Luminescence and Light-Driven Energy and Electron Transfer from an Exceptionally Long-Lived Excited State of a Non-Innocent Chromium(III) Complex
- Publikationstyp:
- Zeitschriftenaufsatz
- Metadaten:
-
- Autoren
- Steffen Treiling
- Cui Wang
- Christoph Foerster
- Florian Reichenauer
- Jens Kalmbach
- Pit Boden
- Joe P Harris
- Luca M Carrella
- Eva Rentschler
- Ute Resch-Genger
- Christian Reber
- Michael Seitz
- Markus Gerhards
- Katja Heinze
- Autoren-URL
- https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=fis-test-1&SrcAuth=WosAPI&KeyUT=WOS:000499984500023&DestLinkType=FullRecord&DestApp=WOS_CPL
- DOI
- 10.1002/anie.201909325
- eISSN
- 1521-3773
- Externe Identifier
- Clarivate Analytics Document Solution ID: JS0DK
- PubMed Identifier: 31600421
- ISSN
- 1433-7851
- Ausgabe der Veröffentlichung
- 50
- Zeitschrift
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Schlüsselwörter
- Earth-abundant metals
- Laporte's rule
- Luminescence
- Photoredox chemistry
- Sustainable Chemistry
- Paginierung
- 18075 - 18085
- Datum der Veröffentlichung
- 2019
- Status
- Published
- Titel
- Luminescence and Light-Driven Energy and Electron Transfer from an Exceptionally Long-Lived Excited State of a Non-Innocent Chromium(III) Complex
- Sub types
- Article
- Ausgabe der Zeitschrift
- 58
Datenquelle: Web of Science (Lite)
- Andere Metadatenquellen:
-
- Abstract
- <jats:title>Abstract</jats:title><jats:p>Photoactive metal complexes employing Earth‐abundant metal ions are a key to sustainable photophysical and photochemical applications. We exploit the effects of an inversion center and ligand non‐innocence to tune the luminescence and photochemistry of the excited state of the [CrN<jats:sub>6</jats:sub>] chromophore [Cr(tpe)<jats:sub>2</jats:sub>]<jats:sup>3+</jats:sup> with close to octahedral symmetry (tpe=1,1,1‐tris(pyrid‐2‐yl)ethane). [Cr(tpe)<jats:sub>2</jats:sub>]<jats:sup>3+</jats:sup> exhibits the longest luminescence lifetime (<jats:italic>τ</jats:italic>=4500 μs) reported up to date for a molecular polypyridyl chromium(III) complex together with a very high luminescence quantum yield of <jats:italic>Φ</jats:italic>=8.2 % at room temperature in fluid solution. Furthermore, the tpe ligands in [Cr(tpe)<jats:sub>2</jats:sub>]<jats:sup>3+</jats:sup> are redox non‐innocent, leading to reversible reductive chemistry. The excited state redox potential and lifetime of [Cr(tpe)<jats:sub>2</jats:sub>]<jats:sup>3+</jats:sup> surpass those of the classical photosensitizer [Ru(bpy)<jats:sub>3</jats:sub>]<jats:sup>2+</jats:sup> (bpy=2,2′‐bipyridine) enabling energy transfer (to oxygen) and photoredox processes (with azulene and tri(<jats:italic>n</jats:italic>‐butyl)amine).</jats:p>
- Autoren
- Steffen Treiling
- Cui Wang
- Christoph Förster
- Florian Reichenauer
- Jens Kalmbach
- Pit Boden
- Joe P Harris
- Luca M Carrella
- Eva Rentschler
- Ute Resch‐Genger
- Christian Reber
- Michael Seitz
- Markus Gerhards
- Katja Heinze
- DOI
- 10.1002/anie.201909325
- eISSN
- 1521-3773
- ISSN
- 1433-7851
