Spin-flip luminescence
- Publikationstyp:
- Zeitschriftenaufsatz
- Metadaten:
-
- Autoren
- Winald Robert Kitzmann
- Johannes Moll
- Katja Heinze
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000764917200002&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1007/s43630-022-00186-3
- eISSN
- 1474-9092
- Externe Identifier
- Clarivate Analytics Document Solution ID: 3M8SW
- PubMed Identifier: 35247169
- ISSN
- 1474-905X
- Ausgabe der Veröffentlichung
- 7
- Zeitschrift
- PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES
- Schlüsselwörter
- Transition metal complex
- Photochemistry
- Excited states
- Ligand field theory
- Spin-flip phosphorescence
- Intersystem crossing
- Paginierung
- 1309 - 1331
- Datum der Veröffentlichung
- 2022
- Status
- Published
- Titel
- Spin-flip luminescence
- Sub types
- Review
- Ausgabe der Zeitschrift
- 21
Datenquelle: Web of Science (Lite)
- Andere Metadatenquellen:
-
- Abstract
- <jats:title>Abstract</jats:title><jats:p>In molecular photochemistry, charge-transfer emission is well understood and widely exploited. In contrast, luminescent metal-centered transitions only came into focus in recent years. This gave rise to strongly phosphorescent Cr<jats:sup>III</jats:sup>complexes with a<jats:italic>d</jats:italic><jats:sup>3</jats:sup>electronic configuration featuring luminescent metal-centered excited states which are characterized by the flip of a single spin. These so-called spin-flip emitters possess unique properties and require different design strategies than traditional charge-transfer phosphors. In this review, we give a brief introduction to ligand field theory as a framework to understand this phenomenon and outline prerequisites for efficient spin-flip emission including ligand field strength, symmetry, intersystem crossing and common deactivation pathways using Cr<jats:sup>III</jats:sup>complexes as instructive examples. The recent progress and associated challenges of tuning the energies of emissive excited states and of emerging applications of the unique photophysical properties of spin-flip emitters are discussed. Finally, we summarize the current state-of-the-art and challenges of spin-flip emitters beyond Cr<jats:sup>III</jats:sup>with<jats:italic>d</jats:italic><jats:sup>2</jats:sup>,<jats:italic>d</jats:italic><jats:sup>3</jats:sup>,<jats:italic>d</jats:italic><jats:sup>4</jats:sup>and<jats:italic>d</jats:italic><jats:sup>8</jats:sup>electronic configuration, where we mainly cover pseudooctahedral molecular complexes of V, Mo, W, Mn, Re and Ni, and highlight possible future research opportunities.</jats:p><jats:p><jats:bold>Graphical abstract</jats:bold></jats:p>
- Autoren
- Winald Robert Kitzmann
- Johannes Moll
- Katja Heinze
- DOI
- 10.1007/s43630-022-00186-3
- eISSN
- 1474-9092
- Ausgabe der Veröffentlichung
- 7
- Zeitschrift
- Photochemical & Photobiological Sciences
- Sprache
- en
- Online publication date
- 2022
- Paginierung
- 1309 - 1331
- Datum der Veröffentlichung
- 2022
- Status
- Published
- Herausgeber
- Springer Science and Business Media LLC
- Herausgeber URL
- http://dx.doi.org/10.1007/s43630-022-00186-3
- Datum der Datenerfassung
- 2023
- Titel
- Spin-flip luminescence
- Ausgabe der Zeitschrift
- 21
Datenquelle: Crossref
- Abstract
- In molecular photochemistry, charge-transfer emission is well understood and widely exploited. In contrast, luminescent metal-centered transitions only came into focus in recent years. This gave rise to strongly phosphorescent Cr<sup>III</sup> complexes with a d<sup>3</sup> electronic configuration featuring luminescent metal-centered excited states which are characterized by the flip of a single spin. These so-called spin-flip emitters possess unique properties and require different design strategies than traditional charge-transfer phosphors. In this review, we give a brief introduction to ligand field theory as a framework to understand this phenomenon and outline prerequisites for efficient spin-flip emission including ligand field strength, symmetry, intersystem crossing and common deactivation pathways using Cr<sup>III</sup> complexes as instructive examples. The recent progress and associated challenges of tuning the energies of emissive excited states and of emerging applications of the unique photophysical properties of spin-flip emitters are discussed. Finally, we summarize the current state-of-the-art and challenges of spin-flip emitters beyond Cr<sup>III</sup> with d<sup>2</sup>, d<sup>3</sup>, d<sup>4</sup> and d<sup>8</sup> electronic configuration, where we mainly cover pseudooctahedral molecular complexes of V, Mo, W, Mn, Re and Ni, and highlight possible future research opportunities.
