-Assembly of [P4W52O178]24- and Disassembly to [P3W39O134]19-

Publikationstyp:
Zeitschriftenaufsatz
Metadaten:
Autoren
  • Chullikkattil P Pradeep
  • De-Liang Long
  • Carsten Streb
  • Leroy Cronin
Autoren-URL
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000260682300022&DestLinkType=FullRecord&DestApp=WOS_CPL
DOI
10.1021/ja806596j
Externe Identifier
  • Clarivate Analytics Document Solution ID: 369GK
  • PubMed Identifier: 18937461
ISSN
0002-7863
Ausgabe der Veröffentlichung
45
Zeitschrift
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Paginierung
14946 - +
Datum der Veröffentlichung
2008
Status
Published
Titel
"Bottom-Up" Meets "Top-Down" Assembly in Nanoscale Polyoxometalate Clusters: Self-Assembly of [P<sub>4</sub>W<sub>52</sub>O<sub>178</sub>]<SUP>24-</SUP> and Disassembly to [P<sub>3</sub>W<sub>39</sub>O<sub>134</sub>]<SUP>19-</SUP>
Sub types
  • Article
Ausgabe der Zeitschrift
130

Datenquelle: Web of Science (Lite)

Andere Metadatenquellen:
Autoren
  • Chullikkattil P Pradeep
  • De-Liang Long
  • Carsten Streb
  • Leroy Cronin
DOI
10.1021/ja806596j
eISSN
1520-5126
ISSN
0002-7863
Ausgabe der Veröffentlichung
45
Zeitschrift
Journal of the American Chemical Society
Sprache
en
Online publication date
2008
Paginierung
14946 - 14947
Datum der Veröffentlichung
2008
Status
Published
Herausgeber
American Chemical Society (ACS)
Herausgeber URL
http://dx.doi.org/10.1021/ja806596j
Datum der Datenerfassung
2024
Titel
“Bottom-Up” Meets “Top-Down” Assembly in Nanoscale Polyoxometalate Clusters: Self-Assembly of [P<sub>4</sub>W<sub>52</sub>O<sub>178</sub>]<sup>24−</sup>and Disassembly to [P<sub>3</sub>W<sub>39</sub>O<sub>134</sub>]<sup>19−</sup>
Ausgabe der Zeitschrift
130

Datenquelle: Crossref

Abstract
The pH-controlled assembly/disassembly of a nanoscale {P4W52O178}24- cluster at pH 2 to a {P4W44O152}20- cluster at pH 3-5 via a {P3W39O134}19- cluster species at pH 2-3 to finally give {P2W19O69(OH2)}14- at pH 6 is reported. This process can be traced in the solid state crystallographically and in solution using dynamic light scattering studies.
Addresses
  • WestCHEM, Department of Chemistry, The University of Glasgow, Glasgow G12 8QQ, UK.
Autoren
  • Chullikkattil P Pradeep
  • De-Liang Long
  • Carsten Streb
  • Leroy Cronin
DOI
10.1021/ja806596j
eISSN
1520-5126
Externe Identifier
  • PubMed Identifier: 18937461
Funding acknowledgements
  • Engineering and Physical Sciences Research Council: EP/F009410/1
  • Engineering and Physical Sciences Research Council: EP/C542819/1
Open access
false
ISSN
0002-7863
Ausgabe der Veröffentlichung
45
Zeitschrift
Journal of the American Chemical Society
Schlüsselwörter
  • Phosphotungstic Acid
  • Anions
  • Phosphorus Compounds
  • Tungsten Compounds
  • Crystallography, X-Ray
  • Hydrogen-Ion Concentration
  • Models, Molecular
  • Nanostructures
Sprache
eng
Medium
Print-Electronic
Online publication date
2008
Paginierung
14946 - 14947
Datum der Veröffentlichung
2008
Status
Published
Datum der Datenerfassung
2008
Titel
"Bottom-up" meets "top-down" assembly in nanoscale polyoxometalate clusters: self-assembly of [P4W52O178](24-) and disassembly to [P3W39O134](19-).
Sub types
  • Research Support, Non-U.S. Gov't
  • Journal Article
Ausgabe der Zeitschrift
130

Datenquelle: Europe PubMed Central

Abstract
The pH-controlled assembly/disassembly of a nanoscale {P4W52O178}24- cluster at pH 2 to a {P4W44O152}20- cluster at pH 3-5 via a {P3W39O134}19- cluster species at pH 2-3 to finally give {P2W19O69(OH2)}14- at pH 6 is reported. This process can be traced in the solid state crystallographically and in solution using dynamic light scattering studies.
Autoren
  • Chullikkattil P Pradeep
  • De-Liang Long
  • Carsten Streb
  • Leroy Cronin
Autoren-URL
https://www.ncbi.nlm.nih.gov/pubmed/18937461
DOI
10.1021/ja806596j
eISSN
1520-5126
Ausgabe der Veröffentlichung
45
Zeitschrift
J Am Chem Soc
Schlüsselwörter
  • Anions
  • Crystallography, X-Ray
  • Hydrogen-Ion Concentration
  • Models, Molecular
  • Nanostructures
  • Phosphorus Compounds
  • Phosphotungstic Acid
  • Tungsten Compounds
Sprache
eng
Country
United States
Paginierung
14946 - 14947
Datum der Veröffentlichung
2008
Status
Published
Datum, an dem der Datensatz öffentlich gemacht wurde
2008
Titel
"Bottom-up" meets "top-down" assembly in nanoscale polyoxometalate clusters: self-assembly of [P4W52O178](24-) and disassembly to [P3W39O134](19-).
Sub types
  • Journal Article
  • Research Support, Non-U.S. Gov't
Ausgabe der Zeitschrift
130

Datenquelle: PubMed

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