Covalent Photosensitizer-Polyoxometalate-Catalyst Dyads for Visible-Light-Driven Hydrogen Evolution
- Publikationstyp:
- Zeitschriftenaufsatz
- Metadaten:
-
- Autoren
- Stefanie Schoenweiz
- Sebastian A Rommel
- Joachim Kuebel
- Mathias Micheel
- Benjamin Dietzek
- Sven Rau
- Carsten Streb
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000382925000017&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1002/chem.201602850
- eISSN
- 1521-3765
- Externe Identifier
- Clarivate Analytics Document Solution ID: DV4WB
- PubMed Identifier: 27418410
- ISSN
- 0947-6539
- Ausgabe der Veröffentlichung
- 34
- Zeitschrift
- CHEMISTRY-A EUROPEAN JOURNAL
- Schlüsselwörter
- Anderson anions
- organic-inorganic hybrids
- organo-functionalization
- polyoxometalates
- self-assembly
- Paginierung
- 12002 - 12005
- Datum der Veröffentlichung
- 2016
- Status
- Published
- Titel
- Covalent Photosensitizer-Polyoxometalate-Catalyst Dyads for Visible-Light-Driven Hydrogen Evolution
- Sub types
- Article
- Ausgabe der Zeitschrift
- 22
Datenquelle: Web of Science (Lite)
- Andere Metadatenquellen:
-
- Abstract
- <jats:title>Abstract</jats:title><jats:p>A general concept for the covalent linkage of coordination compounds to bipyridine‐functionalized polyoxometalates is presented. The new route is used to link an iridium photosensitizer to an Anderson‐type hydrogen‐evolution catalyst. This covalent dyad catalyzes the visible‐light‐driven hydrogen evolution reaction (HER) and shows superior HER activity compared with the non‐covalent reference. Hydrogen evolution is observed over periods >1 week. Spectroscopic, photophysical, and electrochemical analyses give initial insight into the stability, electronic structure, and reactivity of the dyad. The results demonstrate that the proposed linkage concept allows synergistic covalent interactions between functional coordination compounds and reactive molecular metal oxides.</jats:p>
- Autoren
- Stefanie Schönweiz
- Sebastian A Rommel
- Joachim Kübel
- Mathias Micheel
- Benjamin Dietzek
- Sven Rau
- Carsten Streb
- DOI
- 10.1002/chem.201602850
- eISSN
- 1521-3765
- ISSN
- 0947-6539
- Ausgabe der Veröffentlichung
- 34
- Zeitschrift
- Chemistry – A European Journal
- Sprache
- en
- Online publication date
- 2016
- Paginierung
- 12002 - 12005
- Datum der Veröffentlichung
- 2016
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/chem.201602850
- Datum der Datenerfassung
- 2023
- Titel
- Covalent Photosensitizer–Polyoxometalate‐Catalyst Dyads for Visible‐Light‐Driven Hydrogen Evolution
- Ausgabe der Zeitschrift
- 22
Datenquelle: Crossref
- Abstract
- A general concept for the covalent linkage of coordination compounds to bipyridine-functionalized polyoxometalates is presented. The new route is used to link an iridium photosensitizer to an Anderson-type hydrogen-evolution catalyst. This covalent dyad catalyzes the visible-light-driven hydrogen evolution reaction (HER) and shows superior HER activity compared with the non-covalent reference. Hydrogen evolution is observed over periods >1 week. Spectroscopic, photophysical, and electrochemical analyses give initial insight into the stability, electronic structure, and reactivity of the dyad. The results demonstrate that the proposed linkage concept allows synergistic covalent interactions between functional coordination compounds and reactive molecular metal oxides.
- Addresses
- Institute of Inorganic Chemistry I, Ulm University, Albert-Einstein-Allee 11, 89081, Ulm, Germany.
- Autoren
- Stefanie Schönweiz
- Sebastian A Rommel
- Joachim Kübel
- Mathias Micheel
- Benjamin Dietzek
- Sven Rau
- Carsten Streb
- DOI
- 10.1002/chem.201602850
- eISSN
- 1521-3765
- Externe Identifier
- PubMed Identifier: 27418410
- Funding acknowledgements
- EU COST actions: CM1202 and CM1203
- Deutsche Forschungsgemeinschaft: STR1164/4-1
- Open access
- false
- ISSN
- 0947-6539
- Ausgabe der Veröffentlichung
- 34
- Zeitschrift
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Sprache
- eng
- Medium
- Print-Electronic
- Online publication date
- 2016
- Paginierung
- 12002 - 12005
- Datum der Veröffentlichung
- 2016
- Status
- Published
- Datum der Datenerfassung
- 2016
- Titel
- Covalent Photosensitizer-Polyoxometalate-Catalyst Dyads for Visible-Light-Driven Hydrogen Evolution.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 22
Datenquelle: Europe PubMed Central
- Abstract
- A general concept for the covalent linkage of coordination compounds to bipyridine-functionalized polyoxometalates is presented. The new route is used to link an iridium photosensitizer to an Anderson-type hydrogen-evolution catalyst. This covalent dyad catalyzes the visible-light-driven hydrogen evolution reaction (HER) and shows superior HER activity compared with the non-covalent reference. Hydrogen evolution is observed over periods >1 week. Spectroscopic, photophysical, and electrochemical analyses give initial insight into the stability, electronic structure, and reactivity of the dyad. The results demonstrate that the proposed linkage concept allows synergistic covalent interactions between functional coordination compounds and reactive molecular metal oxides.
- Autoren
- Stefanie Schönweiz
- Sebastian A Rommel
- Joachim Kübel
- Mathias Micheel
- Benjamin Dietzek
- Sven Rau
- Carsten Streb
- Autoren-URL
- https://www.ncbi.nlm.nih.gov/pubmed/27418410
- DOI
- 10.1002/chem.201602850
- eISSN
- 1521-3765
- Ausgabe der Veröffentlichung
- 34
- Zeitschrift
- Chemistry
- Schlüsselwörter
- Anderson anions
- organic-inorganic hybrids
- organo-functionalization
- polyoxometalates
- self-assembly
- Sprache
- eng
- Country
- Germany
- Paginierung
- 12002 - 12005
- Datum der Veröffentlichung
- 2016
- Status
- Published
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2018
- Titel
- Covalent Photosensitizer-Polyoxometalate-Catalyst Dyads for Visible-Light-Driven Hydrogen Evolution.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 22
Datenquelle: PubMed
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