Polyoxometalates on Functional Substrates: Concepts, Synergies, and Future Perspectives
- Publikationstyp:
- Zeitschriftenaufsatz
- Metadaten:
-
- Autoren
- Alexey S Cherevan
- Sreejith P Nandan
- Isolda Roger
- Rongji Liu
- Carsten Streb
- Dominik Eder
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000529216500007&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1002/advs.201903511
- eISSN
- 2198-3844
- Externe Identifier
- Clarivate Analytics Document Solution ID: LI1AA
- PubMed Identifier: 32328431
- Ausgabe der Veröffentlichung
- 8
- Zeitschrift
- ADVANCED SCIENCE
- Schlüsselwörter
- charge transfer
- composites
- heterogenization
- molecular metal oxides
- substrates
- Artikelnummer
- ARTN 1903511
- Datum der Veröffentlichung
- 2020
- Status
- Published
- Titel
- Polyoxometalates on Functional Substrates: Concepts, Synergies, and Future Perspectives
- Sub types
- Article
- Ausgabe der Zeitschrift
- 7
Datenquelle: Web of Science (Lite)
- Andere Metadatenquellen:
-
- Abstract
- <jats:title>Abstract</jats:title><jats:p>Polyoxometalates (POMs) are molecular metal oxide clusters that feature a broad range of structures and functionalities, making them one of the most versatile classes of inorganic molecular materials. They have attracted widespread attention in homogeneous catalysis. Due to the challenges associated with their aggregation, precipitation, and degradation under operational conditions and to extend their scope of applications, various strategies of depositing POMs on heterogeneous substrates have been developed. Recent ground‐breaking developments in the materials chemistry of supported POM composites are summarized and links between molecular‐level understanding of POM‐support interactions and macroscopic effects including new or optimized reactivities, improved stability, and novel function are established. Current limitations and future challenges in studying these complex composite materials are highlighted, and cutting‐edge experimental and theoretical methods that will lead to an improved understanding of synergisms between POM and support material from the molecular through to the nano‐ and micrometer level are discussed. Future development in this fast‐moving field is explored and emerging fields of research in POM heterogenization are identified.</jats:p>
- Autoren
- Alexey S Cherevan
- Sreejith P Nandan
- Isolda Roger
- Rongji Liu
- Carsten Streb
- Dominik Eder
- DOI
- 10.1002/advs.201903511
- eISSN
- 2198-3844
- ISSN
- 2198-3844
- Ausgabe der Veröffentlichung
- 8
- Zeitschrift
- Advanced Science
- Sprache
- en
- Online publication date
- 2020
- Datum der Veröffentlichung
- 2020
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/advs.201903511
- Datum der Datenerfassung
- 2023
- Titel
- Polyoxometalates on Functional Substrates: Concepts, Synergies, and Future Perspectives
- Ausgabe der Zeitschrift
- 7
Datenquelle: Crossref
- Abstract
- Polyoxometalates (POMs) are molecular metal oxide clusters that feature a broad range of structures and functionalities, making them one of the most versatile classes of inorganic molecular materials. They have attracted widespread attention in homogeneous catalysis. Due to the challenges associated with their aggregation, precipitation, and degradation under operational conditions and to extend their scope of applications, various strategies of depositing POMs on heterogeneous substrates have been developed. Recent ground-breaking developments in the materials chemistry of supported POM composites are summarized and links between molecular-level understanding of POM-support interactions and macroscopic effects including new or optimized reactivities, improved stability, and novel function are established. Current limitations and future challenges in studying these complex composite materials are highlighted, and cutting-edge experimental and theoretical methods that will lead to an improved understanding of synergisms between POM and support material from the molecular through to the nano- and micrometer level are discussed. Future development in this fast-moving field is explored and emerging fields of research in POM heterogenization are identified.
- Addresses
- Institute of Materials Chemistry Vienna University of Technology Getreidemarkt 9/BC/02 Vienna 1060 Austria.
- Autoren
- Alexey S Cherevan
- Sreejith P Nandan
- Isolda Roger
- Rongji Liu
- Carsten Streb
- Dominik Eder
- DOI
- 10.1002/advs.201903511
- eISSN
- 2198-3844
- Externe Identifier
- PubMed Identifier: 32328431
- PubMed Central ID: PMC7175252
- Funding acknowledgements
- Deutsche Forschungsgemeinschaft: CS1164/12
- Deutsche Forschungsgemeinschaft: TRR234
- Deutsche Forschungsgemeinschaft: 364549901
- Austrian Science Fund FWF: P32801
- Open access
- true
- ISSN
- 2198-3844
- Ausgabe der Veröffentlichung
- 8
- Zeitschrift
- Advanced science (Weinheim, Baden-Wurttemberg, Germany)
- Sprache
- eng
- Medium
- Electronic-eCollection
- Online publication date
- 2020
- Open access status
- Open Access
- Paginierung
- 1903511
- Datum der Veröffentlichung
- 2020
- Status
- Published
- Publisher licence
- CC BY
- Datum der Datenerfassung
- 2020
- Titel
- Polyoxometalates on Functional Substrates: Concepts, Synergies, and Future Perspectives.
- Sub types
- review-article
- Review
- Journal Article
- Ausgabe der Zeitschrift
- 7
Files
https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/advs.201903511 https://europepmc.org/articles/PMC7175252?pdf=render
Datenquelle: Europe PubMed Central
- Abstract
- Polyoxometalates (POMs) are molecular metal oxide clusters that feature a broad range of structures and functionalities, making them one of the most versatile classes of inorganic molecular materials. They have attracted widespread attention in homogeneous catalysis. Due to the challenges associated with their aggregation, precipitation, and degradation under operational conditions and to extend their scope of applications, various strategies of depositing POMs on heterogeneous substrates have been developed. Recent ground-breaking developments in the materials chemistry of supported POM composites are summarized and links between molecular-level understanding of POM-support interactions and macroscopic effects including new or optimized reactivities, improved stability, and novel function are established. Current limitations and future challenges in studying these complex composite materials are highlighted, and cutting-edge experimental and theoretical methods that will lead to an improved understanding of synergisms between POM and support material from the molecular through to the nano- and micrometer level are discussed. Future development in this fast-moving field is explored and emerging fields of research in POM heterogenization are identified.
- Autoren
- Alexey S Cherevan
- Sreejith P Nandan
- Isolda Roger
- Rongji Liu
- Carsten Streb
- Dominik Eder
- Autoren-URL
- https://www.ncbi.nlm.nih.gov/pubmed/32328431
- DOI
- 10.1002/advs.201903511
- Externe Identifier
- PubMed Central ID: PMC7175252
- ISSN
- 2198-3844
- Ausgabe der Veröffentlichung
- 8
- Zeitschrift
- Adv Sci (Weinh)
- Schlüsselwörter
- charge transfer
- composites
- heterogenization
- molecular metal oxides
- substrates
- Sprache
- eng
- Country
- Germany
- Paginierung
- 1903511
- PII
- ADVS1612
- Datum der Veröffentlichung
- 2020
- Status
- Published online
- Titel
- Polyoxometalates on Functional Substrates: Concepts, Synergies, and Future Perspectives.
- Sub types
- Journal Article
- Review
- Ausgabe der Zeitschrift
- 7
Datenquelle: PubMed
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