Metal‐ and Reagent‐Free Electrochemical Synthesis of Alkyl Arylsulfonates in a Multi‐Component Reaction
- Publikationstyp:
- Zeitschriftenaufsatz
- Metadaten:
-
- Abstract
- <jats:title>Abstract</jats:title><jats:p>This work presents the first electrochemical preparation of alkyl arylsulfonates by direct anodic oxidation of electron‐rich arenes. The reaction mechanism features a multi‐component reaction consisting of electron‐rich arenes, an alcohol of choice and excess SO<jats:sub>2</jats:sub> in an acetonitrile‐HFIP reaction mixture. In‐situ formed monoalkyl sulfites are considered as key intermediates with bifunctional purpose. Firstly, this species functions as nucleophile and secondly, excellent conductivity is provided. Several primary and secondary alcohols and electron‐rich arenes are implemented in this reaction to form the alkyl arylsulfonates in yields up to 73 % with exquisite selectivity. Boron‐doped diamond electrodes (BDD) are employed in divided cells, separated by a simple commercially available glass frit.</jats:p>
- Autoren
- Stephan P Blum
- Dieter Schollmeyer
- Maris Turks
- Siegfried R Waldvogel
- DOI
- 10.1002/chem.202001180
- eISSN
- 1521-3765
- ISSN
- 0947-6539
- Ausgabe der Veröffentlichung
- 38
- Zeitschrift
- Chemistry – A European Journal
- Sprache
- en
- Online publication date
- 2020
- Paginierung
- 8358 - 8362
- Datum der Veröffentlichung
- 2020
- Status
- Published
- Herausgeber
- Wiley
- Herausgeber URL
- http://dx.doi.org/10.1002/chem.202001180
- Datum der Datenerfassung
- 2023
- Titel
- Metal‐ and Reagent‐Free Electrochemical Synthesis of Alkyl Arylsulfonates in a Multi‐Component Reaction
- Ausgabe der Zeitschrift
- 26
Datenquelle: Crossref
- Andere Metadatenquellen:
-
- Author's licence
- CC-BY-NC-ND
- Autoren
- Stephan P Blum
- Dieter Schollmeyer
- Maris Turks
- Siegfried R Waldvogel
- Hosting institution
- Universitätsbibliothek Mainz
- Sammlungen
- JGU-Publikationen
- Resource version
- Published version
- DOI
- 10.1002/chem.202001180
- File(s) embargoed
- false
- Open access
- true
- ISSN
- 1521-3765
- Ausgabe der Veröffentlichung
- 38
- Zeitschrift
- Chemistry - a European journal
- Schlüsselwörter
- 540 Chemie
- 540 Chemistry and allied sciences
- Sprache
- eng
- Open access status
- Open Access
- Paginierung
- 8358 - 8362
- Datum der Veröffentlichung
- 2020
- Public URL
- https://openscience.ub.uni-mainz.de/handle/20.500.12030/6257
- Herausgeber
- Wiley-VCH
- Herausgeber URL
- https://doi.org/10.1002/chem.202001180
- Datum der Datenerfassung
- 2021
- Datum, an dem der Datensatz öffentlich gemacht wurde
- 2021
- Zugang
- Public
- Titel
- Metal- and reagent-free electrochemical synthesis of alkyl arylsulfonates in a multi-component reaction
- Ausgabe der Zeitschrift
- 26
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Datenquelle: OPENSCIENCE.UB