Polysiloxane-Backbone Block Copolymers in a One-Pot Synthesis: A Silicone Platform for Facile Functionalization
- Publikationstyp:
- Zeitschriftenaufsatz
- Metadaten:
-
- Autoren
- Paul Boehm
- Mihail Mondeshki
- Holger Frey
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000310602300007&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1002/marc.201200365
- eISSN
- 1521-3927
- Externe Identifier
- Clarivate Analytics Document Solution ID: 030XB
- PubMed Identifier: 22836926
- ISSN
- 1022-1336
- Ausgabe der Veröffentlichung
- 21
- Zeitschrift
- MACROMOLECULAR RAPID COMMUNICATIONS
- Schlüsselwörter
- block copolymers
- hydrosilylation
- polysiloxanes
- ring opening polymerization
- Paginierung
- 1861 - 1867
- Datum der Veröffentlichung
- 2012
- Status
- Published
- Titel
- Polysiloxane-Backbone Block Copolymers in a One-Pot Synthesis: A Silicone Platform for Facile Functionalization
- Sub types
- Article
- Ausgabe der Zeitschrift
- 33
Datenquelle: Web of Science (Lite)
- Andere Metadatenquellen:
-
- Abstract
- <jats:title>Abstract</jats:title><jats:p>Block copolymers consisting exclusively of a silicon–oxygen backbone are synthesized by sequential anionic ring‐opening polymerization of different cyclic siloxane monomers. After formation of a poly(dimethylsiloxane) (PDMS) block by butyllithium‐initiated polymerization of D3, a functional second block is generated by subsequent addition of tetramethyl tetravinyl cyclotetrasiloxane (D4<jats:sup>V</jats:sup>), resulting in diblock copolymers comprised a simple PDMS block and a functional poly(methylvinylsiloxane) (PMVS) block. Polymers of varying block length ratios were obtained and characterized. The vinyl groups of the second block can be easily modified with a variety of side chains using hydrosilylation chemistry to attach compounds with Si—H bond. Conversion of the hydrosilylation used for polymer modification was investigated.</jats:p>
- Autoren
- Paul Boehm
- Mihail Mondeshki
- Holger Frey
- DOI
- 10.1002/marc.201200365
- eISSN
- 1521-3927
- ISSN
- 1022-1336
- Ausgabe der Veröffentlichung
- 21
- Zeitschrift
- Macromolecular Rapid Communications
- Sprache
- en
- Online publication date
- 2012
- Paginierung
- 1861 - 1867
- Datum der Veröffentlichung
- 2012
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/marc.201200365
- Datum der Datenerfassung
- 2023
- Titel
- Polysiloxane‐Backbone Block Copolymers in a One‐Pot Synthesis: A Silicone Platform for Facile Functionalization
- Ausgabe der Zeitschrift
- 33
Datenquelle: Crossref
- Abstract
- Block copolymers consisting exclusively of a silicon-oxygen backbone are synthesized by sequential anionic ring-opening polymerization of different cyclic siloxane monomers. After formation of a poly(dimethylsiloxane) (PDMS) block by butyllithium-initiated polymerization of D3, a functional second block is generated by subsequent addition of tetramethyl tetravinyl cyclotetrasiloxane (D4(V) ), resulting in diblock copolymers comprised a simple PDMS block and a functional poly(methylvinylsiloxane) (PMVS) block. Polymers of varying block length ratios were obtained and characterized. The vinyl groups of the second block can be easily modified with a variety of side chains using hydrosilylation chemistry to attach compounds with Si-H bond. Conversion of the hydrosilylation used for polymer modification was investigated.
- Addresses
- Johannes Gutenberg University Mainz, Institute of Organic Chemistry, Duesbergweg 10-14, 55099 Mainz, Germany.
- Autoren
- Paul Boehm
- Mihail Mondeshki
- Holger Frey
- DOI
- 10.1002/marc.201200365
- eISSN
- 1521-3927
- Externe Identifier
- PubMed Identifier: 22836926
- Open access
- false
- ISSN
- 1022-1336
- Ausgabe der Veröffentlichung
- 21
- Zeitschrift
- Macromolecular rapid communications
- Schlüsselwörter
- Siloxanes
- Silicones
- Molecular Structure
- Polymerization
- Sprache
- eng
- Medium
- Print-Electronic
- Online publication date
- 2012
- Paginierung
- 1861 - 1867
- Datum der Veröffentlichung
- 2012
- Status
- Published
- Datum der Datenerfassung
- 2012
- Titel
- Polysiloxane-backbone block copolymers in a one-pot synthesis: a silicone platform for facile functionalization.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 33
Datenquelle: Europe PubMed Central
- Abstract
- Block copolymers consisting exclusively of a silicon-oxygen backbone are synthesized by sequential anionic ring-opening polymerization of different cyclic siloxane monomers. After formation of a poly(dimethylsiloxane) (PDMS) block by butyllithium-initiated polymerization of D3, a functional second block is generated by subsequent addition of tetramethyl tetravinyl cyclotetrasiloxane (D4(V) ), resulting in diblock copolymers comprised a simple PDMS block and a functional poly(methylvinylsiloxane) (PMVS) block. Polymers of varying block length ratios were obtained and characterized. The vinyl groups of the second block can be easily modified with a variety of side chains using hydrosilylation chemistry to attach compounds with Si-H bond. Conversion of the hydrosilylation used for polymer modification was investigated.
- Autoren
- Paul Boehm
- Mihail Mondeshki
- Holger Frey
- Autoren-URL
- https://www.ncbi.nlm.nih.gov/pubmed/22836926
- DOI
- 10.1002/marc.201200365
- eISSN
- 1521-3927
- Ausgabe der Veröffentlichung
- 21
- Zeitschrift
- Macromol Rapid Commun
- Schlüsselwörter
- Molecular Structure
- Polymerization
- Silicones
- Siloxanes
- Sprache
- eng
- Country
- Germany
- Paginierung
- 1861 - 1867
- Datum der Veröffentlichung
- 2012
- Status
- Published
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2013
- Titel
- Polysiloxane-backbone block copolymers in a one-pot synthesis: a silicone platform for facile functionalization.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 33
Datenquelle: PubMed
- Beziehungen:
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