Redox and Photochemistry of Bis(terpyridine) ruthenium(II) Amino Acids and Their Amide Conjugates - from Understanding to Applications

Publikationstyp:
Zeitschriftenaufsatz
Metadaten:
Autoren
  • Aaron Breivogel
  • Christoph Kreitner
  • Katja Heinze
Autoren-URL
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000344791900001&DestLinkType=FullRecord&DestApp=WOS_CPL
DOI
10.1002/ejic.201402466
eISSN
1099-0682
Externe Identifier
  • Clarivate Analytics Document Solution ID: AT2UL
ISSN
1434-1948
Ausgabe der Veröffentlichung
32
Zeitschrift
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Schlüsselwörter
  • Electron transfer
  • Energy transfer
  • Luminescence
  • Photochemistry
  • Redox chemistry
  • Ruthenium
  • Tridentate ligands
Paginierung
5468 - 5490
Datum der Veröffentlichung
2014
Status
Published
Titel
Redox and Photochemistry of Bis(terpyridine) ruthenium(II) Amino Acids and Their Amide Conjugates - from Understanding to Applications
Sub types
  • Review

Datenquelle: Web of Science (Lite)

Andere Metadatenquellen:
Abstract
<jats:title>Abstract</jats:title><jats:p>The push‐pull‐substituted bis(terpyridine)ruthenium(II) amino acid [Ru(4′‐tpy‐COOH)(4′‐tpy‐NH<jats:sub>2</jats:sub>)]<jats:sup>2+</jats:sup> ([<jats:bold>5</jats:bold>]<jats:sup>2+</jats:sup>; tpy = 2,2′;6′,2″‐terpyridine) with carboxylic acid and amino substituents features exceptional chemical and photophysical properties. Its interaction with photons, electrons, and/or protons results in room‐temperature phosphorescence, reversible oxidative and reductive redox chemistry, reversible acid/base chemistry, proton‐coupled electron transfer, photoinduced reductive and oxidative electron transfer, excited‐state proton transfer and energy transfer reactions. These properties can be fine‐tuned by variations of the bis(terpyridine) amino acid motif, namely extension of the π system and expansion of the chelate ring. Furthermore, the chemically orthogonal functional groups enable the incorporation of this metallo amino acid into peptide architectures in a highly selective manner, even by solid‐phase peptide synthesis protocols. Amide‐linked conjugates with other metal complexes [(terpyridine)ruthenium(II), ferrocene, (bipyridine)rhenium(I), (bipyridine)platinum(II)], organic chromophores, or ZnO nanoparticles underscore the versatile synthetic, redox, and photochemistry of this building block. First real‐world applications of [<jats:bold>5</jats:bold>]<jats:sup>2+</jats:sup> and its derivatives include light‐emitting electrochemical cells (LECs) and dye‐sensitized solar cells (DSSCs).</jats:p>
Autoren
  • Aaron Breivogel
  • Christoph Kreitner
  • Katja Heinze
DOI
10.1002/ejic.201402466
eISSN
1099-0682
ISSN
1434-1948
Ausgabe der Veröffentlichung
32
Zeitschrift
European Journal of Inorganic Chemistry
Sprache
en
Online publication date
2014
Paginierung
5468 - 5490
Datum der Veröffentlichung
2014
Status
Published
Herausgeber
Wiley
Herausgeber URL
http://dx.doi.org/10.1002/ejic.201402466
Datum der Datenerfassung
2023
Titel
Redox and Photochemistry of Bis(terpyridine)ruthenium(II) Amino Acids and Their Amide Conjugates – from Understanding to Applications
Ausgabe der Zeitschrift
2014

Datenquelle: Crossref

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