Selective C-H Activation of Methoxy Groups in a Three-Component Photoreaction
- Publikationstyp:
- Zeitschriftenaufsatz
- Metadaten:
-
- Autoren
- Guenther Lahm
- Till Opatz
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000366877900084&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1021/acs.joc.5b02373
- eISSN
- 1520-6904
- Externe Identifier
- Clarivate Analytics Document Solution ID: CZ1PN
- PubMed Identifier: 26575961
- ISSN
- 0022-3263
- Ausgabe der Veröffentlichung
- 24
- Zeitschrift
- JOURNAL OF ORGANIC CHEMISTRY
- Paginierung
- 12711 - 12717
- Datum der Veröffentlichung
- 2015
- Status
- Published
- Titel
- Selective C-H Activation of Methoxy Groups in a Three-Component Photoreaction
- Sub types
- Article
- Ausgabe der Zeitschrift
- 80
Datenquelle: Web of Science (Lite)
- Andere Metadatenquellen:
-
- Autoren
- Günther Lahm
- Till Opatz
- DOI
- 10.1021/acs.joc.5b02373
- eISSN
- 1520-6904
- ISSN
- 0022-3263
- Ausgabe der Veröffentlichung
- 24
- Zeitschrift
- The Journal of Organic Chemistry
- Sprache
- en
- Online publication date
- 2015
- Paginierung
- 12711 - 12717
- Datum der Veröffentlichung
- 2015
- Status
- Published
- Herausgeber
- American Chemical Society (ACS)
- Herausgeber URL
- http://dx.doi.org/10.1021/acs.joc.5b02373
- Datum der Datenerfassung
- 2023
- Titel
- Selective C–H Activation of Methoxy Groups in a Three-Component Photoreaction
- Ausgabe der Zeitschrift
- 80
Datenquelle: Crossref
- Abstract
- Surprisingly, the photocatalytic activation of ethers by H-abstraction and addition of the generated radicals to iminium ions formed in situ from aldehydes and anilines predominantly yielded the products of methoxy activation for dimethoxymethane and 1,2-dimethoxyethane. Various anilines and aromatic as well as aliphatic aldehydes are suitable reaction partners for this three-component photoreaction (Porta-type process) which also provides a simple access to 1,2-aminoalcohols.
- Addresses
- Institute of Organic Chemistry, University of Mainz , Duesbergweg 10-14, D-55128 Mainz, Germany.
- Autoren
- Günther Lahm
- Till Opatz
- DOI
- 10.1021/acs.joc.5b02373
- eISSN
- 1520-6904
- Externe Identifier
- PubMed Identifier: 26575961
- Open access
- false
- ISSN
- 0022-3263
- Ausgabe der Veröffentlichung
- 24
- Zeitschrift
- The Journal of organic chemistry
- Sprache
- eng
- Medium
- Print-Electronic
- Online publication date
- 2015
- Paginierung
- 12711 - 12717
- Datum der Veröffentlichung
- 2015
- Status
- Published
- Datum der Datenerfassung
- 2015
- Titel
- Selective C-H Activation of Methoxy Groups in a Three-Component Photoreaction.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 80
Datenquelle: Europe PubMed Central
- Abstract
- Surprisingly, the photocatalytic activation of ethers by H-abstraction and addition of the generated radicals to iminium ions formed in situ from aldehydes and anilines predominantly yielded the products of methoxy activation for dimethoxymethane and 1,2-dimethoxyethane. Various anilines and aromatic as well as aliphatic aldehydes are suitable reaction partners for this three-component photoreaction (Porta-type process) which also provides a simple access to 1,2-aminoalcohols.
- Autoren
- Günther Lahm
- Till Opatz
- Autoren-URL
- https://www.ncbi.nlm.nih.gov/pubmed/26575961
- DOI
- 10.1021/acs.joc.5b02373
- eISSN
- 1520-6904
- Ausgabe der Veröffentlichung
- 24
- Zeitschrift
- J Org Chem
- Sprache
- eng
- Country
- United States
- Paginierung
- 12711 - 12717
- Datum der Veröffentlichung
- 2015
- Status
- Published
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2016
- Titel
- Selective C-H Activation of Methoxy Groups in a Three-Component Photoreaction.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 80
Datenquelle: PubMed
- Beziehungen:
- Eigentum von