Three Novel Thiazole-Arm Containing 1,3,4-Oxadiazole-Based [HS-HS] Fe(II) Dinuclear Complexes

Publikationstyp:
Zeitschriftenaufsatz
Metadaten:
Autoren
Autoren-URL
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000775868100001&DestLinkType=FullRecord&DestApp=WOS_CPL
DOI
10.3390/cryst12030404
eISSN
2073-4352
Externe Identifier
  • Clarivate Analytics Document Solution ID: 0D2ZE
Ausgabe der Veröffentlichung
3
Zeitschrift
CRYSTALS
Schlüsselwörter
  • Fe(II)
  • HS-complexes
  • coordination-chemistry
  • 1
  • 3
  • 4-oxadiazole
  • spin-crossover
Artikelnummer
ARTN 404
Datum der Veröffentlichung
2022
Status
Published
Titel
Three Novel Thiazole-Arm Containing 1,3,4-Oxadiazole-Based [HS-HS] Fe(II) Dinuclear Complexes
Sub types
  • Article
Ausgabe der Zeitschrift
12

Datenquelle: Web of Science (Lite)

Andere Metadatenquellen:
Abstract
<jats:p>Novel synthesis of 2,5-bis[(1,3-thiazol-2-ylmethyl)amino]methyl-1,3,4-oxadiazole (LThiazole) is reported, along with the preparation of three new dinuclear Fe(II) complexes with different counterions [FeII2(μ2-LThiazole)2](BF4)4·2CH3CN (1), [FeII2(μ2-LThiazole)2](ClO4)4 (2) and [FeII2(μ2-LThiazole)2](CF3SO3)4·2CH3CN (3). The obtained complexes were characterized by single-crystal X-ray crystallography, SQUID magnetometry and IR spectroscopy. The structure of the crystalline material was determined at 120 K for 1 and 3. The magnetic properties of all three complexes (1–3) were measured between 2–300 K and clearly show that all three complexes stay in the high-spin state over the measured temperature range.</jats:p>
Autoren
DOI
10.3390/cryst12030404
eISSN
2073-4352
Ausgabe der Veröffentlichung
3
Zeitschrift
Crystals
Sprache
en
Online publication date
2022
Paginierung
404 - 404
Status
Published online
Herausgeber
MDPI AG
Herausgeber URL
http://dx.doi.org/10.3390/cryst12030404
Datum der Datenerfassung
2022
Titel
Three Novel Thiazole-Arm Containing 1,3,4-Oxadiazole-Based [HS-HS] Fe(II) Dinuclear Complexes
Ausgabe der Zeitschrift
12

Datenquelle: Crossref

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