Polyoxometalate-Based Frameworks as Adsorbents for Drug of Abuse Extraction from Hair Samples

Publikationstyp:
Zeitschriftenaufsatz
Metadaten:
Autoren
  • Shadi Derakhshanrad
  • Masoud Mirzaei
  • Carsten Streb
  • Amirhassan Amiri
  • Chris Ritchie
Autoren-URL
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000617925100024&DestLinkType=FullRecord&DestApp=WOS_CPL
DOI
10.1021/acs.inorgchem.0c02769
eISSN
1520-510X
Externe Identifier
  • Clarivate Analytics Document Solution ID: QG9UN
  • PubMed Identifier: 33434012
ISSN
0020-1669
Ausgabe der Veröffentlichung
3
Zeitschrift
INORGANIC CHEMISTRY
Paginierung
1472 - 1479
Datum der Veröffentlichung
2021
Status
Published
Titel
Polyoxometalate-Based Frameworks as Adsorbents for Drug of Abuse Extraction from Hair Samples
Sub types
  • Article
Ausgabe der Zeitschrift
60

Datenquelle: Web of Science (Lite)

Andere Metadatenquellen:
Autoren
  • Shadi Derakhshanrad
  • Masoud Mirzaei
  • Carsten Streb
  • Amirhassan Amiri
  • Chris Ritchie
DOI
10.1021/acs.inorgchem.0c02769
eISSN
1520-510X
ISSN
0020-1669
Ausgabe der Veröffentlichung
3
Zeitschrift
Inorganic Chemistry
Sprache
en
Online publication date
2021
Paginierung
1472 - 1479
Datum der Veröffentlichung
2021
Status
Published
Herausgeber
American Chemical Society (ACS)
Herausgeber URL
http://dx.doi.org/10.1021/acs.inorgchem.0c02769
Datum der Datenerfassung
2023
Titel
Polyoxometalate-Based Frameworks as Adsorbents for Drug of Abuse Extraction from Hair Samples
Ausgabe der Zeitschrift
60

Datenquelle: Crossref

Abstract
The linkage of molecular components into functional heterogeneous framework materials has revolutionized modern materials chemistry. Here, we use this principle to design polyoxometalate-based frameworks as high affinity adsorbents for drugs of abuse, leading to their application in solid-phase extraction analysis. The frameworks are assembled by the reaction of a Keggin-type polyanion, [SiW<sub>12</sub>O<sub>40</sub>]<sup>4-</sup>, with lanthanoids Dy(III), La(III), Nd(III), and Sm(III) and the multidentate linking ligand 1,10-phenanthroline-2,9-dicarboxylic acid (H<sub>2</sub>PDA). Their reaction leads to the formation of crystalline 1D coordination polymers. Because of the charge mismatch between the lanthanoids (+3) and the dodecasilicotungstate (-4), we observe incorporation of the PDA<sup>2-</sup> ligands into crystalline materials, leading to four polyoxometalate-based frameworks where Keggin-type heteropolyanions are linked by cationic {Ln<sub><i>n</i></sub>(PDA)<sub><i>n</i></sub>} groups (Ln = Dy (<b>1</b>), La (<b>2</b>), Nd (<b>3</b>), and Sm (<b>4</b>)). Structural analysis of the polyoxometalate-based frameworks suggested that they might be suitable for surface binding of common drugs of abuse via supramolecular interactions. To this end, they were used for the extraction and quantitative determination of four model drugs of abuse (amphetamine, methamphetamine, codeine, and morphine) by using micro-solid-phase extraction (D-μSPE) and high-performance liquid chromatography (HPLC). The method showed wide linear ranges, low limits of detection (0.1-0.3 ng mL<sup>-1</sup>), high precision, and satisfactory spiked recoveries. Our results demonstrate that polyoxometalate-based frameworks are suitable sorbents in D-μSPE for molecules containing amine functionalities. The modular design of these networks could in the future be used to expand and tune their substrate binding behavior.
Addresses
  • Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad, Mashhad 9177948974, Iran.
Autoren
  • Shadi Derakhshanrad
  • Masoud Mirzaei
  • Carsten Streb
  • Amirhassan Amiri
  • Chris Ritchie
DOI
10.1021/acs.inorgchem.0c02769
eISSN
1520-510X
Externe Identifier
  • PubMed Identifier: 33434012
Funding acknowledgements
  • Ferdowsi University of Mashhad: 3/42201
  • Universit?t Ulm:
  • Australian Research Council:
  • Helmholtz-Gemeinschaft:
  • Iran National Science Foundation:
  • Monash University:
  • Iran Science Elites Federation:
  • Iranian Chemical Society:
Open access
false
ISSN
0020-1669
Ausgabe der Veröffentlichung
3
Zeitschrift
Inorganic chemistry
Schlüsselwörter
  • Hair
  • Humans
  • Tungsten Compounds
  • Amphetamine
  • Methamphetamine
  • Morphine
  • Codeine
  • Molecular Structure
  • Adsorption
  • Healthy Volunteers
  • Metal-Organic Frameworks
Sprache
eng
Medium
Print-Electronic
Online publication date
2021
Paginierung
1472 - 1479
Datum der Veröffentlichung
2021
Status
Published
Datum der Datenerfassung
2021
Titel
Polyoxometalate-Based Frameworks as Adsorbents for Drug of Abuse Extraction from Hair Samples.
Sub types
  • Journal Article
Ausgabe der Zeitschrift
60

