The Interplay of Hydrogen Bonding and Multiple Metal Binding - A New Cyclic Polyaminopolyalcohol Ligand as Building Block for the Construction of Microporous, Supramolecular Networks

Publikationstyp:
Zeitschriftenaufsatz
Metadaten:
Autoren
  • Guenter J Merten
  • Christian Neis
  • Stefan Stucky
  • Volker Huch
  • Eva Rentschler
  • Harald Natter
  • Rolf Hempelmann
  • Klaus Stoewe
  • Kaspar Hegetschweiler
Autoren-URL
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000301488500003&DestLinkType=FullRecord&DestApp=WOS_CPL
DOI
10.1002/ejic.201100914
eISSN
1099-0682
Externe Identifier
  • Clarivate Analytics Document Solution ID: 908KE
ISSN
1434-1948
Ausgabe der Veröffentlichung
1
Zeitschrift
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Schlüsselwörter
  • Coordination modes
  • Bridging ligands
  • N,O ligands
  • Amino alcohols
  • Chelates
  • Hydrogen bonds
Paginierung
31 - 35
Datum der Veröffentlichung
2012
Status
Published
Titel
The Interplay of Hydrogen Bonding and Multiple Metal Binding - A New Cyclic Polyaminopolyalcohol Ligand as Building Block for the Construction of Microporous, Supramolecular Networks
Sub types
  • Article

Datenquelle: Web of Science (Lite)

Andere Metadatenquellen:
Abstract
<jats:title>Abstract</jats:title><jats:p>Cyclohexane‐based polyaminopolyalcohols (PAPAs) such as 1,3‐diamino‐1,2,3‐trideoxy‐<jats:italic>cis</jats:italic>‐inositol (daci) have been prepared by hydrogenation of suitable aromatic precursors. The pentanuclear complex [Cu<jats:sub>5</jats:sub>(daci)<jats:sub>4</jats:sub>(H<jats:sub>–2</jats:sub>daci)<jats:sub>2</jats:sub>](SO<jats:sub>4</jats:sub>)<jats:sub>3</jats:sub><jats:bold>·</jats:bold>18H<jats:sub>2</jats:sub>O (<jats:bold>C3</jats:bold>) revealed antiferromagnetic and ferromagnetic interactions between the Cu<jats:sup>II</jats:sup> centers with an <jats:italic>S</jats:italic> = 3/2 ground state. The microporous structure of <jats:bold>C3</jats:bold> exhibited a dehydration/rehydration reaction with an entirely amorphous dehydrated phase at 150 °C and a completely reversible rehydration process at 30 °C. The potential of PAPA ligands for forming polynuclear complexes and supramolecular, hydrogen‐bonded networks is discussed.</jats:p>
Autoren
  • Günter J Merten
  • Christian Neis
  • Stefan Stucky
  • Volker Huch
  • Eva Rentschler
  • Harald Natter
  • Rolf Hempelmann
  • Klaus Stöwe
  • Kaspar Hegetschweiler
DOI
10.1002/ejic.201100914
eISSN
1099-0682
ISSN
1434-1948
Ausgabe der Veröffentlichung
1
Zeitschrift
European Journal of Inorganic Chemistry
Sprache
en
Online publication date
2011
Paginierung
31 - 35
Datum der Veröffentlichung
2012
Status
Published
Herausgeber
Wiley
Herausgeber URL
http://dx.doi.org/10.1002/ejic.201100914
Datum der Datenerfassung
2023
Titel
The Interplay of Hydrogen Bonding and Multiple Metal Binding – A New Cyclic Polyaminopolyalcohol Ligand as Building Block for the Construction of Microporous, Supramolecular Networks
Ausgabe der Zeitschrift
2012

Datenquelle: Crossref

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