Structural and magnetic characterization of a μ-1,5-dicyanamide-bridged iron basic carboxylate [Fe3O(O2C(CH3)3)6] 1D chain

Publikationstyp:
Zeitschriftenaufsatz
Metadaten:
Autoren
  • Pablo Albores
  • Eva Rentschler
Autoren-URL
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000259093700009&DestLinkType=FullRecord&DestApp=WOS_CPL
DOI
10.1021/ic801113d
eISSN
1520-510X
Externe Identifier
  • Clarivate Analytics Document Solution ID: 346UB
  • PubMed Identifier: 18707098
ISSN
0020-1669
Ausgabe der Veröffentlichung
18
Zeitschrift
INORGANIC CHEMISTRY
Paginierung
7960 - 7962
Datum der Veröffentlichung
2008
Status
Published
Titel
Structural and magnetic characterization of a μ-1,5-dicyanamide-bridged iron basic carboxylate [Fe<sub>3</sub>O(O<sub>2</sub>C(CH<sub>3</sub>)<sub>3</sub>)<sub>6</sub>] 1D chain
Sub types
  • Article
Ausgabe der Zeitschrift
47

Datenquelle: Web of Science (Lite)

Andere Metadatenquellen:
Autoren
  • Pablo Alborés
  • Eva Rentschler
DOI
10.1021/ic801113d
eISSN
1520-510X
ISSN
0020-1669
Ausgabe der Veröffentlichung
18
Zeitschrift
Inorganic Chemistry
Sprache
en
Online publication date
2008
Paginierung
7960 - 7962
Datum der Veröffentlichung
2008
Status
Published
Herausgeber
American Chemical Society (ACS)
Herausgeber URL
http://dx.doi.org/10.1021/ic801113d
Datum der Datenerfassung
2024
Titel
Structural and Magnetic Characterization of a μ-1,5-Dicyanamide-Bridged Iron Basic Carboxylate [Fe<sub>3</sub>O(O<sub>2</sub>C(CH<sub>3</sub>)<sub>3</sub>)<sub>6</sub>] 1D Chain
Ausgabe der Zeitschrift
47

Datenquelle: Crossref

Abstract
We are reporting an unprecedented example of a mu-1,5-dicyanamide (dca)-bridged iron basic carboxylate, [Fe3O(O2C(CH3)3)6], 1D chain. As revealed from X-ray determination, the Fe3O cores are arranged in a zigzag configuration along the chain and strictly aligned in the same plane. The chains are well-isolated by the bulky tert-butyl groups. Magnetic measurements showed that the Fe3O units are weakly antiferromagnetically coupled (J = -0.6 cm(-1)) through the dca ligand while possessing a well-isolated S = 1/2 spin ground state arising from competing antiferromagnetic interactions.
Addresses
  • Institute of Inorganic and Analytical Chemistry, Johannes Gutenberg University of Mainz, D-55128 Mainz, Germany. albores@uni-mainz.de
Autoren
  • Pablo Alborés
  • Eva Rentschler
DOI
10.1021/ic801113d
eISSN
1520-510X
Externe Identifier
  • PubMed Identifier: 18707098
Open access
false
ISSN
0020-1669
Ausgabe der Veröffentlichung
18
Zeitschrift
Inorganic chemistry
Sprache
eng
Medium
Print-Electronic
Online publication date
2008
Paginierung
7960 - 7962
Datum der Veröffentlichung
2008
Status
Published
Datum der Datenerfassung
2008
Titel
Structural and magnetic characterization of a mu-1,5-dicyanamide-bridged iron basic carboxylate [Fe3O(O2C(CH3)3)6] 1D chain.
Sub types
  • Journal Article
Ausgabe der Zeitschrift
47

Datenquelle: Europe PubMed Central

Abstract
We are reporting an unprecedented example of a mu-1,5-dicyanamide (dca)-bridged iron basic carboxylate, [Fe3O(O2C(CH3)3)6], 1D chain. As revealed from X-ray determination, the Fe3O cores are arranged in a zigzag configuration along the chain and strictly aligned in the same plane. The chains are well-isolated by the bulky tert-butyl groups. Magnetic measurements showed that the Fe3O units are weakly antiferromagnetically coupled (J = -0.6 cm(-1)) through the dca ligand while possessing a well-isolated S = 1/2 spin ground state arising from competing antiferromagnetic interactions.
Autoren
  • Pablo Alborés
  • Eva Rentschler
Autoren-URL
https://www.ncbi.nlm.nih.gov/pubmed/18707098
DOI
10.1021/ic801113d
eISSN
1520-510X
Ausgabe der Veröffentlichung
18
Zeitschrift
Inorg Chem
Sprache
eng
Country
United States
Paginierung
7960 - 7962
Datum der Veröffentlichung
2008
Status
Published
Datum, an dem der Datensatz öffentlich gemacht wurde
2008
Titel
Structural and magnetic characterization of a mu-1,5-dicyanamide-bridged iron basic carboxylate [Fe3O(O2C(CH3)3)6] 1D chain.
Sub types
  • Journal Article
Ausgabe der Zeitschrift
47

Datenquelle: PubMed

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