Solvent-dependent SCO Behavior of Dinuclear Iron(II) Complexes with a 1,3,4-Thiadiazole Bridging Ligand
- Publikationstyp:
- Zeitschriftenaufsatz
- Metadaten:
-
- Autoren
- Christian F Herold
- Sergii I Shylin
- Eva Rentschler
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000379455900011&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1021/acs.inorgchem.6b00163
- eISSN
- 1520-510X
- Externe Identifier
- Clarivate Analytics Document Solution ID: DQ8JC
- PubMed Identifier: 27295388
- ISSN
- 0020-1669
- Ausgabe der Veröffentlichung
- 13
- Zeitschrift
- INORGANIC CHEMISTRY
- Paginierung
- 6414 - 6419
- Datum der Veröffentlichung
- 2016
- Status
- Published
- Titel
- Solvent-dependent SCO Behavior of Dinuclear Iron(II) Complexes with a 1,3,4-Thiadiazole Bridging Ligand
- Sub types
- Article
- Ausgabe der Zeitschrift
- 55
Datenquelle: Web of Science (Lite)
- Andere Metadatenquellen:
-
- Autoren
- Christian F Herold
- Sergii I Shylin
- Eva Rentschler
- DOI
- 10.1021/acs.inorgchem.6b00163
- eISSN
- 1520-510X
- ISSN
- 0020-1669
- Ausgabe der Veröffentlichung
- 13
- Zeitschrift
- Inorganic Chemistry
- Sprache
- en
- Online publication date
- 2016
- Paginierung
- 6414 - 6419
- Datum der Veröffentlichung
- 2016
- Status
- Published
- Herausgeber
- American Chemical Society (ACS)
- Herausgeber URL
- http://dx.doi.org/10.1021/acs.inorgchem.6b00163
- Datum der Datenerfassung
- 2023
- Titel
- Solvent-dependent SCO Behavior of Dinuclear Iron(II) Complexes with a 1,3,4-Thiadiazole Bridging Ligand
- Ausgabe der Zeitschrift
- 55
Datenquelle: Crossref
- Abstract
- Two dinuclear iron(II) complexes [Fe2(μ-L)2]X4*4DMF (X = BF4(-) (1·4DMF) and ClO4(-) (2·4DMF)) with a 1,3,4-thiadiazole bridging ligand have been synthesized and show a very distinct solvent-depending SCO behavior. The complexes represent new solvatomorphs of the first dinuclear iron(II) complexes with the ligand L (2,5-bis[(2-pyridylmethyl)amino]methyl-1,3,4-thiadiazole). The incorporated lattice DMF molecules directly affect the spin state of these complexes. This behavior reveals a structural insight into the role of the solvent molecules on the spin transition.
- Addresses
- Institute of Inorganic and Analytical Chemistry, Johannes Gutenberg University , Mainz, Germany.
- Autoren
- Christian F Herold
- Sergii I Shylin
- Eva Rentschler
- DOI
- 10.1021/acs.inorgchem.6b00163
- eISSN
- 1520-510X
- Externe Identifier
- PubMed Identifier: 27295388
- Open access
- false
- ISSN
- 0020-1669
- Ausgabe der Veröffentlichung
- 13
- Zeitschrift
- Inorganic chemistry
- Sprache
- eng
- Medium
- Print-Electronic
- Online publication date
- 2016
- Paginierung
- 6414 - 6419
- Datum der Veröffentlichung
- 2016
- Status
- Published
- Datum der Datenerfassung
- 2016
- Titel
- Solvent-dependent SCO Behavior of Dinuclear Iron(II) Complexes with a 1,3,4-Thiadiazole Bridging Ligand.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 55
Datenquelle: Europe PubMed Central
- Abstract
- Two dinuclear iron(II) complexes [Fe2(μ-L)2]X4*4DMF (X = BF4(-) (1·4DMF) and ClO4(-) (2·4DMF)) with a 1,3,4-thiadiazole bridging ligand have been synthesized and show a very distinct solvent-depending SCO behavior. The complexes represent new solvatomorphs of the first dinuclear iron(II) complexes with the ligand L (2,5-bis[(2-pyridylmethyl)amino]methyl-1,3,4-thiadiazole). The incorporated lattice DMF molecules directly affect the spin state of these complexes. This behavior reveals a structural insight into the role of the solvent molecules on the spin transition.
- Autoren
- Christian F Herold
- Sergii I Shylin
- Eva Rentschler
- Autoren-URL
- https://www.ncbi.nlm.nih.gov/pubmed/27295388
- DOI
- 10.1021/acs.inorgchem.6b00163
- eISSN
- 1520-510X
- Ausgabe der Veröffentlichung
- 13
- Zeitschrift
- Inorg Chem
- Sprache
- eng
- Country
- United States
- Paginierung
- 6414 - 6419
- Datum der Veröffentlichung
- 2016
- Status
- Published
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2018
- Titel
- Solvent-dependent SCO Behavior of Dinuclear Iron(II) Complexes with a 1,3,4-Thiadiazole Bridging Ligand.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 55
Datenquelle: PubMed
- Beziehungen:
- Eigentum von