- Ausgabe der Veröffentlichung
- 50
- Zeitschrift
- Angewandte Chemie International Edition
- Sprache
- en
- Online publication date
- 2019
- Paginierung
- 18075 - 18085
- Datum der Veröffentlichung
- 2019
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/anie.201909325
- Datum der Datenerfassung
- 2023
- Titel
- Luminescence and Light‐Driven Energy and Electron Transfer from an Exceptionally Long‐Lived Excited State of a Non‐Innocent Chromium(III) Complex
- Ausgabe der Zeitschrift
- 58
Datenquelle: Crossref
- Abstract
- Photoactive metal complexes employing Earth-abundant metal ions are a key to sustainable photophysical and photochemical applications. We exploit the effects of an inversion center and ligand non-innocence to tune the luminescence and photochemistry of the excited state of the [CrN<sub>6</sub> ] chromophore [Cr(tpe)<sub>2</sub> ]<sup>3+</sup> with close to octahedral symmetry (tpe=1,1,1-tris(pyrid-2-yl)ethane). [Cr(tpe)<sub>2</sub> ]<sup>3+</sup> exhibits the longest luminescence lifetime (τ=4500 μs) reported up to date for a molecular polypyridyl chromium(III) complex together with a very high luminescence quantum yield of Φ=8.2 % at room temperature in fluid solution. Furthermore, the tpe ligands in [Cr(tpe)<sub>2</sub> ]<sup>3+</sup> are redox non-innocent, leading to reversible reductive chemistry. The excited state redox potential and lifetime of [Cr(tpe)<sub>2</sub> ]<sup>3+</sup> surpass those of the classical photosensitizer [Ru(bpy)<sub>3</sub> ]<sup>2+</sup> (bpy=2,2'-bipyridine) enabling energy transfer (to oxygen) and photoredox processes (with azulene and tri(n-butyl)amine).
- Addresses
- Institute of Inorganic Chemistry and Analytical Chemistry, Johannes Gutenberg University of Mainz, Duesbergweg 10-14, 55128, Mainz, Germany.
- Autoren
- Steffen Treiling
- Cui Wang
- Christoph Förster
- Florian Reichenauer
- Jens Kalmbach
- Pit Boden
- Joe P Harris
- Luca M Carrella
- Eva Rentschler
- Ute Resch-Genger
- Christian Reber
- Michael Seitz
- Markus Gerhards
- Katja Heinze
- DOI
- 10.1002/anie.201909325
- eISSN
- 1521-3773
- Externe Identifier
- PubMed Identifier: 31600421
- PubMed Central ID: PMC6916301
- Funding acknowledgements
- Deutsche Forschungsgemeinschaft: RE 1203/23-1
- Deutsche Forschungsgemeinschaft: GE 961/10-1
- Deutsche Forschungsgemeinschaft: SE 1448/8-1
- Deutsche Forschungsgemeinschaft: HE 2778/15-1
- Deutscher Akademischer Austauschdienst:
- Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada:
- Open access
- true
- ISSN
- 1433-7851
- Ausgabe der Veröffentlichung
- 50
- Zeitschrift
- Angewandte Chemie (International ed. in English)
- Sprache
- eng
- Medium
- Print-Electronic
- Online publication date
- 2019
- Open access status
- Open Access
- Paginierung
- 18075 - 18085
- Datum der Veröffentlichung
- 2019
- Status
- Published
- Publisher licence
- CC BY
- Datum der Datenerfassung
- 2019
- Titel
- Luminescence and Light-Driven Energy and Electron Transfer from an Exceptionally Long-Lived Excited State of a Non-Innocent Chromium(III) Complex.
