Rational design of covalently bridged [Fe2IIIMIIO] clusters
- Publikationstyp:
- Zeitschriftenaufsatz
- Metadaten:
-
- Autoren
- Pablo Albores
- Eva Rentschler
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000277689800045&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1039/b925214b
- eISSN
- 1477-9234
- Externe Identifier
- Clarivate Analytics Document Solution ID: 596MR
- PubMed Identifier: 21491702
- ISSN
- 1477-9226
- Ausgabe der Veröffentlichung
- 20
- Zeitschrift
- DALTON TRANSACTIONS
- Paginierung
- 5005 - 5019
- Datum der Veröffentlichung
- 2010
- Status
- Published
- Titel
- Rational design of covalently bridged [Fe<sub>2</sub><SUP>III</SUP>M<SUP>II</SUP>O] clusters
- Sub types
- Article
- Ausgabe der Zeitschrift
- 39
Datenquelle: Web of Science (Lite)
- Andere Metadatenquellen:
-
- Autoren
- Pablo Alborés
- Eva Rentschler
- DOI
- 10.1039/b925214b
- eISSN
- 1477-9234
- ISSN
- 1477-9226
- Ausgabe der Veröffentlichung
- 20
- Zeitschrift
- Dalton Transactions
- Sprache
- en
- Paginierung
- 5005 - 5005
- Datum der Veröffentlichung
- 2010
- Status
- Published
- Herausgeber
- Royal Society of Chemistry (RSC)
- Herausgeber URL
- http://dx.doi.org/10.1039/b925214b
- Datum der Datenerfassung
- 2024
- Titel
- Rational design of covalently bridged [FeIII2MIIO] clusters
- Ausgabe der Zeitschrift
- 39
Datenquelle: Crossref
- Abstract
- We are reporting the first supramolecular dimeric units of basic carboxylates. The neutral [Fe(III)₂M(II)O] motif for different 3d M metals is covalently bound through 2,2'-bipyrimidine. We have structurally characterized the hexanuclear clusters and the related trinuclear building blocks. Their magnetic properties have been fully analyzed and DFT calculations have been performed as a supplementary tool. All results evidence a weak antiferromagnetic interaction through the bpym bridge between isolated spin ground states (in some examples) arising from intra-Fe₂MO core exchange couplings.
- Addresses
- Institute of Inorganic and Analytical Chemistry, Johannes Gutenberg-University of Mainz, Duesbergweg 10-14, D-55128 Mainz, Germany. albores@qi.fcen.uba.ar
- Autoren
- Pablo Alborés
- Eva Rentschler
- DOI
- 10.1039/b925214b
- eISSN
- 1477-9234
- Externe Identifier
- PubMed Identifier: 21491702
- Open access
- false
- ISSN
- 1477-9226
- Ausgabe der Veröffentlichung
- 20
- Zeitschrift
- Dalton transactions (Cambridge, England : 2003)
- Sprache
- eng
- Medium
- Paginierung
- 5005 - 5019
- Datum der Veröffentlichung
- 2010
- Status
- Published
- Datum der Datenerfassung
- 2011
- Titel
- Rational design of covalently bridged [Fe(III)₂M(II)O] clusters.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 39
Datenquelle: Europe PubMed Central
- Abstract
- We are reporting the first supramolecular dimeric units of basic carboxylates. The neutral [Fe(III)₂M(II)O] motif for different 3d M metals is covalently bound through 2,2'-bipyrimidine. We have structurally characterized the hexanuclear clusters and the related trinuclear building blocks. Their magnetic properties have been fully analyzed and DFT calculations have been performed as a supplementary tool. All results evidence a weak antiferromagnetic interaction through the bpym bridge between isolated spin ground states (in some examples) arising from intra-Fe₂MO core exchange couplings.
- Autoren
- Pablo Alborés
- Eva Rentschler
- Autoren-URL
- https://www.ncbi.nlm.nih.gov/pubmed/21491702
- DOI
- 10.1039/b925214b
- eISSN
- 1477-9234
- Ausgabe der Veröffentlichung
- 20
- Zeitschrift
- Dalton Trans
- Sprache
- eng
- Country
- England
- Paginierung
- 5005 - 5019
- Datum der Veröffentlichung
- 2010
- Status
- Published
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2011
- Titel
- Rational design of covalently bridged [Fe(III)₂M(II)O] clusters.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 39
Datenquelle: PubMed
- Beziehungen:
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