- Addresses
- Department of Chemistry, Johannes Gutenberg University Mainz, Duesbergweg 10-14, Mainz, Germany. Kitzmann@Uni-Mainz.de.
- Autoren
- Winald Robert Kitzmann
- Johannes Moll
- Katja Heinze
- DOI
- 10.1007/s43630-022-00186-3
- eISSN
- 1474-9092
- Externe Identifier
- PubMed Identifier: 35247169
- Funding acknowledgements
- Deutsche Forschungsgemeinschaft: HE2778/13-1
- Johannes Gutenberg-Universität Mainz:
- Verband der Chemischen Industrie: Kekule grant
- Open access
- false
- ISSN
- 1474-905X
- Ausgabe der Veröffentlichung
- 7
- Zeitschrift
- Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology
- Sprache
- eng
- Medium
- Print-Electronic
- Online publication date
- 2022
- Paginierung
- 1309 - 1331
- Datum der Veröffentlichung
- 2022
- Status
- Published
- Publisher licence
- CC BY
- Datum der Datenerfassung
- 2022
- Titel
- Spin-flip luminescence.
- Sub types
- Review
- Journal Article
- Ausgabe der Zeitschrift
- 21
Datenquelle: Europe PubMed Central
- Abstract
- In molecular photochemistry, charge-transfer emission is well understood and widely exploited. In contrast, luminescent metal-centered transitions only came into focus in recent years. This gave rise to strongly phosphorescent CrIII complexes with a d3 electronic configuration featuring luminescent metal-centered excited states which are characterized by the flip of a single spin. These so-called spin-flip emitters possess unique properties and require different design strategies than traditional charge-transfer phosphors. In this review, we give a brief introduction to ligand field theory as a framework to understand this phenomenon and outline prerequisites for efficient spin-flip emission including ligand field strength, symmetry, intersystem crossing and common deactivation pathways using CrIII complexes as instructive examples. The recent progress and associated challenges of tuning the energies of emissive excited states and of emerging applications of the unique photophysical properties of spin-flip emitters are discussed. Finally, we summarize the current state-of-the-art and challenges of spin-flip emitters beyond CrIII with d2, d3, d4 and d8 electronic configuration, where we mainly cover pseudooctahedral molecular complexes of V, Mo, W, Mn, Re and Ni, and highlight possible future research opportunities.
- Date of acceptance
- 2022
- Autoren
- Winald Robert Kitzmann
- Johannes Moll
- Katja Heinze
- Autoren-URL
- https://www.ncbi.nlm.nih.gov/pubmed/35247169
- DOI
- 10.1007/s43630-022-00186-3
- eISSN
- 1474-9092
- Funding acknowledgements
- Deutsche Forschungsgemeinschaft: HE2778/13-1
- Verband der Chemischen Industrie: Kekule grant
- Ausgabe der Veröffentlichung
- 7
- Zeitschrift
- Photochem Photobiol Sci
- Schlüsselwörter
- Excited states
- Intersystem crossing
- Ligand field theory
- Photochemistry
- Spin-flip phosphorescence
- Transition metal complex
- Sprache
- eng
- Country
- England
- Paginierung
- 1309 - 1331
- PII
- 10.1007/s43630-022-00186-3
- Datum der Veröffentlichung
- 2022
- Status
- Published
- Titel
- Spin-flip luminescence.
- Sub types
- Journal Article
- Review
- Ausgabe der Zeitschrift
- 21
Datenquelle: PubMed
- Author's licence
- CC-BY
- Autoren
- Winald Robert Kitzmann
- Johannes Moll
- Katja Heinze
- Hosting institution
- Universitätsbibliothek Mainz
- Sammlungen
- DFG-491381577-H
- Resource version
- Published version
- DOI
- 10.1007/s43630-022-00186-3
- Funding acknowledgements
- Gefördert durch die Deutsche Forschungsgemeinschaft (DFG) - Projektnummer 491381577
- File(s) embargoed
- false
- Open access
- true
- ISSN
- 1474-9092
- Zeitschrift
- Photochemical & photobiological sciences
- Schlüsselwörter
- 540 Chemie
- 540 Chemistry and allied sciences
- Sprache
- eng
- Open access status
- Open Access
- Paginierung
- 1309 - 1331
- Datum der Veröffentlichung
- 2022
- Public URL
- https://openscience.ub.uni-mainz.de/handle/20.500.12030/8320
- Herausgeber
- Springer
- Datum der Datenerfassung
- 2022
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2022
- Zugang
- Public
- Titel
- Spin-flip luminescence
- Ausgabe der Zeitschrift
- 21
Files
spinflip_luminescence-20221114161155966.pdf
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