Controlled Reactivity Tuning of Metal-Functionalized Vanadium Oxide Clusters
- Publikationstyp:
- Zeitschriftenaufsatz
- Metadaten:
-
- Autoren
- Katharina Kastner
- Johannes Forster
- Hiromichi Ida
- Graham N Newton
- Hiroki Oshio
- Carsten Streb
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000354204300007&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1002/chem.201501049
- eISSN
- 1521-3765
- Externe Identifier
- Clarivate Analytics Document Solution ID: CH7GQ
- PubMed Identifier: 25850969
- ISSN
- 0947-6539
- Ausgabe der Veröffentlichung
- 21
- Zeitschrift
- CHEMISTRY-A EUROPEAN JOURNAL
- Schlüsselwörter
- mass spectrometry
- metal oxides
- metal-functionalization
- polyoxometalates
- self-assembly
- Paginierung
- 7686 - 7689
- Datum der Veröffentlichung
- 2015
- Status
- Published
- Titel
- Controlled Reactivity Tuning of Metal-Functionalized Vanadium Oxide Clusters
- Sub types
- Article
- Ausgabe der Zeitschrift
- 21
Datenquelle: Web of Science (Lite)
- Andere Metadatenquellen:
-
- Abstract
- <jats:title>Abstract</jats:title><jats:p>Controlling the assembly and functionalization of molecular metal oxides [M<jats:sub><jats:italic>x</jats:italic></jats:sub>O<jats:sub><jats:italic>y</jats:italic></jats:sub>]<jats:sup><jats:italic>n−</jats:italic></jats:sup> (M=Mo, W, V) allows the targeted design of functional molecular materials. While general methods exist that enable the predetermined functionalization of tungstates and molybdates, no such routes are available for molecular vanadium oxides. Controlled design of polyoxovanadates, however, would provide highly active materials for energy conversion, (photo‐) catalysis, molecular magnetism, and materials science. To this end, a new approach has been developed that allows the reactivity tuning of vanadium oxide clusters by selective metal functionalization. Organic, hydrogen‐bonding cations, for example, dimethylammonium are used as molecular placeholders to block metal binding sites within vanadate cluster shells. Stepwise replacement of the placeholder cations with reactive metal cations gives mono‐ and difunctionalized clusters. Initial reactivity studies illustrate the tunability of the magnetic, redox, and catalytic activity.</jats:p>
- Autoren
- Katharina Kastner
- Johannes Forster
- Hiromichi Ida
- Graham N Newton
- Hiroki Oshio
- Carsten Streb
- DOI
- 10.1002/chem.201501049
- eISSN
- 1521-3765
- ISSN
- 0947-6539
- Ausgabe der Veröffentlichung
- 21
- Zeitschrift
- Chemistry – A European Journal
- Sprache
- en
- Online publication date
- 2015
- Paginierung
- 7686 - 7689
- Datum der Veröffentlichung
- 2015
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/chem.201501049
- Datum der Datenerfassung
- 2023
- Titel
- Controlled Reactivity Tuning of Metal‐Functionalized Vanadium Oxide Clusters
- Ausgabe der Zeitschrift
- 21
Datenquelle: Crossref
- Abstract
- Controlling the assembly and functionalization of molecular metal oxides [Mx Oy ](n-) (M=Mo, W, V) allows the targeted design of functional molecular materials. While general methods exist that enable the predetermined functionalization of tungstates and molybdates, no such routes are available for molecular vanadium oxides. Controlled design of polyoxovanadates, however, would provide highly active materials for energy conversion, (photo-) catalysis, molecular magnetism, and materials science. To this end, a new approach has been developed that allows the reactivity tuning of vanadium oxide clusters by selective metal functionalization. Organic, hydrogen-bonding cations, for example, dimethylammonium are used as molecular placeholders to block metal binding sites within vanadate cluster shells. Stepwise replacement of the placeholder cations with reactive metal cations gives mono- and difunctionalized clusters. Initial reactivity studies illustrate the tunability of the magnetic, redox, and catalytic activity.
- Addresses
- Institute of Inorganic Chemistry, Ulm University, Albert-Einstein-Allee 11, 89081 Ulm (Germany) http://www.strebgroup.net.
- Autoren
- Katharina Kastner
- Johannes Forster
- Hiromichi Ida
- Graham N Newton
- Hiroki Oshio
- Carsten Streb
- DOI
- 10.1002/chem.201501049
- eISSN
- 1521-3765
- Externe Identifier
- PubMed Identifier: 25850969
- Open access
- false
- ISSN
- 0947-6539
- Ausgabe der Veröffentlichung
- 21
- Zeitschrift
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Sprache
- eng
- Medium
- Print-Electronic
- Online publication date
- 2015
- Paginierung
- 7686 - 7689
- Datum der Veröffentlichung
- 2015
- Status
- Published
- Datum der Datenerfassung
- 2015
- Titel
- Controlled reactivity tuning of metal-functionalized vanadium oxide clusters.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 21
Datenquelle: Europe PubMed Central
- Abstract
- Controlling the assembly and functionalization of molecular metal oxides [Mx Oy ](n-) (M=Mo, W, V) allows the targeted design of functional molecular materials. While general methods exist that enable the predetermined functionalization of tungstates and molybdates, no such routes are available for molecular vanadium oxides. Controlled design of polyoxovanadates, however, would provide highly active materials for energy conversion, (photo-) catalysis, molecular magnetism, and materials science. To this end, a new approach has been developed that allows the reactivity tuning of vanadium oxide clusters by selective metal functionalization. Organic, hydrogen-bonding cations, for example, dimethylammonium are used as molecular placeholders to block metal binding sites within vanadate cluster shells. Stepwise replacement of the placeholder cations with reactive metal cations gives mono- and difunctionalized clusters. Initial reactivity studies illustrate the tunability of the magnetic, redox, and catalytic activity.
- Autoren
- Katharina Kastner
- Johannes Forster
- Hiromichi Ida
- Graham N Newton
- Hiroki Oshio
- Carsten Streb
- Autoren-URL
- https://www.ncbi.nlm.nih.gov/pubmed/25850969
- DOI
- 10.1002/chem.201501049
- eISSN
- 1521-3765
- Ausgabe der Veröffentlichung
- 21
- Zeitschrift
- Chemistry
- Schlüsselwörter
- mass spectrometry
- metal oxides
- metal-functionalization
- polyoxometalates
- self-assembly
- Sprache
- eng
- Country
- Germany
- Paginierung
- 7686 - 7689
- Datum der Veröffentlichung
- 2015
- Status
- Published
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2015
- Titel
- Controlled reactivity tuning of metal-functionalized vanadium oxide clusters.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 21
Datenquelle: PubMed
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- Eigentum von