Decomposition studies of group 6 hexacarbonyl complexes. Part 1: Production and decomposition of Mo(CO)6 and W(CO)6
- Publikationstyp:
- Zeitschriftenaufsatz
- Metadaten:
-
- Autoren
- I Usoltsev
- R Eichler
- Y Wang
- J Even
- A Yakushev
- H Haba
- M Asai
- H Brand
- A Di Nitto
- Ch E Duellmann
- F Fangli
- W Hartmann
- M Huang
- E Jaeger
- D Kaji
- J Kanaya
- Y Kaneya
- J Khuyagbaatar
- B Kindler
- JV Kratz
- J Krier
- Y Kudou
- N Kurz
- B Lommel
- S Miyashita
- K Morimoto
- K Morita
- M Murakami
- Y Nagame
- H Nitsche
- K Ooe
- TK Sato
- M Schaedel
- J Steiner
- P Steinegger
- T Sumita
- M Takeyama
- K Tanaka
- A Toyoshima
- K Tsukada
- A Tuerler
- Y Wakabayashi
- N Wiehl
- S Yamaki
- Z Qin
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000371921300001&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1515/ract-2015-2445
- eISSN
- 2193-3405
- Externe Identifier
- Clarivate Analytics Document Solution ID: DG2TO
- ISSN
- 0033-8230
- Ausgabe der Veröffentlichung
- 3
- Zeitschrift
- RADIOCHIMICA ACTA
- Schlüsselwörter
- Transition metals
- carbonyl complexes
- transactinides
- group 6
- seaborgium
- thermal stability
- Paginierung
- 141 - 151
- Datum der Veröffentlichung
- 2016
- Status
- Published
- Titel
- Decomposition studies of group 6 hexacarbonyl complexes. Part 1: Production and decomposition of Mo(CO)<sub>6</sub> and W(CO)<sub>6</sub>
- Sub types
- Article
- Ausgabe der Zeitschrift
- 104
Datenquelle: Web of Science (Lite)
- Andere Metadatenquellen:
-
- Abstract
- <jats:title>Abstract</jats:title> <jats:p>Chemical studies of superheavy elements require fast and efficient techniques, due to short half-lives and low production rates of the investigated nuclides. Here, we advocate for using a tubular flow reactor for assessing the thermal stability of the Sg carbonyl complex – Sg(CO)<jats:sub>6</jats:sub>. The experimental setup was tested with Mo and W carbonyl complexes, as their properties are established and supported by theoretical predictions. The suggested approach proved to be effective in discriminating between the thermal stabilities of Mo(CO)<jats:sub>6</jats:sub> and W(CO)<jats:sub>6</jats:sub>. Therefore, an experimental verification of the predicted Sg–CO bond dissociation energy seems to be feasible by applying this technique. By investigating the effect of <jats:sup>104,105</jats:sup>Mo beta-decay on the formation of <jats:sup>104,105</jats:sup>Tc carbonyl complex, we estimated the lower reaction time limit for the metal carbonyl synthesis in the gas phase to be more than 100 ms. We examined further the influence of the wall material of the recoil chamber, the carrier gas composition, the gas flow rate, and the pressure on the production yield of <jats:sup>104</jats:sup>Mo(CO)<jats:sub>6</jats:sub>, so that the future stability tests with Sg(CO)<jats:sub>6</jats:sub> can be optimized accordingly.</jats:p>
- Autoren
- I Usoltsev
- R Eichler
- Y Wang
- J Even
- A Yakushev
- H Haba
- M Asai
- H Brand
- A Di Nitto
- Ch E Düllmann
- F Fangli
- W Hartmann
- M Huang
- E Jäger
- D Kaji
- J Kanaya
- Y Kaneya
- J Khuyagbaatar
- B Kindler
- JV Kratz
- J Krier
- Y Kudou
- N Kurz
- B Lommel
- S Miyashita
- K Morimoto
- K Morita
- M Murakami
- Y Nagame
- H Nitsche
- K Ooe
- TK Sato
- M Schädel
- J Steiner
- P Steinegger
- T Sumita
- M Takeyama
- K Tanaka
- A Toyoshima
- K Tsukada
- A Türler
- Y Wakabayashi
- N Wiehl
- S Yamaki
- Z Qin
- DOI
- 10.1515/ract-2015-2445
- eISSN
- 2193-3405
- ISSN
- 0033-8230
- Ausgabe der Veröffentlichung
- 3
- Zeitschrift
- Radiochimica Acta
- Sprache
- en
- Online publication date
- 2015
- Paginierung
- 141 - 151
- Datum der Veröffentlichung
- 2016
- Status
- Published
- Herausgeber
- Walter de Gruyter GmbH
- Herausgeber URL
- http://dx.doi.org/10.1515/ract-2015-2445
- Datum der Datenerfassung
- 2021
- Titel
- Decomposition studies of group 6 hexacarbonyl complexes. Part 1: Production and decomposition of Mo(CO)<sub>6</sub> and W(CO)<sub>6</sub>
- Ausgabe der Zeitschrift
- 104
Datenquelle: Crossref
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