The Reactivity and Stability of Polyoxometalate Water Oxidation Electrocatalysts

Publikationstyp:
Zeitschriftenaufsatz
Metadaten:
Autoren
  • Dandan Gao
  • Ivan Trentin
  • Ludwig Schwiedrzik
  • Leticia Gonzalez
  • Carsten Streb
Autoren-URL
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000513770000157&DestLinkType=FullRecord&DestApp=WOS_CPL
DOI
10.3390/molecules25010157
eISSN
1420-3049
Externe Identifier
  • Clarivate Analytics Document Solution ID: KL9XN
  • PubMed Identifier: 31906045
Ausgabe der Veröffentlichung
1
Zeitschrift
MOLECULES
Schlüsselwörter
  • polyoxometalate
  • water oxidation catalysis
  • oxygen evolution reaction
  • self-assembly
  • electrocatalysis
Artikelnummer
ARTN 157
Datum der Veröffentlichung
2020
Status
Published
Titel
The Reactivity and Stability of Polyoxometalate Water Oxidation Electrocatalysts
Sub types
  • Review
Ausgabe der Zeitschrift
25

Datenquelle: Web of Science (Lite)

Andere Metadatenquellen:
Abstract
<jats:p>This review describes major advances in the use of functionalized molecular metal oxides (polyoxometalates, POMs) as water oxidation catalysts under electrochemical conditions. The fundamentals of POM-based water oxidation are described, together with a brief overview of general approaches to designing POM water oxidation catalysts. Next, the use of POMs for homogeneous, solution-phase water oxidation is described together with a summary of theoretical studies shedding light on the POM-WOC mechanism. This is followed by a discussion of heterogenization of POMs on electrically conductive substrates for technologically more relevant application studies. The stability of POM water oxidation catalysts is discussed, using select examples where detailed data is already available. The review finishes with an outlook on future perspectives and emerging themes in electrocatalytic polyoxometalate-based water oxidation research.</jats:p>
Autoren
  • Dandan Gao
  • Ivan Trentin
  • Ludwig Schwiedrzik
  • Leticia González
  • Carsten Streb
DOI
10.3390/molecules25010157
eISSN
1420-3049
Ausgabe der Veröffentlichung
1
Zeitschrift
Molecules
Sprache
en
Online publication date
2019
Paginierung
157 - 157
Status
Published online
Herausgeber
MDPI AG
Herausgeber URL
http://dx.doi.org/10.3390/molecules25010157
Datum der Datenerfassung
2020
Titel
The Reactivity and Stability of Polyoxometalate Water Oxidation Electrocatalysts
Ausgabe der Zeitschrift
25

Datenquelle: Crossref

Abstract
This review describes major advances in the use of functionalized molecular metal oxides (polyoxometalates, POMs) as water oxidation catalysts under electrochemical conditions. The fundamentals of POM-based water oxidation are described, together with a brief overview of general approaches to designing POM water oxidation catalysts. Next, the use of POMs for homogeneous, solution-phase water oxidation is described together with a summary of theoretical studies shedding light on the POM-WOC mechanism. This is followed by a discussion of heterogenization of POMs on electrically conductive substrates for technologically more relevant application studies. The stability of POM water oxidation catalysts is discussed, using select examples where detailed data is already available. The review finishes with an outlook on future perspectives and emerging themes in electrocatalytic polyoxometalate-based water oxidation research.
Addresses
  • Institute of Inorganic Chemistry I, Ulm University, Albert-Einstein-Allee 11, 89081 Ulm, Germany.
Autoren
  • Dandan Gao
  • Ivan Trentin
  • Ludwig Schwiedrzik
  • Leticia González
  • Carsten Streb
DOI
10.3390/molecules25010157
eISSN
1420-3049
Externe Identifier
  • PubMed Identifier: 31906045
  • PubMed Central ID: PMC6983101
Funding acknowledgements
  • China Scholarship Council: -
  • Deutsche Forschungsgemeinschaft: 364549901
  • Austrian Science Fund FWF: I 3987
  • Austrian Science Fund FWF: I3987-N28
  • Deutsche Forschungsgemeinschaft: STR1164/4
Open access
true
ISSN
1420-3049
Ausgabe der Veröffentlichung
1
Zeitschrift
Molecules (Basel, Switzerland)
Schlüsselwörter
  • Electrolytes
  • Oxides
  • Protons
  • Water
  • Metals
  • Tungsten Compounds
  • Ligands
  • Electrodes
  • Oxidation-Reduction
  • Catalysis
  • Electrons
Sprache
eng
Medium
Electronic
Online publication date
2019
Open access status
Open Access
Paginierung
E157
Datum der Veröffentlichung
2019
Status
Published
Publisher licence
CC BY
Datum der Datenerfassung
2020
Titel
The Reactivity and Stability of Polyoxometalate Water Oxidation Electrocatalysts.
Sub types
  • review-article
  • Review
  • Journal Article
Ausgabe der Zeitschrift
25

Files

https://www.mdpi.com/1420-3049/25/1/157/pdf https://europepmc.org/articles/PMC6983101?pdf=render

Datenquelle: Europe PubMed Central

Abstract
This review describes major advances in the use of functionalized molecular metal oxides (polyoxometalates, POMs) as water oxidation catalysts under electrochemical conditions. The fundamentals of POM-based water oxidation are described, together with a brief overview of general approaches to designing POM water oxidation catalysts. Next, the use of POMs for homogeneous, solution-phase water oxidation is described together with a summary of theoretical studies shedding light on the POM-WOC mechanism. This is followed by a discussion of heterogenization of POMs on electrically conductive substrates for technologically more relevant application studies. The stability of POM water oxidation catalysts is discussed, using select examples where detailed data is already available. The review finishes with an outlook on future perspectives and emerging themes in electrocatalytic polyoxometalate-based water oxidation research.
Date of acceptance
2019
Autoren
  • Dandan Gao
  • Ivan Trentin
  • Ludwig Schwiedrzik
  • Leticia González
  • Carsten Streb
Autoren-URL
https://www.ncbi.nlm.nih.gov/pubmed/31906045
DOI
10.3390/molecules25010157
eISSN
1420-3049
Externe Identifier
  • PubMed Central ID: PMC6983101
Funding acknowledgements
  • Deutsche Forschungsgemeinschaft: STR1164/4
  • Deutsche Forschungsgemeinschaft: 364549901
  • Austrian Science Fund: I3987-N28
  • China Scholarship Council: -
Ausgabe der Veröffentlichung
1
Zeitschrift
Molecules
Schlüsselwörter
  • electrocatalysis
  • oxygen evolution reaction
  • polyoxometalate
  • self-assembly
  • water oxidation catalysis
  • Catalysis
  • Electrodes
  • Electrolytes
  • Electrons
  • Ligands
  • Metals
  • Oxidation-Reduction
  • Oxides
  • Protons
  • Tungsten Compounds
  • Water
Sprache
eng
Country
Switzerland
PII
molecules25010157
Datum der Veröffentlichung
2019
Status
Published online
Datum, an dem der Datensatz öffentlich gemacht wurde
2020
Titel
The Reactivity and Stability of Polyoxometalate Water Oxidation Electrocatalysts.
Sub types
  • Journal Article
  • Review
Ausgabe der Zeitschrift
25

Datenquelle: PubMed

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