Datenquelle: Europe PubMed Central

Abstract
The linkage of molecular components into functional heterogeneous framework materials has revolutionized modern materials chemistry. Here, we use this principle to design polyoxometalate-based frameworks as high affinity adsorbents for drugs of abuse, leading to their application in solid-phase extraction analysis. The frameworks are assembled by the reaction of a Keggin-type polyanion, [SiW12O40]4-, with lanthanoids Dy(III), La(III), Nd(III), and Sm(III) and the multidentate linking ligand 1,10-phenanthroline-2,9-dicarboxylic acid (H2PDA). Their reaction leads to the formation of crystalline 1D coordination polymers. Because of the charge mismatch between the lanthanoids (+3) and the dodecasilicotungstate (-4), we observe incorporation of the PDA2- ligands into crystalline materials, leading to four polyoxometalate-based frameworks where Keggin-type heteropolyanions are linked by cationic {Lnn(PDA)n} groups (Ln = Dy (1), La (2), Nd (3), and Sm (4)). Structural analysis of the polyoxometalate-based frameworks suggested that they might be suitable for surface binding of common drugs of abuse via supramolecular interactions. To this end, they were used for the extraction and quantitative determination of four model drugs of abuse (amphetamine, methamphetamine, codeine, and morphine) by using micro-solid-phase extraction (D-μSPE) and high-performance liquid chromatography (HPLC). The method showed wide linear ranges, low limits of detection (0.1-0.3 ng mL-1), high precision, and satisfactory spiked recoveries. Our results demonstrate that polyoxometalate-based frameworks are suitable sorbents in D-μSPE for molecules containing amine functionalities. The modular design of these networks could in the future be used to expand and tune their substrate binding behavior.
Autoren
  • Shadi Derakhshanrad
  • Masoud Mirzaei
  • Carsten Streb
  • Amirhassan Amiri
  • Chris Ritchie
Autoren-URL
https://www.ncbi.nlm.nih.gov/pubmed/33434012
DOI
10.1021/acs.inorgchem.0c02769
eISSN
1520-510X
Ausgabe der Veröffentlichung
3
Zeitschrift
Inorg Chem
Schlüsselwörter
  • Adsorption
  • Amphetamine
  • Codeine
  • Hair
  • Healthy Volunteers
  • Humans
  • Metal-Organic Frameworks
  • Methamphetamine
  • Molecular Structure
  • Morphine
  • Tungsten Compounds
Sprache
eng
Country
United States
Paginierung
1472 - 1479
Datum der Veröffentlichung
2021
Status
Published
Datum, an dem der Datensatz öffentlich gemacht wurde
2021
Titel
Polyoxometalate-Based Frameworks as Adsorbents for Drug of Abuse Extraction from Hair Samples.
Sub types
  • Journal Article
Ausgabe der Zeitschrift
60

Datenquelle: PubMed

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