3d/4f Sandwich Complex Based on Metallacrowns
- Publikationstyp:
- Zeitschriftenaufsatz
- Metadaten:
-
- Autoren
- Andreas Rauguth
- Alexander Kredel
- Luca M Carrella
- Eva Rentschler
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000699833500029&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1021/acs.inorgchem.1c01356
- eISSN
- 1520-510X
- Externe Identifier
- Clarivate Analytics Document Solution ID: UW0BT
- PubMed Identifier: 34463493
- ISSN
- 0020-1669
- Ausgabe der Veröffentlichung
- 18
- Zeitschrift
- INORGANIC CHEMISTRY
- Paginierung
- 14031 - 14037
- Datum der Veröffentlichung
- 2021
- Status
- Published
- Titel
- 3d/4f Sandwich Complex Based on Metallacrowns
- Sub types
- Article
- Ausgabe der Zeitschrift
- 60
Datenquelle: Web of Science (Lite)
- Andere Metadatenquellen:
-
- Autoren
- Andreas Rauguth
- Alexander Kredel
- Luca M Carrella
- Eva Rentschler
- DOI
- 10.1021/acs.inorgchem.1c01356
- eISSN
- 1520-510X
- ISSN
- 0020-1669
- Ausgabe der Veröffentlichung
- 18
- Zeitschrift
- Inorganic Chemistry
- Sprache
- en
- Online publication date
- 2021
- Paginierung
- 14031 - 14037
- Datum der Veröffentlichung
- 2021
- Status
- Published
- Herausgeber
- American Chemical Society (ACS)
- Herausgeber URL
- http://dx.doi.org/10.1021/acs.inorgchem.1c01356
- Datum der Datenerfassung
- 2023
- Titel
- 3d/4f Sandwich Complex Based on Metallacrowns
- Ausgabe der Zeitschrift
- 60
Datenquelle: Crossref
- Abstract
- A novel lanthanide double-decker complex with nickel metallacrowns (MCs) as coordinating ligands has been synthesized. In the 3d/4f metallacrown complex Tb<sup>III</sup>[12-MC<sub>Ni<sup>II</sup>N(shi)</sub>-4]<sub>2</sub>, the central lanthanide ion is sandwiched between two [12-MC-4] units, forming an almost ideal square-antiprismatic coordination sphere. The resulting zenithal angles at the central lanthanide ion are smaller than those for previously reported sandwich compounds. Magnetic measurements reveal an energy barrier of 346 K under zero field and up to 585 K under 3200 Oe, the highest reported for metallacrowns with <i>D</i><sub>4<i>d</i></sub> symmetry.
- Addresses
- Department of Chemistry, Johannes Gutenberg University of Mainz, Duesbergweg 10-14, Mainz D-55128, Germany.
- Autoren
- Andreas Rauguth
- Alexander Kredel
- Luca M Carrella
- Eva Rentschler
- DOI
- 10.1021/acs.inorgchem.1c01356
- eISSN
- 1520-510X
- Externe Identifier
- PubMed Identifier: 34463493
- Funding acknowledgements
- Deutsche Forschungsgemeinschaft: TRR 173 268565370
- Open access
- false
- ISSN
- 0020-1669
- Ausgabe der Veröffentlichung
- 18
- Zeitschrift
- Inorganic chemistry
- Sprache
- eng
- Medium
- Print-Electronic
- Online publication date
- 2021
- Paginierung
- 14031 - 14037
- Datum der Veröffentlichung
- 2021
- Status
- Published
- Datum der Datenerfassung
- 2021
- Titel
- 3d/4f Sandwich Complex Based on Metallacrowns.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 60
Datenquelle: Europe PubMed Central
- Abstract
- A novel lanthanide double-decker complex with nickel metallacrowns (MCs) as coordinating ligands has been synthesized. In the 3d/4f metallacrown complex TbIII[12-MCNiIIN(shi)-4]2, the central lanthanide ion is sandwiched between two [12-MC-4] units, forming an almost ideal square-antiprismatic coordination sphere. The resulting zenithal angles at the central lanthanide ion are smaller than those for previously reported sandwich compounds. Magnetic measurements reveal an energy barrier of 346 K under zero field and up to 585 K under 3200 Oe, the highest reported for metallacrowns with D4d symmetry.
- Autoren
- Andreas Rauguth
- Alexander Kredel
- Luca M Carrella
- Eva Rentschler
- Autoren-URL
- https://www.ncbi.nlm.nih.gov/pubmed/34463493
- DOI
- 10.1021/acs.inorgchem.1c01356
- eISSN
- 1520-510X
- Ausgabe der Veröffentlichung
- 18
- Zeitschrift
- Inorg Chem
- Sprache
- eng
- Country
- United States
- Paginierung
- 14031 - 14037
- Datum der Veröffentlichung
- 2021
- Status
- Published
- Titel
- 3d/4f Sandwich Complex Based on Metallacrowns.
- Sub types
- Journal Article
- Ausgabe der Zeitschrift
- 60
Datenquelle: PubMed
- Beziehungen:
- Eigentum von