(1-Adamantyl)methyl Glycidyl Ether: A Versatile Building Block for Living Polymerization

Publikationstyp:
Zeitschriftenaufsatz
Metadaten:
Autoren
  • Christian Moers
  • Robert Wrazidlo
  • Adrian Natalello
  • Isabelle Netz
  • Mihail Mondeshki
  • Holger Frey
Autoren-URL
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000337608800008&DestLinkType=FullRecord&DestApp=WOS_CPL
DOI
10.1002/marc.201400017
eISSN
1521-3927
Externe Identifier
  • Clarivate Analytics Document Solution ID: AJ3ZT
  • PubMed Identifier: 24677644
ISSN
1022-1336
Ausgabe der Veröffentlichung
11
Zeitschrift
MACROMOLECULAR RAPID COMMUNICATIONS
Schlüsselwörter
  • adamantane
  • end-functionalization
  • polyether polyol
  • polyglycerol
  • polystyrene
Paginierung
1075 - 1080
Datum der Veröffentlichung
2014
Status
Published
Titel
(1-Adamantyl)methyl Glycidyl Ether: A Versatile Building Block for Living Polymerization
Sub types
  • Article
Ausgabe der Zeitschrift
35

Datenquelle: Web of Science (Lite)

Andere Metadatenquellen:
Abstract
<jats:p>(1‐Adamantyl)methyl glycidyl ether (AdaGE) is introduced as a versatile monomer for oxyanionic polymerization, enabling controlled incorporation of adamantyl moieties in aliphatic polyethers. Via copolymerization with ethoxyethyl glycidyl ether (EEGE) and subsequent cleavage of the acetal protection groups of EEGE, hydrophilic linear polyglycerols with an adjustable amount of pendant adamantyl moieties are obtained. The adamantyl unit permits control over thermal properties and solubility profile of these polymers (LCST). Additionally, AdaGE is utilized as a termination agent in carbanionic polymerization, affording adamantyl‐terminated polymers. Using these structures as macroinitiators for the polymerization of ethylene oxide affords amphiphilic, in‐chain adamantyl‐functionalized block copolymers. <jats:boxed-text content-type="graphic" position="anchor"><jats:graphic xmlns:xlink="http://www.w3.org/1999/xlink" mimetype="image/jpg" position="anchor" specific-use="enlarged-web-image" xlink:href="graphic/marc201400017-abs-0001-m.jpg"><jats:alt-text>image</jats:alt-text></jats:graphic></jats:boxed-text></jats:p>
Autoren
  • Christian Moers
  • Robert Wrazidlo
  • Adrian Natalello
  • Isabelle Netz
  • Mihail Mondeshki
  • Holger Frey
DOI
10.1002/marc.201400017
eISSN
1521-3927
ISSN
1022-1336
Ausgabe der Veröffentlichung
11
Zeitschrift
Macromolecular Rapid Communications
Sprache
en
Online publication date
2014
Paginierung
1075 - 1080
Datum der Veröffentlichung
2014
Status
Published
Herausgeber
Wiley
Herausgeber URL
http://dx.doi.org/10.1002/marc.201400017
Datum der Datenerfassung
2023
Titel
(1‐Adamantyl)methyl Glycidyl Ether: A Versatile Building Block for Living Polymerization
Ausgabe der Zeitschrift
35

Datenquelle: Crossref

Abstract
(1-Adamantyl)methyl glycidyl ether (AdaGE) is introduced as a versatile monomer for oxyanionic polymerization, enabling controlled incorporation of adamantyl moieties in aliphatic polyethers. Via copolymerization with ethoxyethyl glycidyl ether (EEGE) and subsequent cleavage of the acetal protection groups of EEGE, hydrophilic linear polyglycerols with an adjustable amount of pendant adamantyl moieties are obtained. The adamantyl unit permits control over thermal properties and solubility profile of these polymers (LCST). Additionally, AdaGE is utilized as a termination agent in carbanionic polymerization, affording adamantyl-terminated polymers. Using these structures as macroinitiators for the polymerization of ethylene oxide affords amphiphilic, in-chain adamantyl-functionalized block copolymers.
Addresses
  • Institute of Organic Chemistry, Johannes Gutenberg-Universität Mainz (JGU), Duesbergweg 10-14, D-55128, Mainz, Germany; Graduate School Materials Science in Mainz (MAINZ), Staudinger Weg 9, D-55128, Mainz, Germany.
Autoren
  • Christian Moers
  • Robert Wrazidlo
  • Adrian Natalello
  • Isabelle Netz
  • Mihail Mondeshki
  • Holger Frey
DOI
10.1002/marc.201400017
eISSN
1521-3927
Externe Identifier
  • PubMed Identifier: 24677644
Open access
false
ISSN
1022-1336
Ausgabe der Veröffentlichung
11
Zeitschrift
Macromolecular rapid communications
Schlüsselwörter
  • Glycerol
  • Epoxy Compounds
  • Adamantane
  • Polymers
  • Hydrophobic and Hydrophilic Interactions
  • Polymerization
Sprache
eng
Medium
Print-Electronic
Online publication date
2014
Paginierung
1075 - 1080
Datum der Veröffentlichung
2014
Status
Published
Datum der Datenerfassung
2014
Titel
(1-Adamantyl)methyl glycidyl ether: a versatile building block for living polymerization.
Sub types
  • Journal Article
Ausgabe der Zeitschrift
35

Datenquelle: Europe PubMed Central

Abstract
(1-Adamantyl)methyl glycidyl ether (AdaGE) is introduced as a versatile monomer for oxyanionic polymerization, enabling controlled incorporation of adamantyl moieties in aliphatic polyethers. Via copolymerization with ethoxyethyl glycidyl ether (EEGE) and subsequent cleavage of the acetal protection groups of EEGE, hydrophilic linear polyglycerols with an adjustable amount of pendant adamantyl moieties are obtained. The adamantyl unit permits control over thermal properties and solubility profile of these polymers (LCST). Additionally, AdaGE is utilized as a termination agent in carbanionic polymerization, affording adamantyl-terminated polymers. Using these structures as macroinitiators for the polymerization of ethylene oxide affords amphiphilic, in-chain adamantyl-functionalized block copolymers.
Autoren
  • Christian Moers
  • Robert Wrazidlo
  • Adrian Natalello
  • Isabelle Netz
  • Mihail Mondeshki
  • Holger Frey
Autoren-URL
https://www.ncbi.nlm.nih.gov/pubmed/24677644
DOI
10.1002/marc.201400017
eISSN
1521-3927
Ausgabe der Veröffentlichung
11
Zeitschrift
Macromol Rapid Commun
Schlüsselwörter
  • adamantane
  • end-functionalization
  • polyether polyol
  • polyglycerol
  • polystyrene
  • Adamantane
  • Epoxy Compounds
  • Glycerol
  • Hydrophobic and Hydrophilic Interactions
  • Polymerization
  • Polymers
Sprache
eng
Country
Germany
Paginierung
1075 - 1080
Datum der Veröffentlichung
2014
Status
Published
Datum, an dem der Datensatz öffentlich gemacht wurde
2015
Titel
(1-Adamantyl)methyl glycidyl ether: a versatile building block for living polymerization.
Sub types
  • Journal Article
Ausgabe der Zeitschrift
35

Datenquelle: PubMed

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