- Sub types
- review-article
- Review
- Journal Article
- Ausgabe der Zeitschrift
- 58
Files
https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/anie.201909325 https://europepmc.org/articles/PMC6916301?pdf=render
Datenquelle: Europe PubMed Central
- Abstract
- Photoactive metal complexes employing Earth-abundant metal ions are a key to sustainable photophysical and photochemical applications. We exploit the effects of an inversion center and ligand non-innocence to tune the luminescence and photochemistry of the excited state of the [CrN6 ] chromophore [Cr(tpe)2 ]3+ with close to octahedral symmetry (tpe=1,1,1-tris(pyrid-2-yl)ethane). [Cr(tpe)2 ]3+ exhibits the longest luminescence lifetime (τ=4500 μs) reported up to date for a molecular polypyridyl chromium(III) complex together with a very high luminescence quantum yield of Φ=8.2 % at room temperature in fluid solution. Furthermore, the tpe ligands in [Cr(tpe)2 ]3+ are redox non-innocent, leading to reversible reductive chemistry. The excited state redox potential and lifetime of [Cr(tpe)2 ]3+ surpass those of the classical photosensitizer [Ru(bpy)3 ]2+ (bpy=2,2'-bipyridine) enabling energy transfer (to oxygen) and photoredox processes (with azulene and tri(n-butyl)amine).
- Autoren
- Steffen Treiling
- Cui Wang
- Christoph Förster
- Florian Reichenauer
- Jens Kalmbach
- Pit Boden
- Joe P Harris
- Luca M Carrella
- Eva Rentschler
- Ute Resch-Genger
- Christian Reber
- Michael Seitz
- Markus Gerhards
- Katja Heinze
- Autoren-URL
- https://www.ncbi.nlm.nih.gov/pubmed/31600421
- DOI
- 10.1002/anie.201909325
- eISSN
- 1521-3773
- Externe Identifier
- PubMed Central ID: PMC6916301
- Funding acknowledgements
- Deutsche Forschungsgemeinschaft: RE 1203/23-1
- Deutsche Forschungsgemeinschaft: HE 2778/15-1
- Deutsche Forschungsgemeinschaft: SE 1448/8-1
- Deutsche Forschungsgemeinschaft: GE 961/10-1
- Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada:
- Deutscher Akademischer Austauschdienst:
- Ausgabe der Veröffentlichung
- 50
- Zeitschrift
- Angew Chem Int Ed Engl
- Schlüsselwörter
- Earth-abundant metals
- Laporte's rule
- Luminescence
- Photoredox chemistry
- Sustainable Chemistry
- Sprache
- eng
- Country
- Germany
- Paginierung
- 18075 - 18085
- Datum der Veröffentlichung
- 2019
- Status
- Published
- Titel
- Luminescence and Light-Driven Energy and Electron Transfer from an Exceptionally Long-Lived Excited State of a Non-Innocent Chromium(III) Complex.
- Sub types
- Journal Article
- Review
- Ausgabe der Zeitschrift
- 58
Datenquelle: PubMed
- Author's licence
- CC-BY
- Autoren
- Steffen Treiling
- Cui Wang
- Christoph Förster
- Florian Reichenauer
- Jens Kalmbach
- Pit Boden
- Joe P Harris
- Luca M Carrella
- Eva Rentschler
- Ute Resch-Genger
- Christian Reber
- Michael Seitz
- Markus Gerhards
- Katja Heinze
- Hosting institution
- Universitätsbibliothek Mainz
- Sammlungen
- JGU-Publikationen
- Resource version
- Published version
- DOI
- 10.1002/anie.201909325
- File(s) embargoed
- false
- Open access
- true
- ISSN
- 1521-3773
- Ausgabe der Veröffentlichung
- 50
- Zeitschrift
- Angewandte Chemie : International edition
- Schlüsselwörter
- 540 Chemie
- 540 Chemistry and allied sciences
- Sprache
- eng
- Open access status
- Open Access
- Paginierung
- 18075 - 18085
- Datum der Veröffentlichung
- 2019
- Public URL
- https://openscience.ub.uni-mainz.de/handle/20.500.12030/7074
- Herausgeber
- Wiley-VCH
- Datum der Datenerfassung
- 2022
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2022
- Zugang
- Public
- Titel
- Luminescence and light-driven energy and electron transfer from an exceptionally long-lived excited state of a non-innocent chromium(III) complex
- Ausgabe der Zeitschrift
- 58
Files
luminescence_and_lightdriven_-20220601114716967.pdf
Datenquelle: OPENSCIENCE.UB
- Beziehungen:
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