Crystal structure and electronic and magnetic properties of hexacyanoosmate(III)

Publikationstyp:
Zeitschriftenaufsatz
Metadaten:
Autoren
  • P Albores
  • LD Slep
  • LM Baraldo
  • R Baggio
  • MT Garland
  • E Rentschler
Autoren-URL
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000236119700002&DestLinkType=FullRecord&DestApp=WOS_CPL
DOI
10.1021/ic0516818
Externe Identifier
  • Clarivate Analytics Document Solution ID: 023IG
  • PubMed Identifier: 16529444
ISSN
0020-1669
Ausgabe der Veröffentlichung
6
Zeitschrift
INORGANIC CHEMISTRY
Paginierung
2361 - 2363
Datum der Veröffentlichung
2006
Status
Published
Titel
Crystal structure and electronic and magnetic properties of hexacyanoosmate(III)
Sub types
  • Article
Ausgabe der Zeitschrift
45

Datenquelle: Web of Science (Lite)

Andere Metadatenquellen:
Autoren
  • Pablo Albores
  • Leonardo D Slep
  • Luis M Baraldo
  • Ricardo Baggio
  • María Teresa Garland
  • Eva Rentschler
DOI
10.1021/ic0516818
eISSN
1520-510X
ISSN
0020-1669
Ausgabe der Veröffentlichung
6
Zeitschrift
Inorganic Chemistry
Sprache
en
Online publication date
2006
Paginierung
2361 - 2363
Datum der Veröffentlichung
2006
Status
Published
Herausgeber
American Chemical Society (ACS)
Herausgeber URL
http://dx.doi.org/10.1021/ic0516818
Datum der Datenerfassung
2021
Titel
Crystal Structure and Electronic and Magnetic Properties of Hexacyanoosmate(III)
Ausgabe der Zeitschrift
45

Datenquelle: Crossref

Abstract
The [Os(III)(CN)6]3- anion is prepared by chemical oxidation in aqueous solution and isolated as yellow prisms of [Ph4P]3[Os(III)(CN)6].6H2O (1). This species crystallizes in the triclinic space group P with cell parameters a = 13.7609(11) A, b = 16.2275(13) A, c = 17.0895(14) A, alpha = 91.4040(10) degrees , beta = 109.3600(10) degrees , gamma = 102.3970(10) degrees , V = 3497.4(5) A(3), and Z = 2. The slightly distorted octahedral moiety displays Os-C and C-N bond lengths that average 2.058 and 1.146 A, respectively. Spin-orbit-coupling splitting of the ground-state term dominates the NIR region of the electronic spectrum and the magnetic behavior of 1. The experimental information points to higher spin delocalization over the coordinated cyanides than in [Fe(III)(CN)6]3-.
Addresses
  • Departamento de Química Inorganica, Analítica y Química Física, INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón 2, Ciudad Universitaria, C1428EHA Buenos Aires, Argentina.
Autoren
  • Pablo Albores
  • Leonardo D Slep
  • Luis M Baraldo
  • Ricardo Baggio
  • María Teresa Garland
  • Eva Rentschler
DOI
10.1021/ic0516818
eISSN
1520-510X
Externe Identifier
  • PubMed Identifier: 16529444
Open access
false
ISSN
0020-1669
Ausgabe der Veröffentlichung
6
Zeitschrift
Inorganic chemistry
Sprache
eng
Medium
Print
Paginierung
2361 - 2363
Datum der Veröffentlichung
2006
Status
Published
Datum der Datenerfassung
2006
Titel
Crystal structure and electronic and magnetic properties of hexacyanoosmate(III).
Sub types
  • Journal Article
Ausgabe der Zeitschrift
45

Datenquelle: Europe PubMed Central

Abstract
The [Os(III)(CN)6]3- anion is prepared by chemical oxidation in aqueous solution and isolated as yellow prisms of [Ph4P]3[Os(III)(CN)6].6H2O (1). This species crystallizes in the triclinic space group P with cell parameters a = 13.7609(11) A, b = 16.2275(13) A, c = 17.0895(14) A, alpha = 91.4040(10) degrees , beta = 109.3600(10) degrees , gamma = 102.3970(10) degrees , V = 3497.4(5) A(3), and Z = 2. The slightly distorted octahedral moiety displays Os-C and C-N bond lengths that average 2.058 and 1.146 A, respectively. Spin-orbit-coupling splitting of the ground-state term dominates the NIR region of the electronic spectrum and the magnetic behavior of 1. The experimental information points to higher spin delocalization over the coordinated cyanides than in [Fe(III)(CN)6]3-.
Autoren
  • Pablo Albores
  • Leonardo D Slep
  • Luis M Baraldo
  • Ricardo Baggio
  • María Teresa Garland
  • Eva Rentschler
Autoren-URL
https://www.ncbi.nlm.nih.gov/pubmed/16529444
DOI
10.1021/ic0516818
ISSN
0020-1669
Ausgabe der Veröffentlichung
6
Zeitschrift
Inorg Chem
Sprache
eng
Country
United States
Paginierung
2361 - 2363
Datum der Veröffentlichung
2006
Status
Published
Datum, an dem der Datensatz öffentlich gemacht wurde
2007
Titel
Crystal structure and electronic and magnetic properties of hexacyanoosmate(III).
Sub types
  • Journal Article
Ausgabe der Zeitschrift
45

Datenquelle: PubMed

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